膜科学与技术

二维材料构筑的CO2分离膜研究进展

作者：李卉，王雨琪，叶志镇，彭新生

单位： 1.浙江大学温州研究院，温州新型光电与纳米材料重点实验室，浙江温州 325000 2.浙江大学硅及先进半导体材料全国重点实验室，材料科学与工程学院，杭州 310058

关键词：二维材料；气体分离；CO2分离膜；分离机制

出版年,卷(期):页码： 2023,43(6):170-179

摘要：

二维材料由于其独特的纳米片结构，已广泛应用于设计高气体渗透通量和选择性的分离膜中。石墨烯类、二维金属有机骨架、二维过渡金属碳化物/碳氮化物等二维材料中构筑的纳米及纳米尺度孔道为分子输运提供了特殊的通道, 它们是高渗透性和高选择性分子筛分的根本原因。本文综述了近年来二维材料基CO2分离膜的研究进展，包括材料种类、分离膜的制备方法、分离性能及分离机制，并对二维材料基CO2分离膜的应用前景进行了总结与展望。

Two-dimensional (2D) materials are widely used in the design of separation membranes with high gas permeability and selectivity due to their unique nanostructures. The sub-nanometer scale spaces present in 2D materials such as graphene, 2D metal-organic frameworks, and 2D MXenes provide special channels for molecular transport, including nanopores and nanochannels, which are fundamentally responsible for high permeability and selectivity. This review summarized the types and separation properties of CO2 separation membranes based on 2D materials, the preparation methods and separation mechanisms. And we finally summarize and discuss the prospects of the application of 2D materials in CO2 separation membranes.

李卉（1997—），女，安徽安庆人，硕士研究生，研究方向为CO2分离膜，E-mail：lllihuiaaaa@163.com

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