聚苯硫醚分离膜材料研究进展
作者:张伟元1,高原23,张马亮23,李振环23
单位: 1. 冀中能源峰峰集团有限公司,河北 邯郸 056001;2. 天津工业大学 省部共建分离膜与膜过程国家重点实验室,天津 300387;3. 天津工业大学 材料科学与工程学院,天津 300387
关键词: 聚苯硫醚分离膜;热致相成形技术;熔融拉伸技术;熔喷技术;膜过滤
出版年,卷(期):页码: 2020,40(6):127-132

摘要:
随着过程工业的发展,医药、能源、石化、冶炼等领域的废弃溶剂、高浓污水、高温尾气、腐蚀性固废等已成为行业持续发展的瓶颈,对生命健康和环境质量造成了巨大的危害。聚苯硫醚(PPS)分离膜材料具有优异的耐酸、耐碱和耐有机溶剂腐蚀性能,在上述苛刻环境下的分离领域具有优良的应用前景。本文针对分离膜用PPS树脂合成及改性、PPS分离膜制备方法和PPS分离膜改性及应用等方面进行了阐述,分析了目前PPS分离膜的研究进展,指出了现存的不足之处,展望了PPS分离膜的发展前景和未来发展方向。
 With the development of process industry, the waste solvents, high concentration sewage, high temperature tail gas and corrosive solid waste et al in medicine, energy, petrochemical, smelting and other fields have become the bottleneck of sustainable development of the industry, and they have the great harm to life, health and environmental quality. Polyphenylene sulfide (PPS) separation membrane material has the excellent acid, alkali and organic solvent corrosion resistance, and it exhibits the good application in the separation field under the above descried the harsh environment condition. This paper described the progress of PPS resin synthesis and modification, PPS separation membrane, modification and application et al. The research progress of PPS separation membrane at present was analyzed, the existing shortcomings were pointed out, and the development prospect and direction of PPS separation membrane in the future were prospected.
张伟元(1967),男,籍贯:河北保定市,职称:高级工程师,学历:本科,学位:学士,研究方向:煤化工,E-mail:1337441561@qq.com

参考文献:
[1] 杜润红, 赵家森. 一种新的膜材料-聚苯硫醚[J]. 膜科学与技术, 2002, 22(3): 56-59.
[2] 王丽华, 盛京, 赵家森. 聚苯硫醚中空纤维微滤膜的研究(Ⅱ)——拉伸工艺对中空纤维结构与性能的影响[J]. 纺织学报, 2004, 25(1): 25-27.
[3] 王丽华, 盛京, 赵家森. 聚苯硫醚中空纤维微滤膜的研究-中空纤维的纺[J]. 纺织学报, 2003, 24(4): 73-74.
[4] Pervin S, Prabu A, Kim K, et al. Preparation and evaluation of poly(vinylidene fluoride)-sulfonated poly(1,4-phenylene sulfide) based membranes with improved hydrophilicity[J]. Macromol Res, 2015, 23(1): 86-93.
[5] Schauer J, Bro?ová L. Heterogeneous ion-exchange membranes based on sulfonated poly(1,4-phenylene sulfide) and linear polyethylene: preparation, oxidation stability, methanol permeability and electrochemical properties[J]. J Membr Sci, 2005, 250(1-2): 151-157.
[6] Schuster M, Araujo C, Atanasov V, et al. Highly Sulfonated Poly(phenylene sulfone): Preparation and Stability Issues[J]. Macromolecules, 2009, 42(8): 3129-3137.
[7] Hill H, Brady D. Properties, environmental stability, and molding characteristics of polyphenylene sulfide[J]. Polym Eng Sci, 1976, 16(12): 831-835.
[8] Tsuchida E, Shouji E, Yamamoto K. Synthesis of high-molecular-weight poly (phenylene sulfide) by oxidative polymerization via poly (sulfonium cation) from methyl phenyl sulfoxide[J]. Macromolecules, 1993, 26(26): 7144-7148.
[9] Rahate A, Nemade K, Waghuley S. Polyphenylene sulfide (PPS): state of the art and applications[J]. Rev Chem Eng, 2013, 29 (6): 471-489.
[10] Rahate A, Nemade K, Waghuley S. Polyphenylene sulfide (PPS): state of the art and applications[J]. Rev Chem Eng, 2013, 29(6): 471-489.
[11] Tsuchida E, Shouji E, Yamamoto K. Synthesis of high-molecular-weight poly(phenylene sulfide) by oxidative polymerization via poly(sulfonium cation) from methyl phenyl sulfoxide [J]. Macromolecules, 1993, 26(26): 7144–7148.
[12] Zhou Y, Cheng B, Li Z, et al. The High Temperature Gel Permeation Chromatography Study on Poly (Phenylene Sulfide) Linear Chain Propagation[J]. Adv Mater Res, 2010, 139-141: 661-665.
[13] Li C, Li Z, Cao L, et al. Graphene preparation by phenylmagnesium bromide and its excellent electrical conductivity performance in graphene/PPS composites[J]. Ind Eng Chem Res, 2016, 55(41): 10860-10867.
[14] Li C, Li Z, Zhang M, et al. SiC-fixed organophilic montmorillonite hybrids for poly(phenylene sulfide) composites with enhanced oxidation resistance[J]. RSC Adv, 2017, 7(74): 46678-46689.
[15] Zhang M, Wang X, Li C, et al. Effects of hydrogen bonding between MWCNT and PPS on the properties of PPS/MWCNT composites[J]. RSC Adv, 2016, 6(95): 92378-92386.
[16] Zhang M, Wang X, Li Z, et al. C60 as fine fillers to improve poly(phenylene sulfide) electrical conductivity and mechanical property[J]. Sci Rep, 2017, 7(1): 1-11.
[17] 小野善之. 微多孔中空纤维聚苯硫醚膜的制造法[P].日本, 日本公开特许公报.昭59-59917, 1984-04-05.
[18] 沈剑辉, 马洪波, 刘进等. 一种耐高温聚苯硫醚中空纤维膜及其制备方法[P].中国,CN107224881A. 2017-10-03.
[19] Zheng H, Zhu S, Yu W, et al. Comparison of Various Solvents for Poly(Phenylene Sulfide) Microporous Membrane Preparation via Thermally Induced Phase Separation[J]. J Macromol Sci B, 2014, 53(9): 1477-1496.
[20] Ding H, Zhang Q, Wang F, et al. Structure control of polyphenylene sulfide membrane prepared by thermally induced phase separation[J]. J Appl Polym Sci, 2007, 105(6): 3280-3286.
[21] Ding H, Zeng Y, Meng X, et al. Porous polyphenylene sulfide membrane with high durability against solvents by the thermally induced phase-separation method[J]. J Appl Polym Sci, 2006, 102(3): 2959-2966.
[22] 王丽华. 聚苯硫醚中空纤维微滤膜的研究[D]. 天津: 天津工业大学,2000.
[23] Wang L, Ding H, Shi Y, et al. Effect of Diluent Mixture on Porous Structure of Polyphenylene Sulfide via Thermally Induced Phase Separation[J]. J Macromol Sci A, 2009, 46(11): 1122-1127.
[24] Wang X, Li Z, Zhang M, et al. Preparation of a polyphenylene sulfide membrane from a ternary polymer/solvent/non-solvent system by thermally induced phase separation[J]. RSC Adv, 2017, 7(17): 10503-10516.
[25] Xu Y, Li Z, Su K, et al. Mussel-inspired modification of PPS membrane to separate and remove the dyes from the waste water[J]. Chem Eng J, 2018, 341: 371-382.
[26] Gao Y, Li Z, Cheng B, et al. Superhydrophilic poly(p-phenylene sulfide) membrane preparation with acid/alkali solution resistance and its usage in oil/water separation[J]. Sep Purif Technol, 2018, 192: 262–270.
[27] Wang C, Li Z, Cheng B. A superhydrophilic and anti-biofouling polyphenylene sulfide microporous membrane with quaternary ammonium salts[J]. Macromol Res, 2018, 26, 800-807.
[28] 李振环,王超,程博闻. 负载Ag纳米粒子的PPS膜的制备及其抗生物污染性能[J]. 天津工业大学学报,2018,37(6): 19-23.
[29] 王海霞, 李振环, 程博闻. 环氧化功能碳纳米管改性氨基PPS[J]. 复合材料学报, 2016, 33(11): 2468-2476.
[30] Fan T, Li Z, Cheng B, et al. Preparation, characterization of PPS micro-porous membranes and its excellent performance in vacuum membrane distillation[J], J Membr Sci, 2018, 556: 107-117.
[31] Fan T, Li Z, Cheng B. Study on the fabrication and properties of polyphenylene sulfide (PPS) membrane and its application in VMD[J], Desalin Water Treat, 2018, 129: 309-318.
[32] Bai Y, Li Z, Cheng B, et al. Higher UV-shielding ability and lower photocatalytic activity of TiO2@SiO2/APTES and its excellent performance in enhancing the photostability of poly(p-phenylene sulfide)[J]. RSC Adv, 2017, 7(35): 21758-21767.
[33] Gao Y, Su K, Li Z, et al. Graphene oxide hybrid poly(p-phenylene sulfide) nanofiltration membrane intercalated by bis(triethoxysilyl) ethane[J], Chem Eng J, 2018, 352(12): 10-19.
[34] Gao L, Su K, Fan T, et al. Study on the structure and properties of PPS/PCNF hybrid membranes and their applications in wastewater treatment[J], Polymer, 2019, 176(8): 274-282.
[35] Fan T, Miao J, Li Z, et al. Bio-inspired robust superhydrophobic-superoleophilic polyphenylene sulfide membrane for efficient oil/water separation under highly acidic or alkaline conditions[J], J Hazard Mater, 2019, 373(3): 11-22.
[36] Gao Y, Su K, Wang X, et al. NGO/PA layer with disordered arrangement hybrid PPS composite[J], Desalination, 2019, 479(4): 114211-10.
[37] Gao Y, Su K, Wang X, et al. A metal-nano GO frameworks/PPS membrane with super water flux and high dyes interception[J], J Membr Sci, 2018, 574(12): 55-64.
[38] Han N, Yang C, Zhang Z, et al. Electrostatic assembly of a Titanium Dioxide@hydrophilic poly(phenylene sulfide) porous membrane with enhanced wetting selectivity for separation of strongly corrosive oil-water emulsions [J]. ACS Appl Mater Inter, 2019, 11 (38): 35479-35487.
[39] Yang C, Han N, Zhang W, et al. Adhesive-free in situ synthesis of a coral-like titanium dioxide@poly(phenylene sulfide) microporous membrane for visible-light photocatalysis[J]. Chem Eng J, 2019, 374: 1382-1393.
[40] Xu Y, Xiong S, Huang H, et al. Fabrication and application of poly (phenylene sulfide) ultrafine fiber[J]. React Funct Polym, 2020, 150: 104539.
[41] 熊思维,罗丹,严珺宝,等. 热轧压力和温度对聚苯硫醚熔喷非织造布性能的影响[J]. 产业用纺织品, 2017, 2: 16-21.
[42] 熊思维,严珺宝,赵正辉,等. 熔喷聚苯硫醚非织造布吸油性能研究[J]. 产业用纺织品, 2017, 9: 20-23.
[43] 何臣臣,殷先泽,彭家顺,等. 聚苯硫醚超细纤维负载零价铁去除六价铬的研究[J]. 合成纤维, 2017, 46(02): 31-35.
[44] Yu Y, Ren L, Liu M, et al. Polyphenylene sulfide ultrafine fibrous membrane modified by nanoscale ZIF8 for highly effective adsorption, interception, and recycling of Iodine vapor [J]. ACS Appl Mater Inter, 2019, 11(34): 31291-31301.
[45] Huang H, Zhao L, Yu Q, et al. Flexible and highly efficient bilayer photothermal paper for water desalination and purification: self-Floating, rapid water transport, and localized heat [J]. ACS Appl Mater Inter, 2020, 12(9): 11204-11213.

服务与反馈:
文章下载】【加入收藏

《膜科学与技术》编辑部 地址:北京市朝阳区北三环东路19号蓝星大厦 邮政编码:100029 电话:010-64426130/64433466 传真:010-80485372邮箱:mkxyjs@163.com

京公网安备11011302000819号