膜科学与技术

利用膜分离技术捕集燃烧后烟气CO2的工艺研究及应用现状

作者：陈斌，吴梦莉，樊雄，吴其荣，王进

单位： 1.国家电投集团远达环保股份有限公司，重庆 401122；2.重庆远达烟气治理特许经营有限公司科技分公司，重庆 401122；3.上海长兴岛热电有限责任公司，上海 201913

关键词：碳捕集；膜分离；燃烧后烟气；工业应用

出版年,卷(期):页码： 2023,43(6):232-242

摘要：

CO2的捕集、利用与封存（CCUS）是实现碳中和的重要技术手段。燃料燃烧后烟气是全球最大的CO2排放源，燃烧后烟气脱碳是膜法碳捕集的重要应用领域。国内外众多机构开展的膜法碳捕集技术研究大多停留在新型膜材料层面，仅有少数几家机构将其膜技术推进至工业示范阶段。本文总结分析了膜法碳捕集工艺及其在实际烟气中的应用情况，论述了单级膜工艺用于燃烧后烟气碳捕集的可行性，对比了不同类型多级膜工艺特点，分析了不同传质驱动力运行方式的优缺点，基于实际烟气碳捕集的研究情况和面临的问题进行了探讨，对膜法碳捕集技术在燃烧后烟气领域的应用前景进行了展望，为后续工业应用提供借鉴。

Carbon Capture, Utilization and Storage (CCUS) of CO2 is an important technical means to achieve carbon neutralization. Membrane separation is a potential technology in the second generation of carbon capture technology. Post-combustion flue gas is the largest CO2 emission source in the world. Decarburization of post-combustion flue gas is an important application field of membrane carbon capture. Most of the research on membrane carbon capture technology carried out by many institutions at home and abroad remain at the level of new membrane materials, and only a few institutions have promoted their membrane technology to the industrial demonstration stage. This paper summarizes and analyzes the membrane carbon capture process and its application in the actual flue gas, discusses the feasibility of single-stage membrane process for carbon capture in the flue gas after combustion, compares the characteristics of different types of multi-stage membrane processes, analyzes the advantages and disadvantages of different mass transfer driving force operation modes, and discusses the problems based on the research situation and faced problems of carbon capture in the actual flue gas, The application prospect of membrane carbon capture technology in the field of flue gas after combustion is explored, which provides reference for subsequent industrial applications.

陈斌（1968－），男，河北保定人，高级工程师，大学本科，主要从事电力行业环保管理及技术研究工作

参考文献：

1．Mantripragada H C，Zhai H B，Rubin E S．Boundary Dam or Petra Nova - Which is a better model for CCS energy supply?[J]．International Journal of Greenhouse Gas Control，2019，82：59-68．
2．Karl S．Start-up of world’s first commercial post-combustion coal fired CCS project：Contribution of shell cansolv to SaskPower boundary dam ICCS project[J]．Energy Procedia，2014，63：6106-6110．
3．方圆．落实“双碳”目标化工建设企业大有可为——陕西国华锦界15万t/a二氧化碳捕集(CCS)示范工程建设纪实[J]．石油化工建设，2021，43(5)：1-5．
4．吴其荣，陶建国，范宝成，等．燃煤电厂开展大规模碳捕集的技术路线选择及经济敏感性分析[J]．热力发电，2022，51(10)：28-34．
5．Robeson L M．The upper bound revisited[J]．J Membr Sci，2008，320(1-2)：390-400．
6．Zhao L，Riensche E，Weber M，et al．Cascaded membrane processes for post-combustion CO2 capture[J]．Chemical Engineering & Technology，2012，35(3)：489-496．
7．Zhang X P，He X Z，Gundersen T．Post-combustion carbon capture with a gas separation membrane：Parametric study，capture cost，and exergy analysis[J]．Energy & Fuels，2013，27(8)：4137-4149．
8．Kakuta A，Ozaki O，Ohno M．Gas permeation in freeze-dried cellulose acetate membrane[J]．Journal of Polymer Science：Polymer Chemistry Edition，1978，16(12)：3249-3257．
9．Kim K M，Lee J W，Lee J B．No-mixing-loss design of a multistage membrane carbon capture process for off-gas in thermal power plants[J]．Journal of Membrane Science，2020，598：117796．
10．Bocciardo D，Ferrari M C，Brandani S．Modelling and multi-stage design of membrane processes applied to carbon capture in coal-fired power plants[J]．Energy Procedia，2013，37：932-940．
11．Ramírez-Santos Á A，Bozorg M，Addis B，et al．Optimization of multistage membrane gas separation processes．Example of application to CO2 capture from blast furnace gas[J]．J Membr Sci，2018，566：346-366．
12．Arias A M，Mussati M C，Mores P L，et al．Optimization of multi-stage membrane systems for CO2 capture from flue gas[J]．International Journal of Greenhouse Gas Control，2016，53：371-390．
13．Merkel T C，Lin H Q，Wei X T，et al．Power plant post-combustion carbon dioxide capture：An opportunity for membranes[J]．J Membr Sci，2010，359(1-2)：126-139．
14．Zhai H B，Rubin E S．Techno-economic assessment of polymer membrane systems for postcombustion carbon capture at coal-fired power plants[J]．Environmental Science & Technology，2013，47(6)：3006-3014．
15．Bounaceur R，Lape N，Roizard D，et al．Membrane processes for post-combustion carbon dioxide capture：A parametric study[J]．Energy，2006，31(14)：2556-2570．
16．Ho M T，Allinson G W，Wiley D E．Reducing the cost of CO2 capture from flue gases using membrane technology[J]．Industrial & Engineering Chemistry Research，2008，47(5)：1562-1568．
17．Giordano L，Roizard D，Bounaceur R，et al．Evaluating the effects of CO2 capture benchmarks on efficiency and costs of membrane systems for post-combustion capture：A parametric simulation study[J]．International Journal of Greenhouse Gas Control，2017，63：449-461．
18．Belaissaoui B，Le Moullec Y，Willson D，et al．Hybrid membrane cryogenic process for post-combustion CO2 capture[J]．J Membr Sci，2012，415-416：424-434．
19．Song C F，Sun Y W，Fan Z C，et al．Parametric study of a novel cryogenic-membrane hybrid system for efficient CO2 separation[J]．International Journal of Greenhouse Gas Control，2018，72：74-81．
20．Hasse D，Ma J F，Kulkarni S，et al．CO2 capture by cold membrane operation[J]．Energy Procedia，2014，63：186-193．
21．Jaschik M，Tanczyk M，Jaschik J，et al．The performance of a hybrid VSA-membrane process for the capture of CO2 from flue gas[J]．International Journal of Greenhouse Gas Control，2020，97：103037．
22．Frimpong R A，Irvin B D，Nikolic H，et al．Integrated hybrid process for solvent-based CO2 capture using a pre-concentrating membrane：A pilot scale study[J]．International Journal of Greenhouse Gas Control，2019，82：204-209．
23. Hybrid Membrane-absorption CO2 Capture Process [Internet]. 2014 [2014-01-01/]. Available from: https://www.sciencedirect.com/science/article/pii/S1876610214018803.
24. Freeman B, Baker RW, Kniep J, Merkel T. Bench scale development of a hybrid membrane-absorption CO2 capture process (Final Report) [D]. United States: Membrane Technology and Research, Inc., 2020.
25．White L S，Wei X T，Pande S，et al．Extended flue gas trials with a membrane-based pilot plant at a one-ton-per-day carbon capture rate[J]．Journal of Membrane Science，2015，496：48-57．
26. Batoon VaB, Adam and Casillas, Carlos and Hofmann, Thomas and Huang, Ivy and Kniep, Jay and Merkel, Tim and Paulaha, Craig and Salim, Witopo and Westling, Erik. Scale-Up Testing of Advanced Polaris™ Membrane CO2 Capture Technology [J]. Proceedings of the 16th Greenhouse Gas Control Technologies Conference (GHGT-16) 23-24 Oct 2022. 2022.
27．Chaubey T，Kulkarni S S，Hasse D J，et al．CO 2 capture by cold membrane operation with actual power plant flue gas[D]．United States: U.S. Department of Energy National Energy Technology Laboratory，2017.
28．Pohlmann J，Bram M，Wilkner K，et al．Pilot scale separation of CO2 from power plant flue gases by membrane technology[J]．International Journal of Greenhouse Gas Control，2016，53：56-64．
29．Scholes C A，Qader A，Stevens G W，et al．Membrane pilot plant trials of CO2 separation from flue gas[J]．Greenhouse Gases：Science and Technology，2015，5(3)：229-237．
30．He X Z，Lindbråthen A，Kim T J，et al．Pilot testing on fixed-site-carrier membranes for CO2 capture from flue gas[J]．International Journal of Greenhouse Gas Control，2017，64：323-332．
31．Sandru M，Kim T J，Capala W，et al．Pilot scale testing of polymeric membranes for CO2 capture from coal fired power plants[J]．Energy Procedia，2013，37：6473-6480．
32．Hägg M B，Lindbråthen A，He X，et al．Pilot demonstration-reporting on CO2 capture from a cement plant using hollow fiber process[J]．Energy Procedia，2017，114：6150-6165．
33．Dai Z D，Fabio S，Giuseppe Marino N，et al．Field test of a pre-pilot scale hollow fiber facilitated transport membrane for CO2 capture[J]．International Journal of Greenhouse Gas Control，2019，86：191-200．
34．Han Y，Salim W，Chen K K，et al．Field trial of spiral-wound facilitated transport membrane module for CO2 capture from flue gas[J]．Journal of Membrane Science，2019，575：242-251．
35．Salim W，Vakharia V，Chen Y X，et al．Fabrication and field testing of spiral-wound membrane modules for CO2 capture from flue gas[J]．J Membr Sci，2018，556：126-137．
36．王志，原野，生梦龙，等．膜法碳捕集技术——研究现状及展望[J]．化工进展，2022，41(3)：1097-1101．
37. 膜法捕集二氧化碳示范装置通过测试 [J]. 膜科学与技术. 2022;42(1):56.
38．Janakiram S，Santinelli F，Costi R，et al．Field trial of hollow fiber modules of hybrid facilitated transport membranes for flue gas CO2 capture in cement industry[J]．Chemical Engineering Journal，2021，413：127405．

服务与反馈：

【文章下载】【加入收藏】

《膜科学与技术》编辑部地址：北京市朝阳区北三环东路19号蓝星大厦邮政编码：100029 电话：010-64426130/64433466 传真：010-80485372邮箱：mkxyjs@163.com