膜科学与技术

PTMSDPA纳滤膜的渗透性能研究

作者：许洁¹，张颖¹，李战胜¹，胡雁鸣²，增田俊夫³

单位： 1大连理工大学化工学院，辽宁大连116024 2中国科学院长春应用化学研究所，长春130022 3日本福井工业大学环境生命化学科，福井910-8505

关键词： PTMSDPA；耐溶剂纳滤；染料截留

出版年,卷(期):页码： 2016,36(1):50-54

摘要：

以新型取代聚乙炔--聚[1-(4-三甲基硅基)苯基-2-苯乙炔]（PTMSDPA）为膜材料，采用溶剂蒸发法制备均质膜，研究其对不同染料-乙醇溶液的纳滤性能。发现在所考察的压力、温度范围内，PTMSDPA均质膜的乙醇渗透性能稳定，耐压密性良好，且无老化现象。膜的分离性能不仅和染料的分子量有关，也和染料所带电荷相关，膜和染料之间的相互作用是影响膜分离性能的重要因素。

As a novel solvent resistant nanofiltration membrane material, poly[1-phenyl-2-[p-(trimethylsilyl)phenyl]acetylene] (PTMSDPA) was used to prepare dense membranes by solution-casting method.Thenanofiltration performance of PTMSDPA membrane for different dyes-alcohol solutions was surveyed. The ethanol permeabilityof the membrane was stable under different pressures and temperatures; no compaction and aging phenomenon were observed. The separation performance of the membrane is affected by the molecular weight of the dyes as well astheir surface charge. The interaction between membrane and dye is the key factor affecting the separation performance of themembrane.

第一作者简介：许洁（1989-），女，河南南阳人，硕士研究生，从事分离膜的制备和过程研究。*通讯作者，Email：lizs@dlut.edu.cn

参考文献：

[1] Marchetti P, Solomon M F J,Szekely G, et al. Molecular separation with organic solvent nanofiltration: A critical review [J]. Chemical Reviews, 2014, 114(21): 10735-10806.
[2] 李祥, 张忠国, 任晓晶,等. 纳滤膜材料研究进展 [J]. 化工进展, 2014, 33(5): 1210-1218, 1229.
[3] 王晓琳, 涂丛慧, 方彦彦, 等. 纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展 [J]. 膜科学与技术, 2011, 31(3): 127-134.
[4] 王晓琳, 张澄洪, 赵杰. 纳滤膜的分离机理及其在食品和医药行业中的应用 [J]. 膜科学与技术, 2000, 20(1): 29-36.
[5] 吴法东, 周勇, 高从堦. 耐溶剂高分子纳滤膜研究进展 [J]. 水处理技术, 2010, 36(12): 1-5, 14.
[6] Vandezande P, Gevers L E M, Vankelecom I F J. Solvent resistant nanofiltration: Separating on a molecular level [J]. Chemical Society Reviews, 2008, 37(2): 365-405.
[7] Nagai K, Masuda T, Nakagawa T, et al. Poly 1-(trimethylsilyl)-1-propyne and related polymers: synthesis, properties and functions [J]. Prog Polym Sci, 2001, 26(5): 721-798.
[8] Volkov A V, Stamatialis D F, Khotimsky V S, et al. Poly 1-(trimethylsilyl)-1-propyne as a solvent resistance nanofiltration membrane material [J]. J Membr Sci, 2006, 281(1-2): 351-357.
[9] Volkov A V, Parashchuk V V, Stamatialis D F, et al. High permeable PTMSP/PAN composite membranes for solvent nanofiltration [J]. J Membr Sci, 2009, 333(1-2): 88-93.
[10] Tsuchihara K, Masuda T, Higashimura T. Tractable silicon-containing poly(diphenylacetylenes): their synthesis and high gas permeability [J]. Journal of the American Chemical Society, 1991, 113(22): 8548-8549.
[11] 胡雁鸣, 高可可, 张丛峥, 等. 物理老化对聚[1-(4-三甲基硅基)苯基-2-苯乙炔]膜气体渗透性能的影响 [J]. 化学工业与工程, 2014, 31(1): 53-6.
[12] Fischer K, Wilken M. Experimental determination of oxygen and nitrogen solubility in organic solvents up to 10 MPa at temperatures between 298 K and 398 K [J]. The Journal of Chemical Thermodynamics, 2001, 33(10): 1285-1308.
[13] Poling B E, Prausnits J M, O'Connell J P. The properties of gases and liquids [M]. 5th ed. New York: McGraw-Hill Compamies, Inc., 2005.
[14] Machado D R, Hasson D, Semiat R. Effect of solvent properties on permeate flow through nanofiltration membranes. Part I: investigation of parameters affecting solvent flux [J]. J Membr Sci, 1999, 163(1): 93-102.
[15] Tsar’kov S E, Malakhov A O, Litvinova E G, et al. Nanofiltration of dye solutions through membranes based on poly(trimethylsilylpropyne) [J]. Pet Chem, 2013, 53(7): 537-545.
[16] BhanushaliD, Kloos S, Bhattacharyya D. Solute transport in solvent-resistant nanofiltration membranes for non-aqueous systems: experimental results and the role of solute-solvent coupling[J]. J Membr Sci, 2002,208: 343-359.

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