膜科学与技术

直流电场对凝胶型膜污染层的作用

作者：张姣，李天玉，关晶，黄霞

单位：清华大学环境学院环境模拟与污染控制国家重点实验室；清华大学（环境学院）-北京碧水源科技股份有限公司环境膜技术研发中心，北京100084

关键词：电场；膜污染；凝胶层；上清液

出版年,卷(期):页码： 2018,38(3):9-15

摘要：

膜污染制约着膜技术的发展与应用，形成膜污染的物质多带有负电荷，理论上电场可有效控制膜污染形成和发展。本研究采用富含形成凝胶型污染物质的膜生物反应器上清液为过滤原液，考察直流电场对形成中和形成后的污染层的作用。研究发现对形成中的膜污染层，膜通量随电压强度的升高而升高；而对已形成的膜污染层，则需要合适的电压和通电时间以提高其膜通量。对膜污染层的结构和成分的分析表明，电场可使膜表面凝胶层的交联度降低、孔隙率增大，从而有效降低凝胶类污染；但高电压（如15 V）下水的电解会导致已形成的膜污染层沉积大量颗粒沉淀而使得膜通量快速下降。

Development and application of membrane technologies were restricted by fouling. Foulants were majorly negatively charged, thus, electric field could theoretically effectively suppress the formation and evolution of fouling. In this study, membrane-bioreactor supernatant, which contained great amount of foulants to form gel-type fouling during filtration, were adopted as the feed water; and the effect of a direct electric field on both developing and developed fouling layer were investigated respectively. It was observed that the flux during the fouling layer formation increased with the increment of voltage, while specific voltage and time could increase the flux of a fouled membrane. The analysis of the structure and component of the fouling layer illustrated that gel-type fouling layer would be loosen thereby the porosity were increased. But large number of precipitates were observed on the fouled membrane surface due to electrolysis of water under high voltage (15 V), which led to an advanced reduction of flux.

张姣（1987-），女，山西阳泉人，博士，清华大学环境学院博士后，从事膜法水处理与再生水回用相关研究。E-mail：zhangjiao@tsinghua.edu.cn。*通讯作者，E-mail：xhuang@tsinghua.edu.cn

参考文献：

[1] Meng FG, Zhang SQ, Oh Y, et al. Fouling in membrane bioreactors: An updated review [J]. Water Res, 2017,114:151-180.
[2] Liang S, Gao P, Gao X, et al. Improved blending strategy for membrane modification by virtue of surface segregation using surface-tailored amphiphilic nanoparticles [J]. Frontiers of Environmental Science & Engineering, 2016,10(6).
[3] 权全, 柴俪洪, 肖长发, 等. PMIA中空纤维膜在MBR系统中污染类型和处理城市污水效果研究 [J]. 膜科学与技术, 2017,37(2):96-103.
[4] Guo W, Ngo H-H, Li J. A mini-review on membrane fouling [J]. Bioresour Technol, 2012,122:27-34.
[5] Wang XM, Waite TD. Role of Gelling Soluble and Colloidal Microbial Products in Membrane Fouling [J]. Environ Sci Technol, 2009,43(24):9341-9347.
[6] Wang Z, Wu Z. A Review of Membrane Fouling in MBRs: Characteristics and Role of Sludge Cake Formed on Membrane Surfaces [J]. Sep Purif Technol, 2009,44(15):3571-3596.
[7] Meng FG, Chae SR, Drews A, et al. Recent advances in membrane bioreactors (MBRs): Membrane fouling and membrane material [J]. Water Res, 2009,43(6):1489-1512.
[8] Hong HC, Zhang MJ, He YM, et al. Fouling mechanisms of gel layer in a submerged membrane bioreactor [J]. Bioresour Technol, 2014,166:295-302.
[9] 韩永萍, 肖燕, 宋蕾, 等. MBR膜污染的形成及其影响因素研究进展 [J]. 膜科学与技术, 2013,33(1):102-110.
[10] Le-Clech P, Chen V, Fane TAG. Fouling in membrane bioreactors used in wastewater treatment [J]. J Membr Sci, 2006,284(1-2):17-53.
[11] Akamatsu K, Yoshida Y, Suzaki T, et al. Development of a membrane–carbon cloth assembly for submerged membrane bioreactors to apply an intermittent electric field for fouling suppression [J]. Sep Purif Technol, 2012,88(0):202-207.
[12] Liu L, Liu J, Gao B, et al. Fouling reductions in a membrane bioreactor using an intermittent electric field and cathodic membrane modified by vapor phase polymerized pyrrole [J]. J Membr Sci, 2012,394–395(0):202-208.
[13] Zhang J, Satti A, Chen XG, et al. Low-voltage electric field applied into MBR for fouling suppression: Performance and mechanisms [J]. Chem Eng J, 2015,273:223-230.
[14] Wang Z, Wu Z, Yin X, et al. Membrane fouling in a submerged membrane bioreactor (MBR) under sub-critical flux operation: Membrane foulant and gel layer characterization [J]. J Membr Sci, 2008,325:238-244.
[15] Mo Y, Xiao K, Shen Y, et al. A new perspective on the effect of complexation between calcium and alginate on fouling during nanofiltration [J]. Sep Purif Technol, 2011,82(0):121-127.

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