膜科学与技术

响应曲面法对纳滤处理关闭煤矿山酸性废水的研究—五马河流域为例

作者：赵书晗，金修齐，邓强，张文兴，黄苑龄，张安丰

单位： 1.贵州省环境科学研究设计院，贵阳 550081；2.贵州省地质矿产中心实验室，贵州省贵金属矿产资源综合利用工程技术研究中心，贵阳 550018

关键词：煤矿山酸性废水；铁；锰；纳滤；响应曲面法；五马河

出版年,卷(期):页码： 2023,43(5):127-135

摘要：

本研究以贵州省仁怀市五马河流域关闭煤矿山酸性废水(Acid mine drainage, AMD)为例，采用纳滤膜处理技术进行实验研究。在单因素实验基础上，采用响应曲面法(Response surface methodology,RSM)建立以膜压差、铁、锰浓度为响应因素，膜通量、铁锰截留率、酸恢复率为响应值的回归模型。结果表明：在20℃，浓缩2.5倍，单次循环实验条件下，膜通量响应曲面模型拟合精度高，膜压差对膜通量影响显著，铁、锰浓度影响不显著；其他响应值模型拟合度均较低，不同响应因素条件下铁、锰截留率和酸恢复率无显著差异，主要污染物Fe截留率92.10~100%，锰79.01~98.81%，酸恢复效率95.2~123.6%，纳滤膜处理煤矿山AMD可有效截留主要污染物并高效分离酸。

This study conducts experimental research on treating acid mine drainage (AMD) using nanofiltration membrane, taking the AMD from closed coal mines in the Wuma river watershed of Renhuai City, Guizhou Province as an example. Response surface methodology(RSM) was employed to establish a model for the treatment of AMD based on a single-factor experiment. The results indicate that the model of permeate flows was significant under the conditions of 20 ℃, 2.5 times concentration and a single cycle experiment. Furthermore, trans-membrane pressure drop (TMP) was found to have a significant impact on permeate flows, while the iron and manganese concentration was found to be insignificant. The fitting degree of other RSM models was not significant, and there was no significant difference in iron retention rates, manganese retention rates and acid recovery rates under different response factors. The iron and manganese retention rates ranged from 92.10 to 100% and 79.01% to 98.81% ,respectively, while acid recovery rates ranged from 95.2 to 23.6%. These results suggest that the nanofiltration is efficient and stable during AMD treatment.

赵书晗（1991-），女，吉林省白城人，硕士研究生，工程师，研究方向：水污染防治，E-mail：2110767821@qq.com.

参考文献：

[1] Achaarya B S, Kharel G. Acid mine drainage from coal mining in the United States : An overview [J]. Journal of Hydrology, 2020, 588 : 125061.
[2] 任虎俊. 废弃煤矿岩溶地下水污染机理及防控研究——以贵州凯里鱼洞河流域为例 [D] : [博士论文]. 徐州 : 中国矿业大学, 2021.
[3] Simate G S, Ndlovu S. Acid mine drainage: Challenges and opportunities [J]. Journal of Environmental Chemical Engineering, 2014, 2(3) : 1785~803.
[4] 彭会清, 庞翠玲. 膜分离技术在处理酸性废液中的应用概述 [J]. 金属矿山, 2006, 9 : 14~17.
[5] Agboola O. The role of membrane technology in acid mine water treatment: a review [J]. Korean Journal of Chemical Engineering, 2019, 36(9) : 1389~400.
[6] 钟常明, 方夕辉, 许振良. 纳滤膜脱除矿山酸性废水中重金属离子试验研究 [J]. 环境科学与技术, 2007, 30(7) : 10~12.
[7] 李胤龙. 纳滤膜处理矿山废水中重金属离子的实验研究 [D]:[硕士论文]. 北京: 北京化工大学, 2011.
[8] 张聪慧. 纳滤膜处理大宝山铁泥拦泥坝尾矿库废水的研究 [D]:[硕士论文]. 赣州市: 江西理工大学, 2011.
[9] 李亚宁, 郝亚超, 李亮, 等. 响应曲面法优化纳滤去除废水中重金属离子的研究 [J]. 膜科学与技术, 2020, 40(6): 111~117.
[10] 王洁, 孙珮石, 方富林, 等. 纳滤膜处理含金属离子酸性废液 [J]. 膜科学与技术, 2010, 30(3) : 35~38.
[11] 郭敏俊, 屈撑囤, 车晓军. 纳滤水处理技术研究进展 [J]. 广州化工, 2016, 44(13) : 34~37.
[12] 李莉, 张赛, 何强, 等. 响应面法在试验设计与优化中的应用 [J]. 实验室研究与探索, 2015, 34(8) : 41~45.
[14] Bezerra M, Santelli R, Oliveira E, et al. Response Surface Methodology (RSM) as a Tool for Optimization in Analytical Chemistry [J]. Talanta, 2008, 76 : 965~977.
[14] 国家环境保护总局, 国家质量监督检验检疫总局. GB20426-2006, 煤炭工业污染物排放标准 [S]. 北京:中国环境科学出版社出版发行, 2006.
[15] 国家环境保护总局, 国家质量监督检验检疫总局. GB3838-2002, 地表水环境质量标准[S]. 北京. 2002.
[16] Han Y S, Youm S J, Oh C, et al. Geochemical and eco-toxicological characteristics of stream water and its sediments affected by acid mine drainage [J]. Catena, 2017, 148:52~59.
[17] Kefeni K K, Msagati T a M, Mamba B B. Acid mine drainage: Prevention, treatment options, and resource recovery: A review [J]. Journal of Cleaner Production, 2017, 151(MAY10) : 475~593.
[18] Burstein G T. The iron oxides: Structure, properties, reactions, occurrence and uses: R. M. Cornell and U. Schwertmann. 573 pp. VCH, Weinheim and New York, 1996. ISBN: 3-527-28576-8 [J]. Corrosion Science, 1997, 39(8) : 1499~1500.
[19] Silva R D A, Carlo S D S M, Jean, Lopes F A, et al. Synthesis of a Goethite Pigment by Selective Precipitation of Iron from Acidic Coal Mine Drainage [J]. Mine Water and the Environment, 2017, 36(3) : 386~392.

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com