液膜技术在钴分离中的应用及研究进展
作者:武彦斌,王三反,李广,王翠,张昊
单位: 兰州交通大学环境与市政工程学院 寒旱区水资源综合利用教育部工程研究中心,甘肃兰州 730070
关键词: 钴分离;乳状液液膜;支撑液膜;聚合物包涵体膜
出版年,卷(期):页码: 2015,35(3):126-130

摘要:
液膜技术作为一种具有潜在实用价值的分离技术,受到科研界的极大关注。本文总结了当前存在的主要液膜技术类型,简述了其在废水处理及湿法冶金中钴的分离和提取方面的应用,并对今后液膜技术的发展进行了展望。指出,随着对液膜技术实用化研究的不断深入,液膜技术有望在工业生产中引领新的革命。
Abstract:Liquid membrane technology as a separation technique of potential practical value ,has been paid great attention by scientific community . In this paper, the main types of current film technology were summarized ,the separation and extraction of cobalt in the treatment of wastewater and its hydrometallurgy applications were presented ,and the the future development of membrane technology was prospected .Finally, with the research on the film technology unceasingly thorough, liquid membrane technology will lead the new revolution in industrial production promisingly.
 
武彦斌(1989-),男,河北省藁城市人,硕士生,研究方向市政工程,E-mail:wybvsls@163.com

参考文献:
 
[1]石国亮, 李增波, 郭雨. 液膜分离技术及其应用研究进展[J]. 化学工程师, 2009, 23(5): 48-50.
[2]莫启武. 液膜法在贵金属分离富集中的应用[J]. 贵金属, 1996, 17(2): 46-49.
[3]Heckley P S, Ibana D C. Extraction and separation of nickel and cobalt by electrostatic pseudo liquid membrane[J]. Membrane Technology, 2003, 2003(5): 8-11.
[4]严忠, 孙文东. 乳液液膜分离原理及应用[M]. 化学工业出版社化学与应用化学出版中心, 2005.1~2.
[5]孙玉柱. 乳状液膜分离技术的研究进展 [J]. 湿法冶金, 2005, 24(4): 10-17.
[6]Bourenane S, Samar M E H, Abbaci A. Extraction of cobalt and lead from waste water using a liquid surfactant membrane emulsion[J]. Acta chimica slovenica, 2003, 50(4): 663-676.
[7]张超, 钟宏, 王帅. 镍, 钴分离与回收技术研究进展[J]. 铜业工程, 2011 (5): 29-32.
[8]Dimitrov K, Rollet V, Saboni A. Cobalt recovery from sulfate media applying a liquid membrane containing Cyanex 302[J]. Chemical engineering & technology, 2006, 29(5): 625-630.
[9]Kumbasar R A. Cobalt–nickel separation from acidic thiocyanate leach solutions by emulsion liquid membranes (ELMs) using TOPO as carrier[J]. Separation and Purification Technology, 2009, 68(2): 208-215.
[10]Kumbasar R A. Separation and concentration of cobalt from zinc plant acidic thiocyanate leach solutions containing cobalt and nickel by an emulsion liquid membrane using triisooctylamine as carrier[J]. Journal of Membrane Science, 2009, 333(1): 118-124.
[11]Kumbasar R A, Tutkun O. Separation of cobalt and nickel from acidic leach solutions by emulsion liquid membranes using Alamine 300 (TOA) as a mobile carrier[J]. Desalination, 2008, 224(1): 201-208.
[12]Kumbasar R A. Separation and concentration of cobalt from aqueous thiocyanate solutions containing cobalt–nickel by emulsion liquid membranes using TBP as extractant[J]. Journal of Membrane Science, 2009, 338(1): 182-188.
[13]Kumbasar R A. Selective extraction of cobalt from strong acidic solutions containing cobalt and nickel through emulsion liquid membrane using TIOA as carrier[J]. Journal of Industrial and Engineering Chemistry, 2012, 18(6): 2076-2082.
[14]Kumbasar R A, Kasap S. Selective separation of nickel from cobalt in ammoniacal solutions by emulsion type liquid membranes using 8-hydroxyquinoline (8-HQ) as mobile carrier[J]. Hydrometallurgy, 2009, 95(1): 121-126.
[15]Ribeiro Jr C P, Costa A O S, Lopes I P B, et al. Cobalt extraction and cobalt–nickel separation from a simulated industrial leaching liquor by liquid surfactant membranes using Cyanex 302 as carrier[J]. Journal of membrane science, 2004, 241(1): 45-54.
[16]Kumbasar R A, ?ahin ?. Separation and concentration of cobalt from ammoniacal solutions containing cobalt and nickel by emulsion liquid membranes using 5, 7-dibromo-8-hydroxyquinoline (DBHQ)[J]. Journal of Membrane Science, 2008, 325(2): 712-718.
[17]Kumbasar R A. Selective transport of cobalt (II) from ammoniacal solutions containing cobalt (II) and nickel (II) by emulsion liquid membranes using 8-hydroxyquinoline[J]. Journal of Industrial and Engineering Chemistry, 2012, 18(1): 145-151.
[18]Bukhari N,Chaudry M A, Mazhar M. Cobalt (II) transport through triethanolamine-cyclohexanone supported liquid membranes[J]. Journal of membrane science, 2004, 234(1): 157-165.
[19]Surucu A, Eyupoglu V, Tutkun O. Selective separation of cobalt and nickel by flat sheet supported liquid membrane using Alamine 300 as carrier[J]. Journal of Industrial and Engineering Chemistry, 2012, 18(2): 629-634.
[20]Sürücü A, Eyüpoglu V, Tutkun O. Selective separation of cobalt and nickel by supported liquid membranes[J]. Desalination, 2010, 250(3): 1155-1156.
[21]陈银, 张云燕, 李雪梅, 等. 金属离子提取的支撑型液膜稳定性: 膜材料研究进展[J]. 化学进展, 2011, 23(5): 1033-1040.
[22]Kozlowski C A, Kozlowska J, Pellowski W, et al. Separation of cobalt-60, strontium-90, and cesium-137 radioisotopes by competitive transport across polymer inclusion membranes with organophosphorous acids[J]. Desalination, 2006, 198(1): 141-148.
[23]Po?piech B, Walkowiak W. Separation of copper (II), cobalt (II) and nickel (II) from chloride solutions by polymer inclusion membranes[J]. Separation and Purification Technology, 2007, 57(3): 461-465.
[24]Kagaya S, Cattrall R W, Kolev S D. Solid-phase extraction of cobalt (II) from lithium chloride solutions using a poly (vinyl chloride)-based polymer inclusion membrane with Aliquat 336 as the carrier[J]. Analytical sciences: the international journal of the Japan Society for Analytical Chemistry, 2010, 27(6): 653-657.
[25]张瑞华.液膜分离技术[M].南昌:江西人民出版社,1984.
[26]顾忠茂,万印华,朱国斌.液膜[A].时钧,袁权,高从堦.膜技术手册[C].第13章.北京:化学工业出版社2001. 626~677.
 

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