膜科学与技术

气体分离膜技术在天然气提氦中的研究进展

作者：郑佩君，谢成，白菊，蔡治礼，王璨，彭楠，罗双江

单位：沈阳化工大学能源与化工技术产业研究院化学工程学院 ,沈阳 110000;中国科学院过程工程研究所离子液体清洁过程北京市重点实验室 ,北京 100190;中国科学院理化技术研究所 ,北京 100190

关键词：天然气提氦 ;膜分离 ;气体分离膜 ;耦合工艺

出版年,卷(期):页码： 2022,42(6):168-177

摘要：

氦气是重要战略稀有气体资源 ●在国防军工、高端医疗、电子制造和大科学装置等领域都发挥着不可替代的作用.我国氦资源匮乏 ●绝大部分的氦气都依赖进口●现有资源品位低且提取因难 ●因此发展高效低成本的氦气提取技术对于保障我国氦资源安全具有重要意义.气体分离膜技术具有能效高、投资少、运行简单等优点 ●被认为是实现氦气高效、低成本提取的有效途径.本文系统回顾了气体分离膜技术在天然气提氦中的研究进展 ●总结本课题组及同行近年来开发的高性能天然气提氦膜材料的结构和气体分离性能 ●考察了气体分离膜与深冷技术耦合的天然气提氦工艺 ●深入分析了膜材料性能、膜运行条件和耦合工艺等对天然气提氦经济性的影响规律 ●并对天然气提氦技术的发展趋势进行了展望.

He1ium is an esentia1strategic rare gas resource that p1ays an irep1aceab1ero1ein nationa1 defense,high-end medica1,e1ectronicmanufacturing,and significantscientificdevices.China is short of he1ium resources,mostofwhich areimported,and theexistingresourcesareof1owgradeand dificu1tto extract.Therefore,deve1oping eficientand 1ow-costhe1ium extractiontechno1ogy isofgreatsignificance in ensuring the safety of he1ium resources in China. Membrane gas separation techno1ogy has the advantagesofhighenergyeficiency,1owinvestment,andsimp1eoperation,providinganefectivewayfor eficientand 1ow-cost he1ium extraction.This paper systematica1y reviews the research progres of gas separation membrane techno1ogy in natura1gas he1ium extraction, summarizes the structure and gas separationperformanceof high-performancenatura1gashe1ium extraction membranemateria1sdeve1oped by ourresearch group andpersin recentyears,andinvestigatesthenatura1gashe1ium extractionproces coup1ed with gas separation membrane and cryogenic techno1ogy. The efects of membrane materia1 properties,membraneoperating conditions,and coup1ing procesontheeconomyofhe1ium extractionare ana1yzed,and thedeve1opmenttrend ofhe1ium extractionisforecasted.

郑佩君(1996-),女 ,广东普宁人 ,硕士研究生 ,主要研究方向为高性能气体分离膜材料开发

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