膜科学与技术

基于促进传递机理的烯烃/烷烃分离用固体聚合物电解质膜的研究进展

作者：王雁北，任吉中?，李晖，邓麦村

单位：中国科学院大连化学物理研究所膜技术国家工程研究中心,大连116023

关键词：烯烃/烷烃分离; 促进传递; 固体聚合物电解质; 载体中毒

出版年,卷(期):页码： 2012,32(3):104-111

摘要：

对膜法烯烃/烷烃分离技术的现状进行了总结，论述了膜法促进传递分离烯烃/烷烃的机理、研究进展及存在的问题。分析了固体聚合物电解质膜对烯烃/烷烃分离性能的影响因素，探讨了固体聚合物电解质中高分子材料和烯烃载体对膜性能的影响，阐述了烯烃载体Ag+的中毒及再生过程和烯烃渗透的时间依赖性。

The research status of solid polymer electrolyte membranes for olefin/paraffin separation is reviewed. The olefin/paraffin separation mechanism, research progress and current problems of facilitated transport membrane are described clearly. The influence of solid polymer electrolyte membrane on the performance of olefin/paraffin separation is analyzed, the polymeric membrane materials and olefin carriers for solid polymer electrolyte membranes are also discussed. Finally, the poisoning/regeneration mechanisms of carrier sliver salt and the olefin time-dependent permeation are also discussed.

王雁北（1983-），女，天津，博士，从事膜分离过程研究.?通讯联系人, renjizhong@dicp.ac.cn

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