Position:Home >> Abstract

Analysis Correlative Factor with Proton leakage During the Process of Bipolar Membrane Electrodialysis
Authors: JIAO Yang1,2, YANG Peng-bo2, CONG Wei2*
Units: 1. The Department of Life Science and Engineering ,Hexi University, Zhangye 734000, Gansu; 2. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
KeyWords: BPM; BMED; Current density; Proton leakage
ClassificationCode:TQ028
year,volume(issue):pagination: 2011,31(6):64-68

Abstract:
Study on the H2SO4 and NaOH are regenerated from Na2SO4 liquor by constant current density during bipolar membrane electrodialysis of three cell (BMED). The process of BMED is experiment by two types of bipolar membranes (BPM) and the same anion exchange membranes, and analysed interaction which are bipolar membrane quality and water flux of acid cell with proton leakage in the regeneration process of acid. The results showed that water flux of acid cell connect with proton leakadge, and resistance of bipolar membrane impact water flux of acid cell, while the extent of proton leakage is decreased with increase of water flux of acid cell, accordingly resistance of bipolar membrane should be less,all of investigation during the same current density. Farther ,it is indicated that the losing water quantity for proton leakage is the part of gross of water leakage of acid cell. Which can give some references for industrial application of BMED.

Funds:
863重点项目课题(2006AA020301)、中科院重要方向性项目(KSCX2-YW-G-020)

AuthorIntro:
焦扬:(1973- ),女(汉),甘肃景泰人,硕士,讲师,生物化工方向。E-mail: yangjiao2808@163. com 。 *为通讯联系人

Reference:
[1] A. J. B.肯佩曼(编),徐铜文,傅荣强(译).双极膜技术手册,[M],化学工业出版社,北京,2004.
[2] R. Audinos, A. Nassr-Allah, J.R. Alvarez, et al. Elelctrodialysis in the separation of dilute aqueous solutions of sulphuric and nitric acids, [J]. Membr. Sci., 76 (1993): 147–156.
[3] T. Cohen, P. Dagard, J. Molenat, et al.Proton leakage through perfluorinated anion-exchange membrane, [J]. Electroanal. Chem., 210(1986) : 329–337.
[4] G. Pourcelly, I. Tugas and C. Gavach. Electrotransportof sulphuric acid in special anion exchange membranes for the recovery of acids, [J]. Membr. Sci., 97 (1994) : 99–107.
[5] I. Raissouni,M. Marraha and A. Azmani.Effect of some parameters on the improvement of the bipolar membrane electrodialysis process,[J].Desalination,208(2007): 62-72.
[6]余立新,宋传真,蒋维钧。双极性膜内水迁移速度与最大电流密度间的关系[J]。膜科学与技术,20(2000):20-22.
[7] Brian J. Robbins, R.W.Field, S. T. Kolaczkowski.Rationalisation of the relationship between proton leakage and weater flux through anion exchange membranes,[J].Membrane Sci.,118(1996): 101-110.
[8] G. Pourcelly, M. Boudet-Dumy, A. Lindheimer, et al. Transport of proton in polymeric ionic exchange membrane in relation with the dissociated sorbed acid,[J]. Desalination 80(1991): 193-209.
[9] I. Tugas, G. Pourcelly and C. Gavach,.Electrotransport of protons and chloride ion in anion exchange membranes for the recovery of acids. Part I. Equilibrium properties. Part II. Kinetics of ion transfer at the membrane-solution interface, [J]. Membrane Sci., 85 (1993): 183-204.
 

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号