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Preparation of superhydrophobic organic-inorganic composite membrane based on the bionic mechanism
Authors: HAN Peng, JIANG Chudong, ZHOU Yingying, SUN Haixiang, LUAN Yange
Units: Department of Material Physics and Chemistry, College of Science, China University of Petroleum (East China), Qingdao 266580, China
KeyWords: Super-hydrophobic membrane; Nano-silica; Silane coupling; Composite membrane
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2015,35(2):25-29

Abstract:
Organic-inorganic composite microporous membrane was fabricated by phase inversion after PVDF mixed with modified SiO2 according to a weight ratio, in which SiO2 prepared by sol-gel method was modified by low-surface-energy silane coupling agent. The impact of coupling agent types and SiO2 particles size on the hydrophobicity of the microporous film and the microtopography of the film were investigated. Results indicated that the gelation of SiO2 particles were effectively prevented by silane coupling agent with surface energy of SiO2 particles reduced, which had a significant impact on hydrophobicity of membrane; the water contact angle of the composite microporous membrane surfaces with a nicer micro-nano hierarchical structure was up to 151°.

Funds:
中央高校基本科研业务费专项资金资助(14CX05034A);国家级大学生创新实验(201210425064)

AuthorIntro:
韩鹏(1992-),男,山东济南人,本科生,主要从事高分子膜分离研究。

Reference:
[1] Cassie A B D, Baxter S. Wettability of porous surfaces [J]. Trans Faraday Soc, 1944, 40: 546-551.
[2] Hou X, Jiang L. Learning from nature: building bio-inspired smart nanochannels [J]. ACS Nano, 2009, 11: 3339-3342.
[3] Bhushan B, Jung Y C, Koch K. Self- cleaning efficiency of artificial superhydro- phobic surfaces [J]. Langmuir, 2009, 25: 3240-3248.
[4] 王庐岩, 钱英, 刘淑秀, 等. 聚偏氟乙烯分离膜改性研究进展[J]. 膜科学与技术,2002, 22(5): 52-57.
[5] Bhushan B, Ling X. Integrating elec -trowetting into micromanipulation of liquid droplets [J]. J Phys Condens Matter  2008, 20: 1-10.
[6] Nosonovsky M, Bhushan B. Superhydro- phobicity for energy conversion and nservation applications [J]., J Adhes Sci Technol 2008, 22: 2105-2115.
[7] Öner D, Mccarthy T J. Ultrahydrophobic surfaces: Effects of topography length scales on wettability [J]. Langmuir 2000, 16: 7777-7782.
[8] Liu H, Feng L, Zhai J, et al. Reversible wettability of a chemical vapor deposition prepared ZnO film between superhydrophobicity and superhydrophilicity [J]. Langmuir 2004 20: 5659-5661.
[9] Neinhuis C, Barthlott W. Characte- rization and distribution of water-repellent, self-cleaning plant surfaces [J]. Ann Bot 1997, 79: 667-677.
[10] 张裕卿, 张红柳, 曲云, 等. 填充纳米SiO2 对聚偏氟乙烯膜性能的影响 [J].膜科学与技术, 2007,27 (6): 47-51.
[11] Sethupathy M, Sethuraman V, Manisanker P. Preparation of PVDF/SiO2 Composite Nanofiber Membrane Using Electrospinning for Polymer Electrolyte Analysis[J]. Soft Nanoscience Letters, 2013, 3, 37-43.
[12] 张华峰, 张玉忠, 林立刚, 等. PVDF膜的制备与疏水性研究[C]. 第四届中国膜科学与技术报告会论文集. 中国北京: 《膜科学与技术》编辑部, 2010. 240-242.

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