膜科学与技术

染料分离有机纳滤膜制备技术研究进展

作者：石紫，王志，王宠，王纪孝

单位：天津大学化工学院化学工程研究所，天津市膜科学与海水淡化技术重点实验室，化学工程联合国家重点实验室(天津大学)，天津化学化工协同创新中心，天津 300350

关键词：纳滤膜；染料分离；膜制备；界面聚合；研究进展

出版年,卷(期):页码： 2020,40(1):340-351

摘要：

粗染料纯化与染料、印染废水处理是染料工业的重中之重，两者的根本目的都是实现染料与无机盐的高效分离。利用纳滤膜对染料高截留和对无机盐离子低截留等特点，可以实现含盐染料溶液的高效脱盐浓缩。本文着重综述了近年来研究者采用相转化、多孔基膜表面改性、层层组装和界面聚合等方法制备染料分离纳滤膜所取得的研究进展，并对以上制膜方法存在的问题和适用的分离体系进行了深入分析。最后，基于目前纳滤法纯化染料及处理染料、印染废水存在的问题，对染料分离纳滤膜研究方向和发展前景进行了总结与展望。

Crude dye purification and dyeing and printing wastewater treatment are significant in dye industry. For both of them, the fundamental goal is to achieve efficient separation of dyes and inorganic salts. Nanofiltration membranes possessing high dye retention and low inorganic salt retention can effectively achieve desalination and concentration of dyes in salt-containing dye solutions. In this review, the research progresses of dye separation nanofiltration membranes prepared by phase inversion, surface modification of porous membranes, layer-by-layer assembly and interfacial polymerization were reviewed, and the shortages and suitable separation systems of these methods were analyzed deeply. In the end, based on the existing issues of nanofiltration technique in crude dye purification and dyeing and printing wastewater treatment currently, the research directions and development prospects of dye separation nanofiltration membranes were summarized and forecasted.

第一作者简介：石紫（1995-），女，河北承德人，硕士，从事纳滤膜制备研究. ＊通讯作者，E-mail：wangzhi@tju.edu.cn

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