纳滤预处理反渗透海水淡化研究进展
作者:周栋12,傅寅翼1,朱丽静1,郭志毅3,刘富1,薛立新1
单位: 1.中国科学院宁波材料技术与工程研究所,浙江省宁波市中官西路1219号,315201;
关键词: 纳滤;反渗透;海水淡化
分类号:
出版年,卷(期):页码: 2015,35(3):106-112

摘要:
反渗透(RO)海水淡化是一种有效获取淡水的技术,同时,结垢、浓水处理、能耗等问题制约着反渗透的进一步发展。采用纳滤(NF)作为反渗透的海水淡化预处理工艺,能有效解决反渗透膜结垢问题,并降低能耗,有助于排放浓水的处理。本文从海水淡化预处理纳滤膜的性能、海水淡化纳滤预处理的工艺以及NF-RO与其他方法联用三个方面综述了纳滤-反渗透联用进行海水淡化的研究进展。
Reverse osmosis (RO) seawater desalination is an effective way to produce fresh water. However, the effect of scaling, concentrated water treatment and energy consumption limit thefurther application and development of reverse osmosis seawater desalination.Nanofiltration(NF) usedas the pre-treatment process of seawater,prevented RO membranes from scaling,reduced energy consumption and also played an important role in concentrated water treatment.This study mainly summarizedprogress ofnanofiltration membrane seawater desalinationperformance, nanofiltration as a pretreatment method before reverse osmosisand NF-RO combines with some other desalination technologies.

基金项目:
国家自然科学基金(51273211),宁波材料所一三五规划(Y20222QI08),宁波市自然科学基金(2014A610141)

作者简介:
周栋(1988-),男,湖北孝感,硕士生,从事膜材料制备及应用研究。通讯联系人*,Email: fu.liu@nimte.ac.cn, xuelx@nimte.ac.cn

参考文献:
[1]王世昌. 海水淡化工程[M]. 北京:化学工业出版社,2003.
[2]New Desalination Capacity 1980-2009-Chart[J].Global Water Intelligence,2009, 10
[3]The Big Dipper: Contracted Desalination CapacityForecast-Chart[J]. Global WaterIntelligence, 2009, 10
[4]FritzmannC, Löwenberg J, Wintgens T, et al. State-of-the-art of reverse osmosis desalination [J].Desalination, 2007, 216: 1-76
[5]Khawaji A D, Kutubkhanah I K, Wie J M. Advances in seawater desalination technologies[J]. Desalination,2008, 221: 47-69.
[6]Kim S H, Kim G T, Yim S K, et al. Application of energy efficient reverse osmosis for seawater desalination system[J]. Desalination,2002, 144: 361- 365.
[7]Misdan N, Lau W J, Ismail A F. Seawater Reverse Osmosis (SWRO) desalination by thin-film composite membrane-Current development, challenges and future prospects[J]. Desalination,2012, 287: 228-237
[8]Greenlee L F, Lawler D F, Freeman B D, et al. Reverse osmosis desalination:water sources, technology, and today's challenges[J]. Water Research,2009, 43: 2317-2348.
[9]Energy Makes All the Difference: Desalination Operating Costs Compared – Chart [J]. Global Water Intelligence, 2007, 8
[10]Lee K P, Arnot T C, Mattia D. A review of reverse osmosis membrane materials for desalination—development to date and future potential[J]. Journal of Membrane Science, 2011, 370: 1-22.
[11]Global Water Intelligence (GWI/IDA DesalData),Market pro?le and desalinationmarkets, 2009-2012[J]. Yearbooks and GWI website, 2012
[12]Sbalani S S, Goosen M F A, Al-elushi, et al.Concentration polarization in ultrafiltration and reverse osmosis:acritical review [J]. Desalination,2001, 141: 269-289.
[13]Greenlee L F, Lawler D F, Freeman B D,et al. Reverse osmosis desalination:water sources,technology, and today's challenges[J]. Water Research,2009, 43: 2317-2348.
[14]Sadwhnai J J, Veza J M, Santanb C. Case studies on environmental impact of seawater desalination[J]. Desalination,2005, 185: 1-8.
[15]Mauguin G, Corsin P. Concentrate and other waste disposals from SWRO plants: characterization of their environmental impact[J].Desalination,2005, 182: 355-364.
[16]Liu M H, Yu S C, Tao J, et al.Preparation, structure characteristics and separation properties of thin-film composite polyamide-urethane seawater reverse osmosis membrane[J]. Journal of Membrane Science,2008, 325:947-956.
[17]Petersen R J. Composite reverse osmosis and nanofiltrationmembranes[J]. Journal of Membrane Science,1993, 83: 81-105.
[18]Lu X F, Bian X K, Shi L Q, et al. Preparation and characterization of NF composite membrane[J]. Journal of Membrane Science,2002, 210: 3-11.
[19]Vuong D X. Two stage nanofiltration seawater desalination system [P]. US 8,366,924 B2Feb. 5, 2013.
[20]Long Beach water department. Long Beach desalination technologyreceives patent protection[J].Membrane Technology,2006,11:1
[21]Harrison C J, Gouellec Y A, Cheng R C. Bench-scale testing ofnanofiltration for seawater desalination [J].Journal of EnvironmentalEngineering,2007,133(11):1004-1014.
[22]Liu Jie, XieLixin, Wang Zhi, et al.Dual-stage nanofiltration seawater desalination: waterquality, scaling and energy consumption [J]. Desalination and Water Treatment,2014, 52: 134-144.
[23]Tan CH, Ng HY. A novel hybrid forward osmosis-nanofiltration (FO-NF) process for seawater desalination: draw solution selection and system configuration[J].Desalination and Water Treatment, 2010,13: 356-361.
[24]Zhao S, Zou L, Mulcahy D.Brackish water desalination by a hybrid forward osmosis–nanofiltration system using divalent draw solute [J].Desalination, 2012, 284: 175-181.
[25]SarkarS, SenGuptaAK, A new hybrid ion exchange-nanofiltration (HIX-NF) separation process for energy-efficient desalination: process concept and laboratory evaluation [J]. Journal of Membrane Science, 2008, 324: 76-84.
[26]SarkarS, SenGuptaA K, A hybrid ion exchange-nanofiltration (HIX-NF) process for energy efficient desalination of brackish/seawater [J]. 2009
[27]Abdel Nasser A. Mabrouk, Hassan El-banna S. Fath, Experimental study of high-performance hybrid NF-MSFdesalination pilot test unit driven by renewable energy, Desalination and Water Treatment, 2013, 51: 6895-6904
[28]Mohamed Khayet, Membranes and theoretical modeling of membrane distillation: A review, Advances in Colloid and Interface Science, 2011, 164: 56-88
[29]陈益棠, 陈波. 高回收率反渗透海水淡化[J]. 水处理技术2008, 30:196-198.
[30]Hassan A M, Al-Sofi M A, Al-Amoudi A et al. A nanofiltration (NF) membrane pretreatment of swro feed and MSF make-up[J]. Abstract of Paper presented at IDA World Congress on Desalination and Water Reuse, Oct. 1997 Madrid, Spain.
[31]王玉红, 苏保卫, 徐佳等. 纳滤膜脱盐性能及其在海水软化中应用的研究[J]. 工业水处理,2006, 26:46-49.
[32]张莉娜,黄婕,熊丹柳等. 纳滤膜脱盐及其在海水软化中的应用[J]. 膜科学与技术,2012, 32:97-10.
[33]Hilal N, Al-Zoubi H, Mohammad A W. Nanofiltration of highly concentrated salt solutions up to seawater salinity[J]. Desalination,2005, 184:315-326.
[34]李晓明, 王铎, 高学理等. 纳滤膜海水软化性能及膜污染研究[J]. 水处理技术,2008, 34:8-11.
[35]Llenas L, Mart?´nez-Llado X, Yaroshchuk A, et al.Nanofiltration as pretreatment for scale prevention in seawater reverse osmosis desalination[J]. Desalination and Water Treatment,2011, 36:310-318.
[36]苏保卫, 王玉红, 李晓明等. 胶州湾海水纳滤软化的研究[J]. 水处理技术,2007, 33:64-66.
[37]李晓明, 王铎, 柴涛等. 纳滤海水软化的实验研究[J]. 高校化学工程学报 2009, 23:582-586.
[38]Song YF, XuJ,XuY, et al. Performance of UF-NF integrated membrane process for seawater softening[J]. Desalination,2011, 276:109-116.
[39]陈侠, 詹志斌, 陈丽芳等. 纳滤作为反渗透海水淡化与处理的研究[J]. 膜科学与技术,2013, 33:59-62.
[40]Walha K, Amar R B, Quemeneur F. Treatment by nanofiltration and reverse osmosis of high salinity drilling water for seafood washing and processing[J]. Desalination, 2008, 219:231-239.
[41]Pontié M, Derauw J S, Plantier S, et al. Seawater desalination: nanofiltration–a substitute for reverse osmosis? [J]. Desalination and Water Treatment,2013, 51:485-494.
[42]Llenas L, Ribera G, Mart?´nez-Llado X, et al. Selection of nanofiltration membranes as pretreatment for scaling prevention in SWRO using real seawater[J]. Desalination and Water Treatment,2013, 51:930-935.
[43]Uhlinger R A. Desalination method and apparatus utilizing nanofiltration and reverse osmosis membranes [P]. US 6,190,556 B1 Feb. 20, 2001.
[44]Hassan A M, Al-Sofi M A, Al-Amoudi A ,et al. A new approach to membrane and thermal seawater desalination processes using nanofiltrationmembrane(Part1)[J]. Desalination,1998, 118:35-51.
[45]Hassan A M, Farooque A M, Jamaluddin A T M, et al. Optimization of NF pretreatment of feed to seawater desalination plants[J]. Presented at IDA World Congress on Desalination Water Reuse held at San Diego, USA, 29 Aug.-3 Sept. 1999.
[46]Hassan A M, Farooque A M, Jamaluddin A T M, et al. A demonstration plant based on the new NF-SWRO process[J]. Desalination,2000, 131:157-171.
[47]Hassan A M, Farooque A M, Jamaluddin A T M, et al. Conversion and operation of the commercial umm lujjswro plant from a single swro desalination process to the new dual NF-SWRO desalination process [J]. Paper presented at IDA Conference, March 2002 at Manama Bahrain.
[48]Erikssona P, Kyburzb M, Pergande W. NF membrane characteristics and evaluation for sea water processing applications[J]. Desalination,2005, 184:281-294.
[49]A1-Amoudi A S, Farooque A M. Performance restoration and autopsy of NF membranes used in seawater pretreatment[J]. Desalination,2005, 178:261-271.
[50]SongY F, Su B W, Gao X L, et al. The performance of polyamide nanofiltration membrane for long-term operation in an integrated membrane seawater pretreatment system[J].Desalination,2012, 296:30-36.
[51]Song Y F, Su B W, Gao X L, et al. Investigation on high NF permeate recovery and scaling potential prediction in NF-SWRO integrated membrane operation[J]. Desalination,2013, 330:61-69.
[52]Song Y F, Gao X L, Gao C J. Evaluation of scaling potential in a pilot-scale NF-SWRO integrated seawater desalination system[J]. Journal of Membrane Science,2013, 443:201-209.
[53]Farooque AM, Green TN, Mohammed NK, et al. Autopsy of NF membranes after 5 years of operation at the UmmLujj SWRO plant [J]. Desalination and Water Treatment, 2009, 3: 83-90
[54]Abdullatef A E, Farooque M, Al-Otaibi G, et al. Optimum nanofiltration membrane arrangements in seawater pretreatment -Part-I[J]. Desalination and Water Treatment,2011,28:270-286.
[55]AlTaee A, Sharif A O. Alternative design to dual stage NF seawater desalination using high rejectionbrackish water membranes [J]. Desalination,2011, 273: 391-397
[56]M.A. Darwish, Fatimah M. Al Awadhi, Mahmoud Y. Abdul Raheem, The MSF: Enough is Enough, Desalination and Water Treatment, 2010, 22: 193-203
[57]VrouwenvelderJS,LoosdrechtMCM, KruithJC. Early warning of biofouling in spiral wound nano?ltrationand reverse osmosis membranes [J]. Desalination, 2011, 265: 206-212.
[58]Hassan A M. Process for desalination of saline water, especially water, having inceased product yield and quality [P]. US 6,508,936 B1. Jan. 21, 2003.
[59]A1-Sofi M A, Hassan A M, Hamed O A, et al. Optimization of hybridized seawater desalination process[J]. Desalination,2000, 131:147-156.
[60]Hamed O A. Overview of hybrid desalination systems-current status and future prospects [J]. Desalination,2005, 186:207-214.
[61]Hamed O A, Hassan A M, Al-Shail K, et al. Performance analysis of a trihybrid NF/RO/MSF desalination plant [J].  Desalination and Water Treatment,2009, 1:215-222.
[62]Abdel Nasser A. Mabrouk, Hassan El-banna S. Fath, Experimental study of high-performance hybrid NF-MSFdesalination pilot test unit driven by renewable energy, Desalination and Water Treatment, 2013, 51: 6895-6904
[63]Nasser A A,MabroukH,Fath E S, Techno-economic analysis of hybrid high performance MSFdesalination plant with NF membrane [J].Desalination and Water Treatment, 2013, 51, 844-856
[64]Mohamed K. Membranes and theoretical modeling of membrane distillation: A review [J].Advances in Colloid and Interface Science, 2011, 164: 56-88
[65]马润宇, 王艳辉, 涂感良. 膜结晶技术研究进展及应用前景[J]. 膜科学与技术,2003, 23:145-150.
[66]Drioli E, Lagana F, Criscuoli A, et al. Integrated membrane operations in desalination processes[J].Desalination, 1999, 122:141-145.
[67]Drioli E, Criscuoli A, Curcio E. Integrated membrane operations for seawater desalination[J].Desalination, 2002, 147:77-81.
[68]Macedonio F, Profio G D, Curcio E, et al. Integrated membrane systems for seawater desalination[J].Desalination,2006, 200:612-614.
[69]Macedonio F, Drioli E. An exergetic of a membrane desalination system[J]. Desalination,2010, 261:293-299.
[70]Drioli E, Profio G D, Curcio E. Progress in membrane crystallization[J]. Current Opinion in Chemical Engineering,2012, 1:1-5.
[71]E. Drioli, E. Curcio, G. Di profio, et al, Integrating membrane contactors technologyand pressure-driven membrane operationsfor seawater desalinationEnergy, Exergy and Costs Analysis,Chemical Engineering Research and Design, 2006, 84: 209-220
[72]Kim Y M, Kim S J, Kim Y S, et al. Overview of systems engineering approaches for a large- scale seawater desalination plant with a reverse osmosis network[J]. Desalination,2009, 238:312-332.
[73]Turek M, Dydo P. Hybrid membrane-thermal versus simple membrane systems[J]. Desalination,2003, 157:51-56.
[74]Turek M, Chor??ewska M. Nanofiltration process for seawater desalination-salt production integrated system[J]. Desalination and Water Treatment,2009,7:178-181.
 

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