碳酸钙形貌对陶瓷膜过滤性能的影响
作者:江文叶,胡俭,张峰,邢卫红
单位: 南京工业大学化学化工学院,国家特种分离膜工程技术研究中心,江苏 南京,210009
关键词: 碳酸钙;陶瓷膜;形貌
出版年,卷(期):页码: 2014,34(4):1-5

摘要:
 陶瓷膜进行超细粉体的固液分离时,粉体性质对膜分离性能影响显著。本文通过控制沉淀反应条件,获得了球形、棒状、方形等不同形貌的碳酸钙超细粉体;采用陶瓷膜过滤碳酸钙悬浮液,得到膜孔径与碳酸钙粉体粒径、形貌的匹配关系,球形粉体的膜渗透通量最高,棒状束粉体居中,方形粉体的膜渗透通量最小;膜孔径越大,粉体形貌对通量的影响越大;粉体粒径与膜孔径比值增大,膜通量增大
 Ceramic membrane was widely used to separateultrafinepowder suspension. The separation performance was significantlyinfluenced by the properties of particles. The spherical powder, square powder and bundle of rod-like powder of CaCO3 were obtained respectively through controlling the precipitationreaction conditions.The matching relations between pore size of membrane and the properties of particlessuch as size and morphologywere got. The order of the flux of ceramic membrane for separating particlesuspension was:spherical powder> bundle of rod-like powder>square powder. The larger the pore size of ceramic membrane was,the greater influence of morphology of powder on separation performance was. The flux increasedwith the increasing of ratio of particalsize and pore size of ceramic membrane.
江文叶,(1987-),女,江苏连云港人,硕士研究生,研究方向为膜分离;邢卫红(联系人),研究员, E-mail:xingwh@njut.edu.cn

参考文献:
[1] 蔡国斌. 无定形碳酸钙的一些合成、转化及性质研究[D].合肥: 中国科技大学, 2010.
[2]赵风云, 王琰, 王勇等. 针形纳米碳酸钙的表面改性及在PVC中的应用.[J].高分子材料科学与工程, 2008, 24(2): 124-127.
[3] Yue, L.H., Zheng,Y.F., Jin, D.L. Spherical porous framework of calcium carbonate prepared in the presence of precursor PS–PAA as template.[J].Microporous and Mesoporous Materials, 2008, 113(1-3): 538-541.
[4] Flaten, E.M., Seiersten, M., Andreassen, J.P. Polymorphism and morphology of calcium carbonate precipitated in mixed solvents of ethylene glycol and water.[J]. Journal of Crystal Growth, 2009, 311(13): 3533-3538.
[5] Yan, G.W., Wang, L., Huang, J.H. The crystallization behavior of calcium carbonate in ethanol/water solution containing mixed nonionic/anionic surfactants.[J]. Powder Technology, 2009, 192(1): 58-64.
[6] Belfort G., Davis R.H., Zydney A.L. The behavior of suspensions and macromolecular.[J]. Journal of Membrane Science, 1994, 96(1): 158.
[7]钟璟, 徐南平, 时钧. 颗粒粒径和膜孔径对陶瓷膜微滤微米级颗粒悬浮液的影响.[J].高校化学工程学报, 2000, 14(3): 230-234.
[8] Dong Q., Liu X.Q., Zhang T.S. Ceramic membrane separation technique for washing nano-sized ceramicpowder precursors.[J]. Particuology, 2011, 9(5): 492-496.
[9]崔鹏, 陈桂娟, 赵先治.无机陶瓷膜微滤分离凹凸棒土悬浮液.[J].化学工程,2008,36(12):37-41.
[10]ZhongZ.X.,XingW.H.,Liu X.,etal.Fouling and regeneration of ceramic membranes used in recovering titanium silicalite-1 catalysts.[J].Journal of Membrane Science,2007,301(1-2):67-75.
[11]Hwang, K.J., Chen, H.C., Tsai, M.H. Analysis of Particle Fouling in Constant Pressure Submerged Membrane Filtration.[J]. Chemical Engineering & Technology, 2010, 33(8): 1327-1333.
[12] 徐南平, 李卫星, 赵宜江等. 面向过程的陶瓷膜材料设计理论与方法(Ⅰ)膜性能与微观结构关系模型的建立[J].化工学报, 2003, 54(9): 1284-1289.
 

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号