Position:Home >> Abstract

A method for obtaining the real retention of nanofiltration membrane
Authors: Zhang Xianqiu ,Du Mingxia,Wang Zhiliang, Zhang Yong,Jia Guozheng
Units: 1, School of Environment Science & Engineering, Nanjing Normal Universty Nanjing 210042, China)
KeyWords: nanofiltration membrane; real retention; concentration polarization
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2010,30(6):0-0

Abstract:
Abstract: The real retention of membrane is usually used when performances of nanofiltration membrane are characterized . But the real retention is only obtained from mass transfer coefficient at present because it can not be directly measured. It is difficult for correctly calculation the real retention of spiral-wound modules because there are large difference among mass transfer coefficient equations published in literatures. In this paper, based on concentration polarization theoretic model and the flow structure of spiral-wound modules,and combined  permeation experiments results with NF90-2540 spiral-wound modules, a equation for calculation the real retention of nanofiltration membrane was established. Meanwhile, the experimental and calculation results showed concentration polarization was mainly controlled by permeation flux and solution velocity in membrane: concentration polarization notably increased at low velocity, and the difference between observed retention and real retention was notable; concentration polarization notably lowered as velocity increasing, and when velocity was higher than 0.2m/s, the difference between observed retention and real retention was small.

Funds:
江苏省环保厅基金资助项目(200802);江苏省环境工程重点实验室开放课题(KF2009006)

AuthorIntro:
张显球(1971—),男,安徽太湖人,博士,副教授,从事水污染控制与膜分离技术研究。

Reference:
参考文献
[1]Ana I, Cavaco M, Ana M, et al. Concentration polarization in a reverse osmosis/nanofiltration plate-and-frame membrane module[J]. Journal of Membrane Science, 2008, 325(2):580-591
[2]Geraldes V, Afonso M D. Prediction of the concentration polarization in the nanofiltration/reverse osmosis of dilute multi-ionic solutions[J]. Journal of Membrane Science, 2007, 300( 1-2):20-27.
[3] Vineet K. Gupta, Sun-Tak H, et al. Characterization of nanofiltration and reverse osmosis membrane performance for aqueous salt solutions using irreversible thermodynamics[J]. Desalination, 2007,208 ( 1-3): 1-18
[4]Geraldes V, Semiao V, Norberta M. Concentration polarisation and flow structure within nanofiltration spiral-wound modules with ladder-type spacers[J]. Computers & Structures, 2004, 82(17-19): 1561-1568
[5]Wang X L, Tsuru T, Nakao S, et al. The electrostatic and steric-hindrance model for the transport of charged solutes through nanofiltration membrane[J]. Journal of Membrane Science, 1997, 135(1): 19-32.
[6] Ismail A F, Hassan A R. The deduction of fine structural details of asymmetric nanofiltration membranes using
 
theoretical models[J]. Journal of Membrane Science, 2004, 231(1-2): 25–36.
[7] Wang  Y, Chung T S. The characterization of flat composite nanofiltration membranes and their applications in the separation of cephalexin[J]. Journal of Membrane Science, 2005, 247(1-2):37–50.
[8]  Otero J A , Gutierrez R, Inmaculada A, et al. Structural and functional study of two nanofiltration membranes. Desalination, 2006, 200 (1/2/3): 354-355.
[9]  Deissler R. Analysis of turbulent heat transfer, mass transfer and friction in smooth tubes at high prandtl and Schmidt numbers.New York:1961
[10] Shock G, Miquel A. Mass transfer and pressure loss in spiral wound modules[J]. Desalination, 1987, 64: 339–352.
[11]Hichey P J, Gooding C H. Mass transfer in spiral wound pervaporation modules[J], Journal of Membrane Science, 1994, 92: 59-74.
[12] Hichey P J, Gooding C H. Erratum to in spiral wound pervaporation modules[J]. Journal of Membrane Science, 1995, 98: 293-298.
[13] Eriksson P. water and salt transport through two types of polyamide composite membranes[J]. Journal of Membrane Science, 1988, 36: 297-313.
[14] 王晓琳,丁宁. 反渗透和纳滤技术与应用[M].北京:化学工业出版社,2005
Wang Xiaolin, Ding Ning. Techonology and application of reverse osmosis and Nanofiltration[M]. Beijing: Chinese Chemical Industry Press, 2005
[15]Gang Y, Xing W, Xu N. Concentration polarization in spiral-wound nanofiltration membrane elements[J]. Desalination. 2003, 154: 89-99
[16] Wijmans J G, Baker R W. the solution-diffusion model: A review[J]. Journal of Membrane Science 1995, 107 :1~21.

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号