Position:Home >> Abstract

Study on the anti-fouling properties of novel five-bore PVDF blend modified membranes
Authors: HUANG Jianping 1,2, SHAO Yumin1, LIU Lili2, MA Chunyan1,*,LIU Na2, XI Danli1,YAN Kelu1
Units: 1. Department of Environmental Science and Engineering, College of Chemistry, Chemical Engineering & Biotechnology, Donghua University, Shanghai 200051, China2. Department of Environmental and Civil Engineering North China University of Water Conservancy & Hydroelectric Power, Zhengzhou 450011, China
KeyWords: five-bore blend membrane; critical flux; filtration experiment; anti-fouling property; surface water treatment
ClassificationCode:TQ
year,volume(issue):pagination: 2012,32(3):64-69

Abstract:
The morphologies for of novel five-bore PVDF blend modified membranes were observed by SEM. The water contact angle and critical fluxes of different novel five-bore PVDF hollow fiber membranes were measured. Then the filtration experiments at sub-critical flux and super-critical flux of No.1(PVDF/PMMA/TPU)blend modified membrane and No.2(PVDF/PMMA/PVC)  blend modified membrane were carried out performed. The results showed that the PVDF blend modified membranes possessed excellent microstructure and the microstructure of No.1 was better. The contact angle of No.1 blend membrane was lower than that of No.2 blend membrane. The critical fluxes of two blend membranes were 10 L/(m2?h) and 14 L/(m2?h), respectively. The anti-fouling property of No.1 blend membrane wasere better than that of No.2 blend membrane. The operating characteristic under sub-critical flux was more stable than that of under super-critical flux. Two blend membranes were used to treat ground-surface water under sub-critical flux and the effects of that with coagulation as pretreatment were studied. The results showed that the wastewater treatment performance of coagulation-ultrafiltration combination process was better than that of ultrafiltration process alone, and the wastewater treatment performance of No.1 blend membrane was better than that of No.2 blend membrane.

Funds:
国家科技重大专项“水体污染控制与治理”(2009ZX07210-002);上海市自然科学基金项目(11ZR1400800)

AuthorIntro:
作者简介:黄健平(1968-),女,河南郑州人,博士,副教授,硕导,主要从事膜材料、水污染控制技术、环境评价等研究。<huangjianpingh@yahoo.cn> * 通讯联系人<machunyan@dhu.edu.cn>

Reference:
[ 1] 贠延滨,刘丽英,马润宇. 聚偏氟乙烯膜的研究进展[J]. 膜科学与技术,2003,23(2):57-61
[2] Nunes SP, Peinemann KV. Ultrafiltration membranes from PVDF/PMMA blends[J]. Journal of Membrane Science, 1992, 73(1): 25-35
[3] Zhou Y, Xi DL. Porous PVDF/TPU blends asymmetric hollow fiber membranes prepared with the use of hydrophilic additive PVP (K30) [J]. Desalination, 2008, 223 (1-3): 438-447
[4] 包艳辉,朱宝库,陈炜,等. 聚偏氟乙烯微孔膜的亲水化改性及功能化研究进展[J]. 功         能高分子学报,2003,16(2):269-274
[5] 唐广军,孙本惠. 聚偏氟乙烯膜的亲水性改性研究进展[J]. 化工进展,2004,23(5):480-485
[6] Liu F, Zhu BK, Xu YY. Improving the hydrophilicity of poly(vinylidene fluoride) porous membranes by electron beam initiated surface grafting of AA/SSS binary monomers[J]. Applied Surface Science, 2006, 253(4): 2096-2101
[7] Ying L, Kang ET, Neoh KG. Covalent immobilization of glucose oxidase on microporous membranes prepared from poly(vinylidene fluoride) with grafted poly(acrylic acid) side chains[J]. Journal of Membrane Science, 2002, 208(1-2): 361-374
[8]  Clech PL, Jefferson B, Chang IS, et al. Critical flux determination by the flux-step method in a submerged membrane bioreactor [J]. Journal of membrane science, 2003, 227(1-2): 81 - 93
[9] Bienati B, Bottino A, Capannelli G, et al. Characterization and performance of different types of hollow fibre membranes in a laboratory-scale MBR for the treatment of industrial wastewater[J]. Desalination, 2008, 231 (1-3): 133–140
[ 0]  郭睿威,赵书英,马小乐,等. 两亲梳型嵌段共聚物的合成及其共混改性聚醚砜超滤膜的抗污染性研究[J]. 膜科学与技术,2008,28(2):27-32
[ 1] 国家环境保护总局水和废水监测分析方法编委会. 水和废水监测分析方法[M]. 第四版. 北京:中国环境科学出版社,2002. 223-226
[ 2] 蒋绍阶,刘宗源. 引用UV254作为水处理中有机物控制指标的意义[J]. 重庆建筑大学学报,2002,24(2):61-65
[ 3] Neal PR, Li H,Fane AG,et al.The effect of filament orientation on critical fIux and particle deposition in spacer filled channels[J].Journal of Membrane Science, 2003, 214(2): 165-178
 

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号