膜科学与技术

TiO2溶胶杂化改性PPESK超滤膜的制备及性能研究

作者：赵姗姗，王鹏，张林欢，孙欣

单位：哈尔滨工业大学市政环境工程学院，哈尔滨 150090

关键词：聚醚砜酮；TiO2；溶胶-凝胶；亲水性；高温凝结水

出版年,卷(期):页码： 2013,33(4):47-52

摘要：

采用溶胶-凝胶法制备TiO2溶胶，优化了溶胶制备条件。采用相转化法制备了一系列TiO2含量的PPESK/TiO2有机-无机杂化超滤膜，并通过SEM，水接触角和超滤实验考察了TiO2含量对膜结构和性能的影响。结果表明，冰乙酸、去离子水和NMP用量分别为2 mL, 2 mL和20 mL时，溶胶胶凝时间为42.5 h，利于杂化膜的制备。TiO2溶胶的加入，抑制了亚层指状孔的发展，利于海绵状孔的生成。膜的孔隙率，亲水性和抗污染性得到了明显改善。当TiO2含量为0.4 %时，膜的纯水通量由310 L•m-2•h-1提高到427 L•m-2•h-1，清洗后，膜通量恢复率为95.2 %。但加入过量的TiO2溶胶时，纳米粒子的团聚使得杂化膜的各项性能下降。PPESK/TiO2杂化膜更适于高温凝结水的回用处理，处理效率高。

TiO2 sol was prepared using sol-gel method and the reaction conditions were optimized. PPESK/TiO2 organic-inorganic hybrid ultrafiltration (UF) membranes with different TiO2 concentrations were prepared by phase inversion method. The effects of TiO2 concentration on the morphologies and properties were investigated through SEM, water contact angle and UF experiments. The results showed that the optimal reaction conditions for TiO2 sol preparation were acetic acid 2 mL, deionized water 2 mL and NMP 20 mL. Under the conditions, the gelation time was 42.5 h. The penetrated finger-like pore structure in sublayer was suppressed, and sponge-like structure began to be developed. The porosity, hydrophilicity and anti-fouling properties have been obviously improved. When TiO2 concentration was 0.4 %, the pure water flux was increased from 310 L•m-2•h-1 to 427 L•m-2•h-1, and the flux recovery rate of membrane was 95.2 %. However, excess TiO2 concentration caused the aggregation of nanoparticles resulting in the performance decline. Compared with PPESK membrane, the PPESK/TiO2 organic-inorganic hybrid UF membrane was better for the purification of high temperature condensed water, showing higher removal efficiency.

赵姗姗（1983- ），女，河北唐山人，博士研究生，超滤和纳滤膜制备及应用。通讯作者：pwang73@hit.edu.cn

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