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Effect of draw ratio on the morphology and performance of seven-bore polysulfone hollow fiber membranes during spinning process
Authors: ZHANG Jiemin, ZHAO Baobao, XU Tiancheng, LI Shiwen, FU Zhengang, LI Jianxin*,
Units: State Key Laboratory of Hollow Fiber Membrane Materials and Processes, School of Materials Science and Engineering, Tianjin Polytechnic University, Tianjin 300387, China
KeyWords: Seven-bore hollow fiber membrane; polysulfone (PSf); Draw ratio; Immersion phase precipitation
ClassificationCode:TQ 028.8
year,volume(issue):pagination: 2014,34(6):6-10

Abstract:
Polysulfone(PSf) as a fundamental membrane material,N, N-dimethy lacetamide ( DMAc) as a solvent and polyethylene glycol(PEG) as an additive were used to prepare seven-bore polysulfone hollow fiber membranes via immersion phase precipitation. The effects of draw ratio on the morphologies and performances of PSf hollow fiber membranes were investigated. The results show that the outer diameter of the hollow fiber membrane, the inner diameter of the small bores, the distance between the small bores and the thickness of the dense layer of the small bores decreased with the increase of draw ratio. Meanwhile, the pure water permeation flux increased from 96.5 L/(m2·h) to 131.7 L/(m2·h) with the increase of draw ratio. Besides, BSA rejection, the breaking force and the elongation of the hollow fiber membranes decreased with the increase of draw ratio.

Funds:
科技部国际科技合作项目(2010DF51090)

AuthorIntro:
张洁敏(1989-),女,山东青州市人,硕士研究生,主要从事中空纤维膜制备。

Reference:
[1] Ghosh S, Bhattacharya P, Majumdar S, et al. Comparative study on treatment of kitchen-sink wastewater using single and multichannel ceramic membrane[J]. International Journal of Environmental Technology and Management, 2010, 13(3): 336~347.
[2] Gille D, Czolkoss W. Ultrafiltration with multi-bore membranes as seawater pre-treatment[J]. Desalination, 2005, 182(1): 301~307.
[3] Kesting R E, Fritzsche A K. Polymeric gas separation membranes[M]. New York: Wiley, 1993.
[4] Liu Y, Koops G H, Strathmann H. Characterization of morphology controlled polyethersulfone hollow fiber membranes by the addition of polyethylene glycol to the dope and bore liquid solution[J]. Journal of membrane science, 2003, 223(1): 187~199.
[5] Ren J Z, Chung T S, Li D, et al. Development of asymmetric 6FDA-2, 6 DAT hollow fiber membranes for CO2/CH 4 separation: 1. The influence of dope composition and rheology on membrane morphology and separation performance[J]. Journal of membrane science, 2002, 207(2): 227~240.
[6] Kim J H, Min B R, Won J, et al. Phase behavior and mechanism of membrane formation for polyimide/DMSO/water system[J]. Journal of Membrane Science, 2001, 187(1): 47~55.
[7] Lin K Y, Wang D M, Lai J Y. Nonsolvent-induced gelation and its effect on membrane morphology[J]. Macromolecules, 2002, 35(17): 6697~6706.
[8] Tsai H A, Li L D, Lee K R, et al. Effect of surfactant addition on the morphology and pervaporation performance of asymmetric polysulfone membranes[J]. Journal of Membrane Science, 2000, 176(1): 97~103.
[9] Nakajima T, Kajiwara K, McIntyre JE. Advanced fiber spinning technology[M]. Woodhead Pub Limited, 1994, (Chapter 2).
[10] Wangxi Z, Jie L, Gang W. Evolution of structure and properties of PAN precursors during their conversion to carbon fibers[J]. Carbon, 2003, 41(14): 2805~2812.
[11] Wang K Y, Fei Li D, Chung T S, et al. The observation of elongation dependent macrovoid evolution in single-and dual-layer asymmetric hollow fiber membranes[J]. Chemical engineering science, 2004, 59(21): 4657~4660.
[12] Chou W L, Yang M C. Effect of take-up speed on physical properties and permeation performance of cellulose acetate hollow fibers[J]. Journal of membrane science, 2005, 250(1): 259~267.
[13] Yu D G, Chou W L, Yang M C. Effect of draw ratio and coagulant composition on polyacrylonitrile hollow fiber membranes[J]. Separation and purification technology, 2006, 52(2): 380~387.
[14] 徐天成,张洁敏,付振刚等.聚合物多通道中空纤维膜研究进展. [J] .膜科学与技术,2013,33(5).
[15] 陈颖,李雪梅,李晓明.聚丙烯中空纤维膜拉伸性能测试方法试验研究. [J] .膜科学与技术,2010,30(4):65~68.
[16] Heijnen M, Winkler R, Berg P. Optimisation of the geometry of a polymeric Multibore® ultrafiltration membrane and its operational advantages over standard single bore fibres[J]. Desalination and Water Treatment, 2012, 42(1-3): 24~29.
[17] [16] Cao C, Chung T S, Chen S B, et al. The study of elongation and shear rates in spinning process and its effect on gas separation performance of poly (ether sulfone)(PES) hollow fiber membranes[J]. Chemical engineering science, 2004, 59(5): 1053~1062.
 

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