膜科学与技术

陶瓷前体聚合物应用于碳化硅陶瓷膜研究进展

作者：陈芝，刘阳，王姚，郭健，张君伟，陈雷，饶品华，李光辉

单位： 1上海工程技术大学化学化工学院，上海 201620；2山东赛利科膜科技有限公司，山东潍坊 262517

关键词：聚硅烷；陶瓷化；碳化硅；陶瓷膜；分离与纯化

出版年,卷(期):页码： 2022,42(3):163-171

摘要：

碳化硅陶瓷膜是新一代无机膜材料代表之一。近年来，陶瓷前体聚合物由于可溶、可熔、易于成型、加工温度低、可陶瓷化等优势不断被应用于碳化硅陶瓷膜的研究中，成为膜制备和性能提升的重要选择之一。本文系统总结了陶瓷前体聚合物参与制备碳化硅膜的方法及其优劣；深入探讨了陶瓷前体聚合物的引入对碳化硅膜亲疏水、导电、导热和耐腐蚀性等性能的影响；最后本文介绍了此类膜在气体或液体的分离、纯化方面的应用，并做出总结和分析。

Silicon carbide membrane is one of the representatives of a new generation of inorganic membrane materials. In recent years, ceramic precursor polymers have been continuously used in the research of silicon carbide ceramic membranes due to their advantages such as soluble, meltable, easy to form, low processing temperature, and ceramization, which have become one of the important choices for membrane preparation and performance improvement. This review systematically summarized the preparation methods and advantages and disadvantages of silicon carbide membranes with ceramized polymers. The effects of ceramic precursor polymers on the properties of silicon carbide membranes, such as hydrophilicity and hydrophobicity, electrical, thermal conductivity and corrosion resistance properties, were discussed in depth. Finally, this review introduced the application of such membranes in gas and liquid separation and purification and made a summary and analysis.

陈芝（1999-），女，陕西西安人，在读研究生，从事碳化硅陶瓷膜制备与分离应用

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