膜科学与技术

强化自组装技术在多层复合分离膜领域的应用

作者：纪树兰，张国俊

单位：北京工业大学环境与能源工程学院

关键词：强化自组装；聚电解质复合物膜；渗透汽化

出版年,卷(期):页码： 2011,31(3):156-161

摘要：

强化自组装技术是近年来被发展的一种制备聚电解质复合物多层膜的新方法，该法巧妙地利用外加力与聚合物间作用力的协同效应，强化组装过程，简化成膜程序，提高膜分离性能。本文总结了近年来课题组在这一领域的研究进展。

Enhanced self-assembly technology is a kind of novel method for preparing polyelectrolyte complex multilayer membrane in recent years. The method combined of electrostatic adsorption of oppositely charged polyelectrolyte with the external electric force could facilitate the assembly of polyelectrolyte composite membranes and improved separation performance of membrane. Some research progress of our group in this field was summarized in this paper.

纪树兰（1953 -）, 女，北京人，教授、博导，主要从事膜分离及水处理技术

参考文献：

[1] Decher G. Fuzzy nanoassemblies: Toward layered polymeric multicomposites[J]. Science, 1997, 277 (29):1232-1237.
[2] Zhang Xi, Chen Huan, Zhang Hongyu. Layer-by-layer assembly: from conventional to unconventional methods [J]. Chem Commun, 2007, (14):1395-1405.
[3] Toutianoush A, Krasemann L, Tieke B. Polyelectrolyte multilayer membranes for pervaporation separation of alcohol/water mixtures[J], Colloids Surf, A: Physicochemical and Engineering Aspects , 2002,198-200:881-889.
[4] Krasemann L, Toutianoush A, Tieke B. Self-assembled polyelectrolyte multilayer membranes with highly improved pervaporation separation of ethanol/water mixtures [J]. J Membr Sci, 2001, 181:221-228.
[5] Toutianoush A, Tieke B. Pervaporation separation of alcohol/water mixtures using self-assembled polyelectrolyte multilayer membranes of high charge density [J]. Mater Sci Eng C, 2002, 22: 459-463.
[6] Li X, Feyter S, Chen D, et al. Solvent-Resistant nanofiltration membranes based on multilayered polyelectrolyte complexes [J]. Chem Mater, 2008, 20(12): 3876-3883.
[7] Li X, Goyensa W, Ahmadiannaminia P, et al. Morphology and performance of solvent-resistant nanofiltration membranes based on multilayered polyelectrolytes: Study of preparation conditions [J]. J Membr Sci, 2010, 358(1-2):150-157.
[8] Chen Yiwei, Xiangli Fenjuan, Jin Wanqin, et al. Organic-inorganic composite pervaporation membranes prepared by self-assembly of polyelectrolyte multilayers on macroporous ceramic supports [J]. J Membr Sci, 2007, 302:78-86.
[9] Zhao Qiang, Qian Jinwen, An Quanfu, et al. Pervaporation dehydration of isopropanol using homogeneous polyelectrolyte complex membranes of poly(diallyldimethylammonium chloride)/sodium carboxymethyl cellulose[J]. J Membr Sci, 2009, 329:175-182.
[10] Zhao Qiang, Qian Jinwen, An Quanfu, et al. Synthesis and characterization of soluble chitosan/sodium carboxymethyl cellulose polyelectrolyte complexes and the pervaporation dehydration of their homogeneous membranes [J]. J Membr Sci, 2009, 333:68-78
[11] Zhang Guojun, Gu Weiliang, Ji Shulan, et al. Preparation of polyelectrolyte multilayer membranes by dynamic layer-by-layer process for pervaporation separation of alcohol/water mixtures [J]. J Membr Sci, 2006, 280:727-733.
[12] Zhang Guojun, Yan Haihong, Ji Shulan, et al. Self-Assembly of polyelectrolyte multilayer pervaporation membranes by a dynamic layer-by-layer technique on a hydrolyzed polyacrylonitrile ultrafiltration membrane[J]. J Membr Sci, 2007, 292:1-8.
[13] Zhang Guojun, Gao Xue, Ji Shulan, et al. One-step dynamic assembly of polyelectrolyte complex membrane [J]. Mater. Sci. Eng., C, 2009，29 (6):1877-1884.
[14] Zhang Guojun, Song Xue, Ji Shulan, et al. Self-assembly of inner skin hollow fiber polyelectrolyte multilayer membranes by a dynamic negative pressure layer-by-layer technique [J]. J Membr Sci, 2008, 325: 109-116.
[15] Zhang Guojun, Wang Naixin, Song Xue, et al. Preparation of pilot-scale inner skin hollow fiber pervaporation membrane module: effects of dynamic assembly conditions [J]. J Membr Sci, 2009, 338: 43-50.
[16] Zhang Guojun, Gao Xue, Ji Shulan, et al. Electric field-enhanced assembly of polyelectrolyte composite membranes [J]. J Membr Sci, 2008, 307:151-155
[17] 高学,张国俊,纪树兰,等.电场强化组装聚电解质复合物膜研究[J].膜科学与技术,2008,28(4):97-100.
[18] Deng Huiyu, Xu Youyi, Zhu Baoku, et al. Polyelectrolyte membranes prepared by dynamic self-assembly of poly(4-styrenesulfonic acid-co-maleic acid) sodium salt (PSSMA)for nanofiltration (I) [J]. J Membr Sci, 2008, 323: 125-133.
[19] Wang Jinwen, Yao Yaxuan, Yue Zhongren, et al. Preparation of polyelectrolyte multilayer films consisting of sulfonated poly(ether ether ketone) alternating with selected anionic layers [J]. J Membr Sci, 2009, 337: 200-207.
[20] Zhang Peng, Qian Jinwen, Yang Yang, et al. Polyelectrolyte layer-by-layer self-assembly enhanced by electric field and their multilayer membranes for separating isopropanol-water mixtures [J]. J Membr Sci, 2008, 320:73-77.
[21] Zhang Peng, Qian Jinwen, An Quanfu, et al. Surface morphology and pervaporation performance of electric field enhanced multilayer membranes [J]. J Membr Sci, 2009, 328:141-147.
[22] Wang Naixin, Zhang Guojun, Ji Shulan, et al. The salt-, pH- and oxidant-responsive pervaporation behaviors of weak polyelectrolyte multilayer membranes [J]. J Membr Sci, 2010, 354:14-22.
[23] Zhang Guojun, Ruan Zhengang, Ji Shulan, et al. Construction of metal-ligand-coordinated multilayers and their selective separation behavior [J]. Langmuir, 2010, 26: 4782-4789.
[24] Zhang Guojun, Dai Limin, Ji Shulan. Dynamic pressure-driven covalent assembly of inner skin hollow fiber multilayer membrane [J]. AIChE Journal, 2010, DOI:10.1002/aic.12481.

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com