海水淡化反渗透膜支撑层的制备与表征
作者:杨峰  周尚寅  潘窔伊 潘巧明
单位: 杭州北斗星膜制品有限公司 浙江 杭州 310022
关键词: 支撑层;二甲基甲酰胺;耐压密性
出版年,卷(期):页码: 2014,34(3):59-62

摘要:
以100μm聚酯(PET)无纺布为基材,聚砜(PS)为溶质,二甲基甲酰胺(DMF)和二甲基乙酰胺(DMAC)为溶剂配置铸膜液,纯水做为凝固浴,用浸没沉淀相转法化法制备支撑层,并以界面聚合反应的方式制备了海水淡化反渗透膜。对所形成支撑层的结构、纯水通量、比表面积、孔容、平均孔径、海水淡化反渗透膜的压密性能以及压密前后的脱盐率和水通量进行测定及表征。结果表明,以PS为溶质,DMF为溶剂的铸膜液,制备的支撑层耐压密性好,适用于海水淡反渗透膜的制备。
In this study, porous support layer was prepared by immerse precipitation phase inversion method with polyester (PET) (100 μm) non-woven fabric as reinforced material, polysulfone (PS) as solute, dimethylformamide (DMF) and dimethylacetamide (DMAC) as solvents, pure water as coagulation bath, and the obtained porous support membrane was used to prepared seawater desalination reverse osmosis desalination membrane through interfacial polymerization technique. The morphological structure , pure water flux, specific surface area, pore volume, average pore size of the support layer , the compaction resistance of seawater desalination reverse osmosis membrane and and salt rejection and water flux of seawater desalination reverse osmosis membrane before and after compaction were measured and characterized. Results showed that compaction resistance of the support layer which was prepared using DMF as solvent was good and could be used for the preparation of seawater desalination reverse osmosis membran
杨峰(1983-),男,浙江诸暨人,工程师,从事液体分离膜研究。通讯作者E-mail:yfinhz@163.com

参考文献:
[1]解利昕,李凭力,王世昌.海水淡化技术现状及各种淡化方法评述[J].化工进展,2003,22(10):1081-1084.
[2]刘忠.多效鼓泡蒸发式太阳能海水淡化技术研究[D].杭州:浙江大学,2010.
[3]任宏波,相凤奎,张磊等.水合物法海水淡化技术应用进展[J].海洋地质前沿,2011,27(6):74-78.
[4]邬晓龄,黄肖容,邓尧.海水淡化技术现状与展望[J].当代化工 ,2012,41(9):964-966.
[5]戴玉玲,张建国,贾铭椿.反渗透技术的研究进展及应用[J].广州化工,2012,40(10):24-26.
[6]C. E. Reid, E. J. Breton.Water and ion flow across cellulosic membranes[J].J Appl Polym Sci,1959,1(2):133-134.
[7]Loeb S, Sourirajan S. Sea Water Demineralization by Means of an Osmotic Membrane[A].Robert F. Gould.Saline Water Conversion—II[C].Washington DC: American Chemical Society,1963. 117-132.
[8]王学松.现代膜技术及其应用指南[M].北京:化学工业出版社,2007.523-524.
 
[9]Howard M. Colquhoun, Andrew L. Lewis, David J. Williams, et al.Hydrophilic poly-ylids derived from 4,4′-bipyridyl: synthesis, structure and membrane-forming characteristics[J].Polymer,1995,36(2):443-446.
[10]魏菊.杂萘联苯聚醚砜酮超滤膜及其复合膜的研究[D].大连:大连理工大学,2007.

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