膜科学与技术

中空纤维复合纳滤膜的研究进展

作者：李红宾¹，石文英¹，王薇²，杜启云²，张海霞¹

单位： 1. 河南工程学院纺织学院，郑州 450007； 2. 天津工业大学中空纤维膜材料与膜过程国家重点实验室，天津 300387

关键词：纳滤；复合膜；中空纤维；界面聚合；涂覆

出版年,卷(期):页码： 2016,36(2):122-131

摘要：

在纳滤膜制备及其应用领域中，绝大多数采用由二元胺与多元酰氯在非织造布基超滤膜表面界面聚合得到的卷式复合纳滤膜。中空纤维复合纳滤膜结合了中空纤维和复合纳滤膜的诸多优点，以其高的装填密度和自支撑结构极大地降低了传质阻力，从而实现较低压力下的高通量和高选择性。本文从基膜制备工艺、新型功能层材料、涂覆工艺和基膜与功能层间相互作用机理等四方面综述了国内外中空纤维复合纳滤膜的研究进展，并对其制备方法中亟需深入研究的内容和其应用前景进行了展望。

In the fields of nanofiltration (NF) membrane fabrication and its application, spiral-wound composite NF membrane is mostly used which is commonly obtained from the interfacial polymerization of diamine and polyacyl chloride on the nonwoven-based ultrafiltration membrane surface. Hollow fiber composite NF membrane with high packing density and self-supported structure has low mass transfer resistance so as to realize high flux and high selectivity simultaneously under lower operation pressure. In this paper, the recent research progress was well described from the aspects of preparation method of hollow fiber support membrane, novel materials of functional layer, coating technique and the interaction mechanism between the functional layer and support membrane. Finally, some contents deserving further research and the application prospects of hollow fiber composite nanofiltration membrane were presented.

李红宾（1985-），男，河南新乡人，博士，讲师，主要从事新型膜材料与膜过程研究，E-mail：lihongbin20033421@163.com. * 通讯联系人：lihongbin20033421@163.com.

参考文献：

[1] Mohammad AW, Teow YH, Ang WL, Chung YT, Oatley-Radcliffe DL, Hilal N. Nanofiltration membranes review: Recent advances and future prospects[J]. Desalination, 2015, 356: 226-254.
[2] 毕飞, 张林, 吴礼光, 陈欢林, 高从堦. 纳滤膜系统优化设计模式探讨[J]. 膜科学与技术, 2012, 32(3): 11-16.
[3] Zhai LH, Pan YT, Guo Y, Ma Z, Bi F. International comparative study on nanofiltration membrane technology based on relevant publications and patents[J]. Scientometrics, 2014, 101: 1361-1374.
[4] Hilal N, A1-Zoubi H, Darwish NA, Mohammad AW, Abu MA. A comprehensive review of nanofiltration membranes: Treatment, pretreatment, modelling, and atomic force microscopy[J]. Desalination, 2004, 170: 281-308.
[5] Liu TY, Bian LX, Yuan HG, Pang B, Lin YK, Tong Y, Bruggen BV, Wang XL. Fabrication of a high-flux thin film composite hollow fiber nanofiltration membrane for wastewater treatment[J]. J Membr Sci, 2015, 478: 25-36.
[6] 王薇, 杜启云. 中空纤维复合膜[J]. 高分子通报, 2007, 5: 54-59.
[7] An QF, Sun WD, Zhao Q, Ji YL, Gao CJ. Study on a novel nanofiltration membrane prepared by interfacial polymerization with zwitterionic amine monomers[J]. J Membr Sci, 2013, 431: 171-179.
[8] Sun SP, Hattona TA, Chan SY, Chung TS. Novel thin-film composite nanofiltration hollow fiber membranes with double repulsion for effective removal of emerging organic matters from water[J]. J Membr Sci, 2012, 401-402: 152-162.
[9] Zhou C, Gao XL, Li SS, Gao CJ. Fabrication and characterization of novel composite nanofiltration membranes based on zwitterionic O-carboxymethyl chitosan[J]. Desalination, 2013, 317: 67-76.
[10] Hu LJ, Zhang SH, Han RL, Jian XG. Preparation and performance of novel thermally stable polyamide/PPENK composite nanofiltration membranes[J]. Appl Surf Sci, 2012, 258: 9047-9053.
[11] Liu JQ, Xu ZL, Li XH, Zhang Y, Zhou Y, Wang ZX, Wang XJ. An improved process to prepare high separation performance PA/PVDF hollow fiber composite nanofiltration membranes[J]. Sep Purif Technol, 2007, 58:53-60.
[12] Yu SC, Zheng YP, Zhou Q, Shuai S, Lü ZH, Gao CJ. Facile modification of polypropylene hollow fiber microfiltration membranes for nanofiltration[J]. Desalination, 2012, 98:49-58.
[13] Zheng YP, Yu SH, Shuai S, Zhou Q, Cheng QB, Liu MH, Gao CJ. Color removal and COD reduction of biologically treated textile effluent through submerged filtration using hollow fiber nanofiltration membrane[J]. Desalination, 2013, 314:89-95.
[14] Nasef MM, Hegazy ES. Preparation and applications of ion exchange membranes by radiation-induced graft copolymerization of polar monomers onto non-polar films[J]. Prog Polym Sci, 2004, 29:499-561.
[15] Zhao YH, Zhu BK, Kong L, Xu YY. Improving hydrophilicity and protein resistance of poly(vinylidene fluoride) membranes by blending with amphiphilic hyper branched star polymer[J]. Langmuir, 2007, 23:5779-5786.
[16] Darvishmanesha S, Tasselli F, Johannes CJ, Tocci E, Bazzarelli F, Bernardo P, Luis P, Degrèvea J, Driolib E, Bart VB. Preparation of solvent stable polyphenylsulfone hollow fiber nanofiltration membranes[J]. J Membr Sci, 2011, 384:89- 96.
[17] Li XH, Zhang CJ, Zhang SN, Li JX, He BQ, Cui ZY. Preparation and characterization of positively charged polyamide composite nanofiltration hollow fiber membrane for lithium and magnesium separation[J]. Desalination, 2015, 369:26-36.
[18] Peyravi M, Rahimpour A, Jahanshahi M. Thin film composite membranes with modified polysulfone supports for organic solvent nanofiltration[J]. J Membr Sci, 2012, 423424:225-237.
[19] Sun SP, Chan SY, Chung TS. A slow-fast phase separation (SFPS) process tofabricatedual-layer hollow fiber substrates for thin-film composite (TFC) organic solvent nanofiltration (OSN) membranes[J]. Chem Eng Sci, 2015, 129:232-242.
[20] 张璐, 安树林, 陈兴福. 异形板纺制中空纤维复合膜基膜的工艺及膜性能研究[J]. 天津工业大学学报, 2010, 29(1):27-30.
[21] 单永广, 陈峰, 杨文婷, 张芦斌, 金涛. 高性能聚砜中空纤维纳滤膜基膜的研制[J]. 水处理技术, 2013, 39:77-80.
[22] Wang XL, Wei JF, Dai Z, Zhao KY, Zhang H. Structural control and chemical functionalization of dual-layer nanofiltration hollow fiber membrane for efficient waste water treatment[J]. Procedia Engineering, 2012, 44:635-636.
[24] Wei XZ, Kong X, Sun CT, Chen JY. Characterization and application of a thin-film composite nanofiltration hollow fiber membrane for dye desalination and concentration[J]. Chem Eng J, 2013, 223:172-182.
[25] Liu TY, Liu ZH, Zhang RX, Wang Y, Bruggen BV, Wang XL. Fabrication of a thin film nanocomposite hollow fiber nanofiltration membrane for wastewater treatment[J]. J Membr Sci, 2015, 488:92-102.
[26] Liu C, Shi L, Wang R. Crosslinked layer-by-layer polyelectrolyte nanofiltration hollow fiber membrane for low-pressure water softening with the presence of SO42- in feed water[J]. J Membr Sci, 2015, 486:169-176.
[27] Zhu WP, Gao J, Sun SP, Zhang S, Chung TS. Poly(amidoamine) dendrimer (PAMAM) grafted on thinfilm composite (TFC) nanofiltration (NF) hollow fiber membranes for heavy metal removal[J]. J Membr Sci, 2015, 487:117-126.
[28] Aba NFD, Chong JY, Wang B, Mattevi C, Li K. Graphene oxide membranes on ceramic hollow fibers–Microstructural stability and nanofiltration performance[J]. J Membr Sci, 2015, 484:87-94.
[29] Fang WX, Shi L, Wang R. Mixed polyamide-based composite nanofiltration hollow fiber membranes with improved low-pressure water softening capability[J]. J Membr Sci, 2014, 468:52-61.
[30] Zhu WP, Sun SP, Gao J, Fu FJ, Chung TS. Dual-layer polybenzimidazole/polyethersulfone (PBI/PES) nanofiltration (NF) hollow fiber membranes for heavy metals removal from wastewater[J]. J Membr Sci, 2014, 456:117-127.
[31] Maurya SJ, Parashuram K, Singh PS, Ray P, Reddy AVR. Preparation of polysulfone-polyamide thin film composite hollow fiber nanofiltration membranes and their performance in the treatment of aqueous dye solutions[J]. Desalination, 2012, 304:11-19.
[32] Zheng YP, Yao GH, Cheng QB, Yu SC, Liu MH, Gao CJ. Positively charged thin-film composite hollow fiber nanofiltration membrane for the removal of cationic dyes through submerged filtration[J]. Desalination, 2013, 328: 42-50.
[33] Han JN, Yang DL, Zhang SH, Wang LJ, Jian XG. Preparation and performance of SPPES/PPES hollow fiber composite nanofiltration membrane with high temperature resistance[J]. Desalination, 2014, 350:95-101.
[34] Wei XZ, Wang SX, Shi YY, Xiang H, Chen JY, Zhu BK. Characterization of a positively charged composite nanofiltration hollow fiber membrane prepared by a simplified process[J]. Desalination, 2014, 350:44-52.
[35] Song JF, Li XM, Li ZS, Zhang MX, Yin Y, Zhao BL, Kong DF, Chen G, He T. Stabilization of composite hollow fiber nanofiltration membranes with a sulfonated poly(ether ether ketone) coating[J]. Desalination, 2015, 355:83-90.
[36] Setiawan L, Shi L, Wang R. Dual layer composite nanofiltration hollow fiber membranes for low-pressure water softening[J]. Polymer, 2014, 55:1367-1374.
[37] Liu C, Shi LK, Wang R. Enhanced hollow fiber membrane performance via semi-dynamic layer-by-layer polyelectrolyte inner surface deposition for nanofiltration and forward osmosis applications[J]. React Funct Polym, 2015, 86:15-160.
[38] Rajaeian B, Rahimpour A, Tade MO, Liu SM. Fabrication and characterization of polyamide thin film nanocomposite (TFN) nanofiltration membrane impregnated with TiO2 nanoparticles[J]. Desalination, 2013, 313:176-188.
[39] Gao J, Sun SP, Zhu WP, Chung TS. Chelating polymer modified P84 nanofiltration (NF) hollow fiber membranes for high efficient heavy metal removal[J]. Water Res, 2014, 63:252-261.
[40] Li LC, Wang BG, Tan HM, Chen TL, Xu JP. A novel nanofiltration membrane prepared with PAMAM and TMC by in situ interfacial polymerization on PEK-C ultrafiltration membrane[J]. J Membr Sci, 2006, 269(1-2):84-93.
[41] Fang WX, Shi L, Wang R. Interfacially polymerized composite nanofiltration hollow fiber membranes for low-pressure water softening[J]. J Membr Sci, 2013, 430:129-139.
[42] Shao L, Cheng XQ, Liu Y, Quan S, Ma J, Zhao SZ, Wang KY. Newly developed nanofiltration (NF) composite membranes by interfacial polymerization for Safranin O and Aniline blue removal[J]. J Membr Sci, 2013, 430:96-105.
[43] Monteiro E, He QC, Yvonnet J. Hyperelastic large deformations of two-phase composites with membrane-type interface[J]. Int J Eng Sci, 2011, 49:985-100.
[44] Yang FJ, Zhang SH, Yang DL, Jian XG. Preparation and characterization of polypiperazine amide/PPESK hollow fiber composite nanofiltration membrane[J]. J Membr Sci, 2007, 301(1-2):85-92.
[45] Veríssimo S, Peinemann KV, Bordado J. Thin-film composite hollow fiber membranes: An optimized manufacturing method[J]. J Membr Sci, 2005, 264(1-2):48-55.
[46] Li HB, Wang W, Zhang YF. Preparation and characterization of high-selectivity hollow fiber composite membrane by two-way coating technique[J]. J Appl Polym Sci, 2014, 131(23):12636-12646.
[47] Wu L, Sun J, Wang Q. Poly(vinylidine fluoride)/polyethersulfone blend membranes: effect of solvent sort, polyethersulfone and polyvinylpyrrolidone concentration on their properties and morphology[J]. J Membr Sci, 2006, 285:290-298.
[48] Jin Y, Su Z. Effects of polymerization conditions on hydrophilic groups in aromatic polyamide thin films[J]. J Membr Sci, 2009, 330:175-179.
[49] 王薇, 张宇峰, 杜启云, 李国东. 复合纳滤膜制备中的界面力学研究[J]. 高分子材料科学与工程, 2007, 23(3):219-222.
[50] Zuo J, Wang Y, Sun SP, Chung TS. Molecular design of thin film composite (TFC) hollow fiber membranes for isopropanol dehydration via pervaporation[J]. J Membr Sci, 2012, 405-406:123-133.

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