Position:Home >> Abstract

Progress of Pervaporation in Bio-butanol Production from ABE Fermentation
Authors: JIN Wanqin, LIU Gongping, XU Nanping
Units: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China
KeyWords: pervaporation; bio-fuel; butanol; ABE fermentation; coupled process
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2011,31(3):25-31

Abstract:
At the last of 20th century, energy crisis and environmental protection promote the research on bio-butanol production from biomass fermentation. Owing to its separation efficiency, energy-saving, environmental friendly and convenient for coupling with fermentation, pervaporation separation technology plays an important role in the bio-butanol production process. Therefore, this paper reviewed the hydrophobic and hydrophilic pervaporation membranes used for bio-butanol production, as well as the ABE fermentation-pervaporation coupled process, and finally the future trend in this field were prospected.

Funds:
国家重点基础研究发展规划项目(2009CB623400);国家自然科学基金(20990222);江苏省六大人才高峰计划(2007007)

AuthorIntro:
作者简介:金万勤(1963- ),男,江苏泰州人,博士,博士生导师,从事膜材料、膜制备及膜反应器的研究。 通讯联系人,E-mail:wqjin@njut.edu.cn

Reference:
[1] Zverlov V V,Berezina O,Velikodvorskaya G A,et al. Bacterial acetone and butanol production by industrial fermentation in the Soviet Union:use of hydrolyzed agricultural waste for biorefinery[J].Appl Microbiol Biotechnol,2006,71:587-597.
[2] Qureshi N,Ezeji T C,Butanol,'a superior biofuel' production from agricultural residues (renewable biomass):Recent progress in technology[J].Biofuels Bioprod Bioref,2008,2:319-330.
[3] Jain M K,Beacom D,Datta R,Mutant strain of C.acetobutylicum and process for making butanol[P].US Patent,1993,5192673.
[4] Qureshi N,Blaschek H P,Butanol recovery from model solution/fermentation broth by pervaporation: evaluation of membrane performance [J].Biomass Bioenergy,1999,17: 175-184.
[5] Jonquieres A,Fane A,Filled and unfilled composite GFT PDMS membranes for the recovery of butanols from dilute aqueous solutions: influence of alcohol polarity[J].J Membr Sci,1997,125:245-255.
[6] Xiangli F J,Chen Y W,Jin W Q,et al.,Polydimethylsiloxane (PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures[J].Ind Eng Chem Res,2007,46:2224-2230.
[7] Liu G P,Hou D,Wei W,et al.,Pervaporation separation of butanol-water mixtures using PDMS/ceramic composite membrane[J].Chin J Chem Eng,2011,19(1):1-5.
[8] Huang J C,Meagher M M,Pervaporative recovery of n-butanol from aqueous solutions and ABE fermentation broth using thin-film silicalite-filled silicone composite membranes[J].J Membr Sci,2001,192:231-242.
[9] Zhou H L,Su Y,Chen X R,Modification of silicalite-1 by vinyltrimethoxysilane (VTMS) and preparation of silicalite-1 filled polydimethylsiloxane (PDMS) hybrid pervaporation membranes[J].Sep Purif Technol,2010,75:286-294.
[10] Matsumura M,Takehara S,Kataoka H,Continuous Butanol/isopropanol fermentation in down-flow column reactor coupled with pervaporation using supported liquid membrane[J].Biotechnol Bioeng,1992,39:148-156.
[11] Thongsukmak A,Sirkar K K,Pervaporation membranes highly selective for solvents present in fermentation broths[J].J Membr Sci,2007,302:45-58.
[12] Fadeev A G,Selinskaya Y A,Kelley S S,et al.,Extraction of butanol from aqueous solutions by pervaporation through poly(1-trimethylsilyl-1-propyne)[J].J Membr Sci,2001,186:205-217.
[13] Liu F F,Liu L,Feng X S,Separation of acetone-butanol-ethanol (ABE) from dilute aqueous solutions by pervaporation[J].Sep Purif Technol,2005,42:273-282.
[14] Friedl A,Qureshi N,Maddox I S,Continuous Acetone-Butanol-Ethanol (ABE) fermentation using immobilized cells of Clostridium acetobutylicum in a packed bed reactor and integration with product removal by pervaporation[J].Biotechnol Bioeng,1991,38:518-527.
[15] Vrana D L,Meagher M M,Hutkins R W,et al.,Pervaporation of model acetone-butanol-ethanol fermentation product solutions using polytetrafluoroethylene membranes[J].Sep Purif Technol,1993,28:2167-2178.
[16] Peters T A,Poeth C H S,Benes N E,Ceramic-supported thin PVA pervaporation membranes combining high flux and high selectivity; contradicting the flux-selectivity paradigm[J].J Membr Sci,2006,276:42-50.
[17] Zhu Y X,Xia S S,Liu G P,et al.,Preparation of ceramic-supported poly(vinyl alcohol)-chitosan composite membranes and their applications in pervaporation dehydration of organic/water mixtures[J].J Membr Sci,2010,349:341-348.
[18] Guo W F,Chung T-S,Study and characterization of the hysteresis behavior of polyimide membranes in the thermal cycle process of pervaporation separation[J].J Membr Sci,2005,253:13-22.
[19] Kreiter R,Wolfs D P,Engelen C W R,High-temperature pervaporation performance of ceramic-supported polyimide membranes in the dehydration of alcohols[J].J Membr Sci,2008,319:126-132.
[20] Wang Y,Suat Goha H,Chung T-S,et al.,Polyamide-imide/polyetherimide dual-layer hollow fiber membranes for pervaporation dehydration of C1-C4 alcohols[J]. J Membr Sci,2009,326:222-233.
[21] van Veen H M,van Delft Y C,Engelen C W R,et al.,Dewatering of organics by pervaporation with silica Membranes[J]. Sep Purif Technol,2001,22-23:361-366.
[22] Peters T A,Fontalvo J,Vorstman M A G,et al.,Hollow fibre microporous silica membranes for gas separation and pervaporation Synthesis,performance and stability[J].J Membr Sci,2005,248:73-80.
[23] Castricum H L,Kreiterc R,van Veen H M,et al.,High-performance hybrid pervaporation membranes with superior hydrothermal and acid stability[J].J Membr Sci,2008,324:111-118.
[24] Sommer S,Melin T,Influence of operation parameters on the separation of mixtures by pervaporation and vapor permeation with inorganic membranes. Part 1: Dehydration of solvents[J].Chem Eng Sci,2005,60:4509-4523.
[25] Biduru S,Sridhar S,Murthy G S,et al.,Pervaporation of tertiary butanol/water mixtures through chitosan membranes cross-linked with toluylene diisocyanate[J].J Chem Technol Biotechnol,2005,80:1416-1424.
[26] Kalyani S,Smitha B,Sridhar S,et al.,Blend membranes of sodium alginate and hydroxyethylcellulose for pervaporation-based enrichment of t-butyl alcohol[J].Carbohydr Polym,2006,64:425-432.
[27] Toutianoush A,Krasemann L,Tieke B,Polyelectrolyte multilayer membranes for pervaporation separation of alcohol/water mixtures[J].Colloids Surf A,2002,198-200:881-889.
[28] Zhang G J,Song X,Ji S L,et al.,Self-assembly of inner skin hollow fiber polyelectrolyte multilayer membranes by a dynamic negative pressure layer-by-layer technique[J].J Membr Sci,2008,325:109-116.
[29] Qureshi N,Maddox I S,Friedlt A,Application of continuous substrate feeding to the ABE fermentation: relief of product inhibition using extraction, perstraction, stripping, and pervaporation[J].Biotechnol Prog,1992,8:382-390.
[30] Groot W J,Luyben K C A M,Continuous production of butanol from a glucose/xylose mixture with an immobilized cell system coupled to pervaporation[J].Biotechnol Lett,1987,9:867-870.
[31] Matsumura M,Takehara S,Kataoka H,Continuous butanol/isopropanol fermentation in down-flow column reactor coupled with pervaporation using supported liquid membrane[J].Biotechnol Bioeng,1992,39:148-156.
[32] Qureshi N,Blaschek H P,Production of acetone butanol ethanol (ABE) by a hyper-producing mutant strain of Clostridium beijerinckii BA101 and recovery by pervaporation[J].Biotechnol Prog,1999,15:594-602.
[33] Qureshi N,Meagher M M,Huang J C,et al.,Acetone butanol ethanol (ABE) recovery by pervaporation using silicalite-silicone composite membrane from fed-batch reactor of Clostridium acetobutylicum[J].J Membr Sci,2001,187:93-102.
[34] Qureshi N,Blaschek H P,Fouling studies of a pervaporation membrane with commercial fermentation media and fermentation broth of hyper-butanol-producing Clostridium beijerinckii BA101[J].Sep Sci Technol,1999,34:2803-2815.
[35] Liu G P,Wei W,Wu H,pervaporation performance of PDMS/ceramic composite membrane in Acetone Butanol Ethanol (ABE) fermentation-PV coupled process[J].J Membr Sci,2011,Accept.

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号