Position:Home >> Abstract

Graphene Oxide: Challenges and Opportunities for Membrane Science
Authors: LI Fang   MENG Die
Units: (1 College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China; 2 State Environmental Protection Engineering Center for pollution Treatment and Control in textile Industry, Shanghai 201620, China
KeyWords: GO; membrane filtration;separation mechanism;molecular size sieving
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2015,35(6):106-112

Abstract:
 Due to its special structure, graphene oxide (GO) exhibits superior properties, such as flexibility, chemical stability and mechanical strength. The membranes prepared by GO sheets show an unique separation performance. According to recent research reports, the basic separation mechanism of GO membranes is molecular sieving of size exclusion, and the separation efficiency is influenced by the other factors. Based on the principle of molecular size sieving, GO membranes present more prominent advantages in size tunability which can be realized by changing the interlayer size via vacuum filtration or self-assembling. Meanwhile, GO can improve the permeability and antifouling performance of organic membranes by blending GO nanosheets with macromolecular polymers. In conclusion, GO provides challenges and opportunities for the development of membrane science.
 

Funds:

AuthorIntro:

Reference:
 [1] Freeman B D.Polymer membranes for water purification[J].Abstr.Papers Am.Chem.Soc, 2013, 246: 359-362.
[2] Zhao S F, Zou, L C, Tang Y, et al.Recent developments in forward osmosis: Opportunities and challenges[J]. J Membr Sci, 2012, 396: 1-21.
[3] 付乐乐, 李方, 吴亮, 等. 超滤膜深度处理染整废水的膜污染机理[J].环境工程学报, 2013, 3: 1313-1318.
[4] Cai Z, Wee C, Benjamin M M.Fouling mechanisms in low-pressure membrane filtration in the presence of an adsorbent cake layer [J].J Membr Sci, 2013, 433: 32-38.
[5] Shao L, Wang Z X, Zhang Y L, et al.A facile strategy to enhance PVDF ultrafiltration membrane performance via self-polymerized polydopamine followed by hydrolysis of ammonium fluotitanate[J].J Membr Sci, 2014, 461: 10-21.
[6] Gullinkala T, Escobar I.Study of the hydrophilic-enhanced ultrafiltration membrane[J].Environ Prog, 2008, 27: 210-217.
[7] Huang H, Ying Y, Peng X.Graphene oxide nanosheet: an emerging star material for novel separation membranes[J].J.Mater.Chem., 2014, 2: 13772-13782.
[8] Dreyer D R, Park S, Bielawski C W, et al. The chemistry of graphene oxide[J]. Chem Soc Rev , 2010, 39(1): 228-240.
[9] Li D, Mueller M B, Gilje S, et al.Processable aqueous dispersions of graphene nanosheets[J].Nat.Nanotech., 2008, 3(2): 101-105.
[10] Huang H B, Mao Y Y, Ying Y L, et al.Salt concentration, pH and pressure controlled separation of small molecules through lamellar graphene oxide membranes[J].Chem Commun, 2013, 49(53): 5963-5965.
[11] Smith Z P, Freeman B D.Graphene oxide: a new platform for high-performance gas and liquid-separation membranes[J].Angew.Chem , 2014, 53: 10286-10288.
[12] Qiu L, Zhang X H, Yang W R, et al.Controllable corrugation of chemically converted graphene sheets in water and potential application for nanofiltration[J].Chem Commun, 2011,47(20): 5810-5812.
[13] Wang X L, Bai H, Shi G Q.Size fractionation of graphene oxide sheets by pH-assisted selective sedimentation[J].J Am Chem Soc, 2011,133(16): 6338-6342.
[14] Zhao J, Wang Z, White J C, et al.Graphene in the Aquatic Environment: Adsorption, Dispersion, Toxicity and Transformation[J]. Environ Sci & Technol, 2014, 48: 9995-10009.
[15] Zhu Y, Murali S, Cai W, et al.Graphene and Graphene Oxide: Synthesis, Properties, and Applications[J].Adv.Mater., 2010, 22: 3906-3924.
[16] Cote L J, Kim F, Huang J X.Langmuir- Blodgett assembly of graphite oxide single layers[J].J Am Chem Soc, 2008, 131(3): 1043-1049.
[17] Pham V H, Cuong T V, Hur S H, et al.Fast simple fabrication of a large transparent chemically-converted graphene film by spray-coating[J].Carbon, 2010,48(7): 1945-1951.
[18]杨永清,齐署华,张翼,等.石墨及其改性产物研究进展[J].材料导报,2011,25(15):53-57
[19] Berry V.Impermeability of graphene and its applications[J].Carbon, 2013, 62: 1-10.
[20] Koenig S P, Wang L, Pellegrino J, et al.Selective molecular sieving through porous graphene[J].Nat.Nanotech., 2012, 7: 728-732.
[21]王蓓娣, GO的功能化改性及应用研究[C].上海:复旦大学,2012.
[22] Wei N, Peng X, Xu Z.Understanding Water Permeation in Graphene Oxide Membranes[J]. Acs Appl Mater & Inter, 2014, 6(8): 5877-5883.
[23] Li H, Song Z N, Zhang X J,et al.Ultrathin, Molecular-Sieving Graphene Oxide Membranes for Selective Hydrogen Separation[J]. Science, 2013, 342(6154): 95-98.
[24]Shao L, Chen X Q, Wang Z X, et al.Tuning the performance of polypyrrole-based solvent-resistant composite nanofiltration membranes by optimizing polymerization conditions and incorporating graphene oxide[J].J Membr Sci, 2014, 452: 82-89.
[25]Nicolai A, Sumpter B G, Meunier V.Tunable water desalination across graphene oxide framework membranes[J]. Phy Chem Chem Phy, 2014, 16(18): 8646-8654.
[26]唐秀之, GO表面功能化修饰[C].北京:北京化工大学, 2012.
[27] Joshi R K, Carbone P, Wang F C, et al.Precise and Ultrafast Molecular Sieving Through Graphene Oxide Membranes[J].Science, 2014, 343: 752-754.
[28] Nair R R, Wu H A, Jayaram P N, et al.Unimpeded Permeation of Water Through Helium-Leak-Tight Graphene-Based Membranes[J].Science, 2012, 335: 442-444.
[29] Huang H B, Ying Y L, Peng X S.Graphene oxide nanosheet: an emerging star material for novel separation membranes[J].J Mater Chem, 2014 , 2: 13772-13782.
[30] Kim H W, Yoon H W, Yoon S M, et al.Selective Gas Transport Through Few-Layered Graphene and Graphene Oxide Membranes[J].Science, 2013, 342: 91-95.
[31] Wei N, Peng X, Xu Z. Understanding Water Permeation in Graphene Oxide Membranes[J].Acs Appl Mater & Inter, 2014, 6: 5877-5883.
[32]Richard W.Baker. Membrane technology and applications[M].second edition. California: Menlo Park,2003.
[33] Zhang J G, Xu Z W, Shan M J, et al.Synergetic effects of oxidized carbon nanotubes and graphene oxide on fouling control and anti-fouling mechanism of polyvinylidene fluoride ultrafiltration membranes[J].J Membr Sci, 2013, 448(0): 81-92.
[34] Athanasekou C P, Morales-Torres S, Likodimos V, et al.Prototype composite membranes of partially reduced graphene oxide/TiO2 for photocatalytic ultrafiltration water treatment under visible light[J].Appl Catal B-Environ, 2014,158: 361-372.
[35] Mohammad-Rezaei R, Razmi H, Dehgan-Reyhan S.Preparation of graphene oxide doped eggshell membrane bioplatform modified Prussian blue nanoparticles as a sensitive hydrogen peroxide sensor[J].Colloid Surface B, 2014,118: 188-193.
[36] 邵路, 程喜全.一种石墨烯/聚吡咯复合正渗透膜的制备方法[P].中国,发明, CN103301758A.2013.05.20.
[37] Liu R, Arabale G, Kim J, et al.Graphene oxide membrane for liquid phase organic molecular separation[J].Carbon, 2014.77: 933-938.
[38] Mi B.Graphene Oxide Membranes for Ionic and Molecular Sieving[J].Science, 2014, 343: 740-742.
[39] Ganesh B M, Isloor A M, Ismail A F.Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane[J].Desalination, 2013, 313: 199-207.
[40] 黄虎彪.GO超滤分离膜[C].浙江:浙江大学,2014.
[41] Hu M, Mi B. Enabling Graphene Oxide Nanosheets as Water Separation Membranes[J].Environ Sci & Technol, 2013,47: 3715-3723.
[42] An Z, Compton O C, Putz K W, et al.Bio-Inspired Borate Cross-Linking in Ultra-Stiff Graphene Oxide Thin Films[J].Adv.Mater, 2011, 23: 3842-3846.
[43] Xu Z, Zhang J, Shan M, et al.Organosilane-functionalized graphene oxide for enhanced antifouling and mechanical properties of polyvinylidene fluoride ultrafiltration membranes[J].J Membr Sci,2014, 458: 1-13.
[44] Zinadini S, Zinatizadeh A A, Rahimi M, et al.Preparation of a novel antifouling mixed matrix PES membrane by embedding graphene oxide nanoplates[J].J Membr Sci, 2014, 453: 292-301.
[45] Shao L, Cheng X, Wang Z, et al.Tuning the performance of polypyrrole-based solvent-resistant composite nanofiltration membranes by optimizing polymerization conditions and incorporating graphene oxide[J].J Membr Sci, 2014 ,452: 82-89.
[46] Zhang J, Xu Z, Shan M, et al.Synergetic effects of oxidized carbon nanotubes and graphene oxide on fouling control and anti-fouling mechanism of polyvinylidene fluoride ultrafiltration membranes[J].J Membr Sci, 2013, 448: 81-92.
[47] Gao P, Liu Z, Tai M, et al.Multifunctional graphene oxide–TiO2 microsphere hierarchical membrane for clean water production[J].Appl Catal B-Environ, 2013,138: 17-25.
 

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号