抗污染高分子纳滤膜研究进展
作者:刘兴,邓慧宇,段龙繁,张小广,邦宇,陈庆春,那兵
单位: 东华理工大学省部共建核资源与环境国家重点实验室培育基地,南昌330013
关键词: 抗污染;高分子纳滤膜;表面改性;共混改性;层层自组装
出版年,卷(期):页码: 2018,38(5):113-121

摘要:
 纳滤膜被广泛用于水处理、食品加工、生物化学与制药、石油开采及提炼等方面,但是膜污染引起的性能下降、能耗增大及膜使用寿命缩短等却极大地增加了纳滤成本。为降低膜污染,人们在开发抗污染纳滤膜方面做了大量研究工作。本文在简要介绍纳滤膜污染的种类、污染机制等的基础上,着重总结了近年来研究者采用表面改性、共混改性、层层自组装等方法制备抗污染高分子纳滤膜方面取得的进展,并就今后的研究方向提出建议。
 Nanofiltration membrane is widely used in water treatment, food processing, biochemistry and pharmaceutical, oil extraction and refining etc. However, the performance degradation, increased energy consumption and the shortened service life of the membrane caused by membrane fouling have greatly increased the cost of nanofiltration technology. In order to reduce the membrane fouling and develop antifouling nanofiltration membrane, people have done a lot of research work. On the basis of elaborating the fouling types and mechanism of nanofiltration membrane, this paper focused on the construction of anti-fouling polymeric nanofiltration membrane as surface modification, blending modification and self-assembling etc. The suggestions on future research were also presented.
第一作者简介:刘兴(1993?),女,江西萍乡人,硕士生,主要从事纳滤膜的研究。1102683639@qq.com **通讯作者:邓慧宇 denghuiyu001@163.com

参考文献:
 [1] Wiesner, Mark R, Chellam, Shankararaman. Mass transport considerations for pressure driven membrane processes [J]. Journal American Water Works Association. 1992, (84):88-95.
[2] 罗敏,王占生,候立安. 纳滤膜污染的分析与机理研究[J].水处理技术. 1998, 24(6) : 318-323.
[3] Sun J Y, Xiao K, Mo Y H, et al. Seasonal characteristics of supernatant organics and its effect on membrane fouling in a full-scale  membrane bioreactor [J]. Journal of Membrane science, 2014, 453 :168-174.
[4]杨砾,杜海波,冉祥军,罗志林,纳滤膜污染原因分析及运行管理, 膜科学与技术. 2012, 32(2):92-99..
[5] 杨若松,王磊,张晓婷,王佳璇,有机物对聚酰胺复合纳滤膜硫酸钙结垢的影响[J].哈尔滨工业大学学报2016,48(8):84-90.
[6] Ghulam M, Kenny W, Siebe J, et al. Evaluation of the fouling resistance of methyl grafted ceramic membranes for inorganic foulants and co-effects of organic foulants [J], Separation and Purification Technology,2018,193:29–37.
[7] 郭驭,王小,纳滤膜污染机理/表征及控制,给水排水. 2017, 43 (9):120-131.
[8] Ran B, Zhang Q, Zhang R N, et al. Thin film nanocomposite membranes incorporated with grapheme quantum dots for high flux and antifouling property [J]. Journal of Membrane Science, 2018, 533:17-24.
[9] Safarpour M, Vatanpour V, Khataee A,et al. Development of a novel high flux and fouling-resistant thin film composite nanofiltration membrane by embedding reduced grapheme oxide/TiO2 [J]. Separation and Purification Technology, 2015, 154:96-107.
[10] Zhu J Y, Qin L J, Uliana Adam, et al. Elevated performance of thin film nanocomposite membranes enabled by modified hydrophilic MOFs for nanofiltration [J]. ACS Applied Materials Interfaces, 2017,9:1975-1986.
[11] Abu Seman M N, Khayet M, Bin Ali Z I, et al. Reduction of nanofiltration membrane fouling by UV-initiated graft polymerization technique [J]. Journal of Membrane Science, 2010, 355 (1-2) :133–141.
[12] 孙海静,高学理,王剑,王小娟,高从堦,抗污染抑菌性聚酰胺纳滤膜的制备及性能表征[J].中国海洋大学学报. 2017,47(5):88-93.
[13] Mondal S, Wickramasinghe S R. Photo-induced graft polymerization of N-isopropyl acrylamide on thin film composite membrane: Produced water treatment and antifouling properties [J]. Separation and Purification Technology, 2012, 90: 231–238.
[14] 李霞,曹义鸣,康国栋,于海军,刘中楠.基于多巴胺自聚合与表面接枝PHGH制备抗菌性纳滤膜[J].高等学校化学学报2014,35(9):2026-2030.
[15] Zhang D Y, Liu J, Shi Y S, et al.Antifouling polyimide membrane with surface-bound silver particles [J]. Journal of Membrane Science, 2016, 516:83-93.
[16] Lin Y L.In situ concentration-polarization-enhanced radical graft polymerization of NF270 for mitigating silica fouling and improving pharmaceutical and personal care product rejection [J]. Journal of Membrnae Science, 2018, 552:387-395.
[17]黄文强.聚酰胺复合纳滤膜表面接枝硅烷偶联剂及其性能研究[D].浙江理工大学2017.
[18] Zhao Y F, Zhang P B, Sun J, et al. Versatile antifouling polyethersulfone filtration membranes modified via surface grafting of zwitterionic polymers from a reactive amphiphilic copolymer additive [J]. Journal of Colloid and Interface Science, 2015,448 :380-388.
[19] Wang J, Wang Z, Liu Y Y,et al. Surface modification of NF membrane with zwitterionic polymer to improve anti-biofouling property [J]. Journal of Membrane Science, 2016,514 :407–417.
[20] 吴春林.表面接枝改性制备新型高分子膜材料的研究[D].石河子大学2015.
[21] 张志箭,徐安厚,赵孔银,郭杰,王晓磊,蔡志江,魏俊富.聚羟基丁酸酯纳米纤维支撑海藻酸钙纳滤膜制备及抗污染性能[J].高分子材料科学与工程.33(7) (2017)179-183,190.
[22] Liu M H, Zhou C M, Dong B Y, et al. Ehancing the permselectivity of thin-film composite poly(vinyl alcohol)(PVA) nanofiltration membrane by incorporting poly(sodium-p-styrene-sulfonate)(PSSNa) [J]. Joumal of Membrane Science. 2014, 463: 173-182.
[23] 孙健,邓优,张培斌,朱利平,朱宝库, 纳滤膜三元共聚涂层的构建及其渗透分离性能[J].膜科学与技术, 2016, 36(4):60-66,96.
[24] Zhao S, Wang Z. A loose nano-filtration membrane prepared by coating HPAN UF membrane with modified PEI for dye reuse and desalination[J]. Journal of Membrane Science, 2017,524:214-224.
[25] Ji Y L , An Q F, Zhao Q, et al. Novel composite nanofiltration membranes containing zwitterions with high permeate flux and improved anti-fouling performance [J]. Journal of Membrane Science, 2012, 390–391:243-253.
[26] Manijeh K, Ahmad A, Arash Y L. Chitosan –modified acrylic nanofiltration membrane for efficient removal of pharmaceutical compounds [J], Journal of Enviromental Chemical Engineering, 2018, 6: 583-587.
[27] Blanco J F, Sublet J L, Trong Q, et al. Formation and morphology studies of different polysulfones-based membranes made by wet phase inversion process [J]. Journal of Membrane Science. 2006, 283(1–2): 27-37.
[28] Nabe A, Staude E, Belfort G. Surface modification of polysulfone ultrafiltration membranes and fouling by BSA solutions [J]. Journal of Membrane Science. 1997,133 (1):57-72.
[29] Francesco L, Vincenzo B, Pietro S, et al. Development and characterization of sulfonated polysulfone membranes for direct methanol fuel cells [J]. Desalination, 2006,199 (1–3): 283-285.
[30] Dyck A, Fritsch D, Nunes S P. Proton-conductive membranes of sulfonated polyphenylsulfones [J]. Journal of applied polymer science, 2002, 86(11): 2820–2827.
[31] Byun I S, Kim I C, Seo J W. Pervaporation behavior of asymmetric sulfonated polysulfones and sulfonated poly (ether sulfone) membranes [J]. Journal of applied polymer science, 2000, 76 (6):787-798.
[32] Li Y, Chung T S. Exploration of highly sulfonated polyethersulfone (SPES) as a membrane material with the aid of dual-layer hollow fiber fabrication technology for protein separation [J]. Journal of Membrane Science, 2008, 309(1-2):45-55.
[33] Lu D P, Zou H, Guan R, et al. Sulfonation of polyethersulfone by chlorosulfonic acid[J], Polymer Bulletin, 2005,54:21–28.
[34] Wang J W, Yue Z R, Scott Ince J, et al. Preparation of nanofiltration membranes from polyacrylonitrile ultrafiltration membranes [J]. Journal of Membrane Science, 2006, 286(1-2):333-341.
[35] 黄健,王晓琳.低温等离子体对聚合物多孔膜的亲水化改性[J].高分子通报3(6)(2005)16-21
[36] Steen M L, Jordan A C , Fisher E R. Hydrophilic modification of polymeric membranes by low temperature H2O plasma treatment [J]. Journal of Membrane Science. 2002, 204(1-2): 341-357.
[37] Bhta N V, Wavhal D S. Prepatation of cellulose triacetate pervaporation membrane by ammonia plasma treatment [J]. Journal Applied Polymer Science, 2000, 76(2): 258-265.
[38] Caro J C, Lappan U, Simon F, et al. On the low-pressure plasma treatment of PTFE (polytetrafluoroethylene) with SO2 as process gas [J]. European Polymer Journal, 1999, 35(6):1149-1152.
[39] Dattatray S Wavhal, Ellen R Fisher. Hydrophilic modification of polyethersulfone membranes by low temperature plasma-induced graft polymerization [J]. Journal of Membrane Science, 2002, 209(1): 255-269.
[40] Chen H, Belfort G. Surface modification of poly(ether sulfone) ultrafiltration membranes by loe-temperatyre plasma-induced graft polymerization[J]. Journal Applied Polymer Science, 1999, 72(13): 1699-1711.
[41] 陆晓峰,卞晓锴.超滤膜的改性研究及应用[J].膜科学与技术2003,23(4):97-102 
[42] 金晓懿,张茜,沈新元,吉亚丽.壳聚糖-聚丙烯腈复合纳滤膜的氨气等离子体改性[J].功能高分子学报,2012,25(4):374-380.
[43] Volkov A V, Tsarkov S E, Gilman A B, et al. Surface modification of PTMSP membranes by plasma treatment:Asymmetry of transport inorganic solvent nanofiltration [J]. Advances in Colloid and Interface Science,2015,222 :716–727.
[44] 张茜,沈新元.乙二胺与氮气混合气体等离子体改性壳聚糖-聚丙烯腈复合纳滤膜[J].材料导报2014,28(11):5-11.
[45] Mohammad P, Toraj M, Omid B. Effective treatment of dye wastewater via positively charged TETAMWCNT/PES hybrid nanofiltration membranes [J]. Separation and Purification Technology 2018, 194:488-502.
[46] Bagheripour E., Moghadassi A.R.,Hosseini S.M., et al. Highly hydrophilic and antifouling nanofiltration membrane incorporated with water-dispersible composite activated carbon/chitosan nanoparticles[J]. Chemical Engineering Research and Design, 2018, 132: 812–821.
[47] Gisya A, Abdolhamid A, Sirus Z. Removal of dye and heavy metal ion using a novel synthetic polyethersulfone nanofiltration membrane modified by magnetic grapheme oxide/metformin hybrid [J]. Journal of Membrane Science, 2018,552:326–335.
[48] Rajeswari A, Vismaiya S, Pius A. Preparation, characterization of nano ZnO-blended cellulose acetate-polyurethane membrane for photocatalytic degradation of dyes from water [J].Chemical Engineering Journal, 2017,313 : 928–937.
[49] Zeng G Y, He Y, Zhan Y Q, et al. Novel polyvinylidene fluoride nanofiltration membrane blended with functionalized halloysite nanotubes for dye and heavy metal ions removal [J]. Journal of Hazardous Materials, 2016,317: 60–72.
[50] Nikooe N, Saljoughi E, Preparation and characterization of novel PVDF nanofiltration membranes with hydrophilic property for filtration of dye aqueous solution [J]. Applied Surface Science, 2017, 413: 41–49.
[51] Abbas Babaei Rostam, Majid Peyravi, Mohsen Ghorbani, et al. Antibacterial surface modified of novel nanocomposite sulfonated polyethersulfone/polyrhodanine membrane [J]. Applied Surface Science, 2018,427:17–28.
[52] Meng N, Zhao Wa, Shamsaei E, et al. A low-pressure GO nanofiltration membrane crosslinked via ethylenediamine [J]. Journal of Membrane Science, 2018, 548: 363–371.
[53] Kang H, Shi J, Liu L Y, et al. Sandwich morphology and superior dye-removal performances for nanofiltration membranes self-assemblied via graphene oxide and carbon nanotubes [J]. Applied Surface Science, 2018, 428: 990–999.
[54] Chen L, Moon J H, Ma X X, et al. High performance graphene oxide nanofiltration membrane prepared by electrospraying for wastewater purification [J]. Carbon, 2018, 130: 487-494.

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号