盐浓度对陶瓷膜过滤过程的影响
作者:张荟钦 顾俊杰 李卫星 邢卫红
单位: 南京工业大学膜科学技术研究所,材料化学工程国家重点实验室,江苏 南京210009
关键词: 陶瓷膜;无机盐; 膜过程
出版年,卷(期):页码: 2010,1(6):0-0

摘要:
摘要:陶瓷膜应用过程中常涉及到含盐体系,盐浓度对过滤过程影响显著。本文考察不同温度下,不同浓度氯化钠水溶液的陶瓷膜过滤过程。实验结果表明盐浓度对膜渗透通量影响明显,不同孔径的陶瓷膜过滤通量与盐浓度的变化关系相同;将氯化钠溶液黏度随温度和浓度的经验关系式引入Darcy方程中,计算结果表明,盐溶液的黏度是影响膜渗透通量的主要原因,计算值与实验值吻合较好,误差在10%以内。
Abstract: The ceramic membrane process often involves salt-bearing system, which is effected significantly by the salt concentration. The ceramic membrane filtration process of sodium chloride aqueous solution with different concentrations under different temperatures is studied. Experimental results show that the effect of salt concentration on the membrane flux is very significant; the correlation of flux with salt concentration is the same for ceramic membranes with different pore size. The empirical formula of viscosity of the sodium chloride solution on temperature and concentration was introduced to the Darcy law, the calculated results show that the main reason of the influence on membrane flux is salt solution viscosity, the predicted values fit the experimental values well, with an error in 10%.
作者介绍:张荟钦(1984-),男,,硕士生,新疆和田市人,研究方向:膜分离,Email:whzhanghuiqin@163.com。通讯联系人:邢卫红,电话025-83172288,Email:xingwh@njut.edu.cn。

参考文献:
[1] Elzo D , Huisman I, Middelink E, ,et al. Charge effects on inorganic membrane performance in a cross-flow microfiltration process.[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects . 1998,138:145~159
[2] Zhao Y, Xing W,  Xu N,,et al. Effects of inorganic salt on ceramic membrane microfiltration of titanium dioxide suspension.[J]. Journal of Membrane Science. 2005,254:81~88
[3] Emilio J, Casa D, Guadix A., et al.Guadix, et al. Influence of pH and salt concentration on the cross-flow microfiltration of BSA through a ceramic membrane.[J]. Biochemical Engineering Journal . 2007,33: 110~115
[4] Singh G, Song L.. Experimental correlations of pH and ionic strength effects on the colloidal fouling potential of silica nanoparticles in crossflow ultrafiltration.[J]. Journal of Membrane Science. 2007,303:112~118
[5] Narong P, James A.. Sodium chloride rejection by a UF ceramic membrane in relation to its surface electrical properties.[J]. Separation and Purification Technology . 2006 ,49:122~129
[6] 时钧,汪家鼎,余国琮,陈敏恒.化学工程手册[M].北京:化学工业出版社,1996
[7] HuismanH , Dutrk B, Persson, K et al.Water permeability in ultrafiltration and microfiltration: Viscous and electroviscous effects.[J]. Desalination. 1997, 113: 95~103.
[8] Vladisavljevi G, Vukosavljevi P, Bukvi B,et al.Permeate flux and fouling resistance in ultrafiltration of depectinized apple juice using ceramic membranes. [J].  Journal of Food Engineering. 2003 , 60:241~247.
[9] Wang B, Wei T, Yu Z, et al.Effect of operating temperature on component distribution of West Indian cherry juice in a microfiltration system. [J].LWT-Food science and technology. 2005, 38: 683~689
[10] Bernata X , Fortunyb A , Stübera F, et al A Fabregata, J Fonta, et al. Recovery of iron (III) from aqueous streams by ultrafiltration. [J]. Desalination. 2008, 221:413~418

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号