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The preparation and characterization of Pebax/SAPO-34 mixed matrix membrane
Authors: Dan Zhao1,2, Jizhong Ren1,*, Li Hui1, Xinxue Li1, Maicun Deng1
Units: 1. National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China
KeyWords: poly(amide-6-b-ethylene oxide); mixed matrix membrane;solvent
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2014,34(5):9-15

Abstract:
Poly (amide-6-b-ethylene oxide) (Pebax1657) and SAPO-34 were used to prepare Pebax1657/SAP-O34 mixed matrix membranes (MMMs) by solution-casting method with 1-butanol and acetic acid as solvent respectively. It was found that the casting solvent had more influence on permeability rather than selectivity. The MMMs prepared with 1-butanol had better zeolite distribution at high zeolite content, but the better membrane-forming was belonged to that prepared with acetic acid. The change of permeability was the co-effect of crystallization, diffusivity tortuosity, mobility of polymer chain and membrane morphology. When acetic acid was used, due to the phase separation, the permeability showed a jump and maximum reached 3 fold of the pristine Pebax membrane, and when 1-butanol was used, except for H2, the permeabilities of other gases increased initially and then decreased as a result of chain rigidification and increased diffusivity tortuosity.

Funds:
863基金资助项目;国家科技支撑项目

AuthorIntro:
赵丹(1987-),女,河南新乡人,博士,从事膜分离技术的研究。

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