膜科学与技术

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Preparation and application of thiol-functionalized membrane

Authors： LIU Lanfang, LUO Jianquan, WAN Yinhua, CHEN Xiangrong, WU Yuanpeng

Units： State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, School of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China

KeyWords： polydopamine; poly (ethylene imine); L-cysteine; functionalized membrane; patulin

ClassificationCode：TQ316.6

year,volume(issue):pagination： 2019,39(3):14-21

Abstract：

Patulin is a toxic fungal secondary metabolite, and it can cause a serious threat to human and animals’ healthy. In this paper, nylon membrane was used as the matrix material, polydopamine (PDA) coating was firstly deposited onto the surface of membrane. poly (ethylene imine) (PEI) was grafted onto the surface of membrane through the strong adhesion of PDA layer. Thiol-functionalized membrane was fabricated by thiolation modification for efficient removal of patulin. The effects of membrane preparation parameters, such as membrane pore size, PEI molecule and thiolation reaction conditions on membrane morphology and properties were studied. The results showed that thiol-functionalized membrane could be fabricated successfully by dopamine biomimetic modification. Compared with the pristine membrane, the maximum pore size of thiol-functionalized membrane was slightly decreased, water flux and contact angle were increased obviously. In the dynamic filtration tests, The adsorption efficiency of patulin was raised significantly with the temperature increasing. The adsorption efficiency of patulin was 92.9% at 60 °C.

Funds：

国家重点研究发展计划（2017YFC1600906）; 河北省衡水科技成果转化发展基金；中国工程院咨询项目（2017-XZ-08-01-03）

AuthorIntro：

刘兰芳（1991-），女，河南周口人，硕士生，从事功能膜材料的制备与应用，E-mail: liulanfang421@163.com 通讯作者，陈向荣，E-mail：xrchen@ipe.ac.cn 武元鹏，E-mail：ypwu@swpu.edu.cn

Reference：

[1] 李庆鹏, 靳婧, 崔文慧,等. 欧盟RASFF通报我国食品及饲料类违例信息及趋势分析(2002至2012年)[J]. 食品安全质量检测学报, 2014, 5(04): 1228-34.
[2] Moake M M, Padilla-Zakour O I, Worobo R W. Comprehensive review of patulin control methods in foods[J]. Compr Rev Food Sci Food Saf, 2005, 4: 8-21.
[3] Organization W H. Evaluation of Certain Food Additives and Contaminants: Eightieth Report of the Joint FAO/WHO Expert Committee on Food Additives[J]. World Health Organ Tech Rep Ser, 2016, 995: 1-114.
[4] K.S.McKenzie, A.B.Sarr, K.Mayura,et al. Oxidative Degradation and Detoxification of Mycotoxins Using a Novel Source of Ozone[J]. Food Chem Toxicol, 1997, 35: 807-20.
[5] Appell M, Jackson M A, Dombrink-Kurtzman M A. Removal of patulin from aqueous solutions by propylthiol functionalized SBA-15[J]. J Hazard Mater, 2011, 187(1-3): 150-6.
[6] Zhu R, Feussner K, Wu T,et al. Detoxification of mycotoxin patulin by the yeast Rhodosporidium paludigenum[J]. Food Chem, 2015, 179: 1-5.
[7] Hatab S, Yue T, Mohamad O. Removal of patulin from apple juice using inactivated lactic acid bacteria[J]. J Appl Microbiol, 2012, 112(5): 892-9.
[8] Assatarakul K, Churey J J, Manns D C,et al. Patulin reduction in apple juice from concentrate by UV radiation and comparison of kinetic degradation models between apple juice and apple cider[J]. J Food Prot, 2012, 75(4): 717-24.
[9] Luo Y, Zhou Z, Yue T. Synthesis and characterization of nontoxic chitosan-coated Fe3O4 particles for patulin adsorption in a juice-pH simulation aqueous[J]. Food Chemistry, 2017, 221: 317-23.
[10] 高振鹏, 岳田利, 袁亚宏,等. 苹果汁中展青霉素的超声波降解[J]. 农业机械学报, 2009, 40(09): 138-42.
[11] J. BISSESSUR K P, AND B. ODHAV*. Reduction of Patulin during Apple Juice Clarication[J]. Journal of Food Protection, 2001:
[12] Taydas J A V G E E. The effects of processing technology on the patulin content of juice[J]. ORIGINAL PAPER, 1998:
[13] Gökmen V, Art?k N, Acar J,et al. Effects of various clarification treatments on patulin, phenolic compound and organic acid compositions of apple juice[J]. European Food Research and Technology, 2001, 213(3): 194-9.
[14] Cao X, Luo J, Woodley J M,et al. Mussel-inspired co-deposition to enhance bisphenol A removal in a bifacial enzymatic membrane reactor[J]. Chem Eng J 2018, 336: 315-24.
[15] Song Y, Ye G, Wu F,et al. Bioinspired Polydopamine (PDA) Chemistry Meets Ordered Mesoporous Carbons (OMCs): A Benign Surface Modification Strategy for Versatile Functionalization[J]. Chem Mater, 2016, 28(14): 5013-21.
[16] Lv Y, Yang H-C, Liang H-Q,et al. Nanofiltration membranes via co-deposition of polydopamine/polyethylenimine followed by cross-linking[J]. Journal of Membrane Science, 2015, 476: 50-8.
[17] Iqbal J, Shahnaz G, Dunnhaupt S,et al. Preactivated thiomers as mucoadhesive polymers for drug delivery[J]. Biomaterials, 2012, 33(5): 1528-35.
[18] Constantia E. Kast A B-S. Thiolated polymers _ thiomers_ development and in vitro evaluation of chitosan-thioglycolic acid conjugates[J]. Biomaterials 2001:
[19] Cai T, Li M, Neoh K-G,et al. Preparation of stimuli responsive polycaprolactone membranes of controllable porous morphology via combined atom transfer radical polymerization, ring-opening polymerization and thiol–yne click chemistry[J]. Journal of Materials Chemistry, 2012, 22(32): 16248.
[20] Capozzi L C, Mehmood F M, Giagnorio M,et al. Ultrafiltration Membranes Functionalized with Polydopamine with Enhanced Contaminant Removal by Adsorption[J]. Macromolecular Materials and Engineering, 2017, 302(5): 1600481.
[21] Liu B, Peng X, Chen W,et al. Adsorptive removal of patulin from aqueous solution using thiourea modified chitosan resin[J]. Int J Biol Macromol, 2015, 80: 520-8.
[22] 王杰, 陈明, 李梅生,等. 聚乙烯醇/聚多巴胺-氮化碳渗透汽化复合膜的制备[J]. 膜科学与技术, 2018, 38(02): 37-44.

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