膜科学与技术

过渡层对Pebax/PAN复合膜孔渗现象的影响研究

作者：杜国栋，胡义，王连军，季鹏飞，李恕广，栗广勇，李杨

单位：（1．大连欧科膜技术工程有限公司，大连116035；2．大连理工大学，大连116024）

关键词： Pebax；复合膜；孔渗；过渡层

出版年,卷(期):页码： 2017,37(2):40-45

摘要：

选用聚丙烯腈（PAN）超滤膜作底膜，以乙醇/水混合作为Pebax的溶剂，采用浸渍涂层（dip coating）的方法制备Pebax/PAN复合膜。发现直接在PAN底膜上涂覆Pebax制备Pebax/PAN复合膜会导致涂层液的孔渗。本文借助理论模型分析孔渗深度对Pebax/PAN复合膜渗透速率的影响，研究表明，微小的孔渗深度也会对复合膜的整体气体渗透速率造成显著的影响。引入氨基硅氧烷与PDMS共混过渡层来解决孔渗问题，结果证实引入该过渡层后，Pebax/PAN复合膜的气体渗透速率明显提高，而CO2/N2选择性基本保持不变。

The dip coating method was adopted to prepare Pebax/PAN composite membrane, with polyacrylonitrile(PAN) ultrafiltration membrane as substrate and ethanol-water mixture as solvent for Pebax. It was found that Pebax/PAN composite membrane, which wasprepared by coating Pebax on PAN substrate directly, would lead to the permeation of coating solution. In this paper, the effect of penetration depth on the permeation rate of Pebax/PAN composite membrane was analyzed by the theory model, and the result showed that minutepenetration depth would have a great influence on the overall gas permeation rate of the Pebax/PAN composite membrane.Transition layer, which was prepared by blending amino siloxane and PDMS, was applied to address the above permeation, and the result proved that there was a significant increase of gas permeation of Pebax/PAN composite membrane and its CO2/N2 selectivity was basically stable.

作者简介：杜国栋（1967-），男，辽宁大连人，工程师，从事膜高分子气体分离膜研究工作．＊通讯作者，E-mail：ljwang@eurofilm.com.cn

参考文献：

[1]Cen Y，Claudia S B，LichtenthalerRN．Sorption properties of organic solvents in PEBA membranes [J]．Journal of membrane science，2002，206：341–349．
[2]Loeb GS，Sourirajan S．Sea water demineralization by means of an osmotic membrane [J]．AdvChemSer，1963，38：117–132．
[3]Cabasso I，Lundy K A．Method of Making Membranes for Gas Separation and the Composite Membranes：US；4602922[P]．1986，07，29．
[4]Lundy K A，Cabasso I．Analysis and construction of multilayer composite membranes for the separation of gas mixtures [J]．Ind Eng Chem Res，1989，28：742–756．
[5]Chung T S，Kafchinski E R，Kohn R S，et al．Fabrication of composite hollow fibers for air separation [J]．J Appl Polym Sci，1994，53：701–708．
[6]Chung T S，Kafchinski E R，Spak M，et al．High performance PAN composite membranes：US；5324430 [P]．1994，06，28．
[7]Henis J M S，Tripodi M K．A novel approach to gas separations using compositehollow fiber membranes [J]．Sep Sciand Techn，1980，15(4)：1059–1068．
[8]Henis J M S，Tripodi M K．Multicomponent membranes for gas separations： US，4230463 [P]．1980， 10，28．
[9]Henis J M S，Tripodi M K．Composite hollow fiber membranes for gas separation：the resistance model approach [J]．Journal of membrane science，1981，8：233–246．
[10]Lianjun Wang， Yang Li，Shuguang Li， et al．Preparation of composite poly(ether block amide) membrane for CO2 capture [J]．Journal of energy chemistry，2014，23：717–725．
[11]Ren X，Ren J，Li H，et al．Poly (amide-6-b-ethylene oxide) multilayer composite membrane for carbon dioxide separation [J]．International Journal of Greenhouse Gas Control, 2012，8：111－120．

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com