膜科学与技术

聚酰胺薄层复合膜的耐氯改性研究进展

作者：黄河清，辛俊伟，来仁杰，王旭东，吕永涛，王磊

单位：西安建筑科技大学环境与市政工程学院，陕西省膜分离重点实验室，陕西省膜分离技术研究院，西安 710055

关键词：聚酰胺薄层复合膜；活性氯；氯化机理；耐氯改性

出版年,卷(期):页码： 2023,43(5):190-201

摘要：

易氯化降解制约了聚酰胺薄层复合膜（PA-TFC膜）在脱盐和工业分离等领域的进一步推广和应用。对此，本文归纳了PA-TFC膜受活性氯攻击的氯化机理研究现状，在此基础上，从复合膜结构出发，着重综述了该类型膜耐氯改性的最新研究进展，包括表面改性、PA层改性、支撑层改性和构筑新型耐氯分离层。最后进行总结并作出展望，以期为提升PA-TFC膜的耐氯性能及长期运行稳定性提供参考。

The susceptibility to chlorination degradation has limited the further promotion and application of polyamide thin film composite membranes (PA-TFC membranes) in desalination and industrial separation fields. In this regard, this paper summarizes the current status of research on the chlorination mechanism of PA-TFC membranes attacked by active chlorine. On this basis, we review the latest research progress on chlorine-resistant modification of PA-TFC membranes from the composite membrane structure, including surface modification, PA layer modification, support layer modification and construction of new chlorine-resistant separation layer. Finally, a summary and an outlook are given to provide references for improving the chlorine resistance and long-term operational stability of PA-TFC membranes.

黄河清（1996-），男，广东湛江人，硕士，研究方向为膜法水处理技术，E-mail：943562744@xauat.edu.cn

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