膜科学与技术

乳液涂敷制备硅橡胶富氧膜

作者：安坤，范红玮，董亚军，彭跃莲

单位：北京工业大学环境与能源工程学院化学化工系膜技术中心，北京100124

关键词：富氧膜；硅橡胶；乳液涂敷；环保

出版年,卷(期):页码： 2013,33(3):54-58

摘要：

从空气中分离和富集氧气的富氧膜是一类重要的气体分离膜。本实验将制备聚二甲基硅氧烷/聚砜（PDMS/PS）富氧膜，并考察其富氧性能，分别制备了溶剂型羟基硅橡胶富氧膜和乳液型羟基硅橡胶富氧膜，评价其渗透速率Q和分离系数α(O2/ N2)，得出了二者在性能上的差异，发现溶剂型富氧膜渗透速率Q(O2)是乳液型富氧膜Q(O2)的3-4倍，而乳液型富氧膜α(O2/ N2)比溶剂型富氧膜略好，并且以水代替有机溶剂，采用硅橡胶水乳液作为涂敷材料进行乳液涂敷，制备的乳液型富氧膜相对于传统的溶剂型富氧膜，具有环保、安全和经济等特点。该方法制备的富氧膜同时也具有较好的富氧效果，其氧气渗透速率Q(O2)在113GPU左右，分离系数α(O2/ N2)能达到2.0。

The membrane used in air separation and oxygen enrichment is an important class of gas separation membranes. In this study, silicone rubber/polysulfone (PDMS/PS) composite membranes were prepared; the silicone rubbers included solvent-based hydroxyl silicon rubber and emulsion hydroxyl silicon rubber. The prepared composite membranes were evaluated by the permeation rate and separation factor. The results showed that the permeation rate of solvent-based silicon rubber/polysulfone membrane was 3-4 times more than that of emulsion silicon rubber/polysulfone membrane, but the latter had a little better separation factor than the former. The oxygen permeation rate Q(O2) and separation factor α (O2 N2) was 113 GPU and 2.00, respectively. This latex coating method, coating emulsion hydroxyl silicon rubber on the support, was not only environment-friendly, but also safe and economic.

安坤（1985-），男，山东省德州市人，主要研究方向为膜科学与技术*通讯联系人，彭跃莲（1969—），女，湖北人，近年的主要研究方向为膜蒸馏用膜及过程，联系电话：010-67391090，Email: pyl@ bjut.edu.cn。

参考文献：

[1] Stern S A. Polymers for gas separations: The next decade [J]. J Membr Sci,1994,94:1-65.
[2] 沈光林.膜法富氧技术的研究与应用[J ].现代节能,1998,14(5):4-7.
[3] Ma. Eulalia Vanegas. Syndiotactic poilpropylene copolymer membrane and their performance for oxygen separation[J ].Journal of Membrane Science,2010,348:34-40.
[4] L．Hu, X. Zhang, J. Niu, X. Wang, Structures and properties of modified ethylcellulose oxygen-enrich membranes[J ].Appl. Polym. Sci. 65 (1997) 1837-1841
[5] M. W. Hellums, W. J. Koros, G. R. Husk, D. R. Paul, Gas transport in halogen containing aromatic polycarbonates[J ]. Appl. Polym. Sci. 43(1991) 1997-1986.
[6] G. Xu, X. Sun, X. Qiu, J. Zhang, G. Zheng, XPS studies on surface modified poly[1-(trimethylsilyl)-1-propyne] membranes II surface modification by bromine vapor, Chinese J. Polym.Sci.12(1994)180-184.
[7] S.P. Nunes, K.V. Peinemann, Membrane Technology in the Chemical Industry, Second Revised and Extended Edition, Wiley-VCH, 2006.
[8] 孙余凭. 掺杂二氧化硅的硅橡胶富氧膜及其制备方法[P ].中国专利:200710131769.7,2007
-08-29.
[9] T. Aoki, Macromolecular design of permselective membranes, Prog. Polym. Sca.24 (1999) 951
[10] Zi-Yong Zhang, Hua-Xin Rao, Fan-Na Liu. Preparation and oxygen/nitrogen permeability of PDMS crosslinked membrane and PDMS / tetraethoxysilicone hybrid membrane. Journal of Membrane Science,2007,303:132-139.
[11] Zi-Yong Zhang, Facilitated oxygen transport in a novel silicone polymer membrane containing carboxylic cobalt groups, J. Appl. Polym. Sci. 90 (2003) 1038.
[12] 郭勇,华曼等.硅橡胶-聚砜中空纤维复合膜的制备及性能研究[J ].膜科学与技术,2002,22(5):58-60.
[13] P. Pandey, R. S.Chauhan, P reparation of gas separation membranes and their evaluation, Defen. Sci. [J ].54(2004)335-343
[14] 刘光仙。孙晓然. 富氧膜技术的进展[J ] 化学工程师,2006,135(12):33-37.
[15] 李宁,贺高红等.硅橡胶-聚碳酸酯富氧膜的制备[J ].膜科学与技术,2009,29(2):56-59.
[16] 李宁.基膜对硅橡胶复合膜富氧性能的影响研究[D ].大连:大连理工大学,2008.
[17] 张阳,王湛等.聚砜-硅橡胶富氧膜的制备[J ].膜科学与技术,2007,27 (3):53-56.
[18] 张志庆,徐桂英,叶繁等.十二烷基甜菜碱/十二烷基硫酸钠复配体系的表面活性[J ].物理化学学报,2001,17(12):1122-1125.

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