膜科学与技术

Position：Home >> Abstract

Study on the filtration mechanism of humic acidbymembrane separation and photocatalysis coupling technology

Authors： CHENHuangmeng1，SONG Hongchen2,*，WANG Jianming2，LIUZili1

Units： 1. School of Chemistry &Chemical Engineering of GuangzhouUniversity,

KeyWords： ultrafiltration;photocatalysis;PVDF;humic acid

ClassificationCode：TQ028.8;TU991.2

year,volume(issue):pagination： 2014,34(6):89-95

Abstract：

In order to make use of the advantage of membrane separation and supported photocatalystcoupling technology, TiO2-doped PVDF membrane was prepared by the nonsolvent induced phase method, and theeffect of process conditions (such as UV light intensity, membrane filtration flow rate, solution concentration) on membrane performance were studied by self-made testing device, ultraviolet-visible spectrophotometer and scanning electron microscope(SEM), and the optimal process condition was obtained. Results indicated thatthe foulants’ rejection and photocatalytic degradation could be got simultaneously by the coupling technology. And the optimal removal of humic acid could be attainedwhen the UV light intensity was 1.0mW/cm2, the flow rate was 300mL/min, and the solution concentration was 2mg/L.

Funds：

国家自然科学基金项目(21307146)；

AuthorIntro：

陈黄锰(1989-)，男，广东汕头人，硕士研究生，主要从事光催化-膜分离耦合工艺的机理研究；

Reference：

[1] VatshaB, NgilaJ C, MoutloaliMR. Preparation of antifouling polyvinylpyrrolidone (PVP 40K) modified polyethersulfone (PES) ultrafiltration (UF) membrane for water purification[J]. Physics and Chemistry of the Earth, 2013, 9:1-7
[2] LevitskyI, DuekA, Naim R, et al. Cleaning UF membranes with simple and formulated solutions[J]. Chemical Engineering Science, 2012, 69(1):679-683.
[3] NorazmanN, WuW, LiH, et al. Evaluation of chemical of UF membranes fouled with whey protein isolates via analysis of residual protein components on membranes surface[J]. Separation and Purification Technology, 2013, 103:241-250.
[4]孙秀丽,李伟英,文晨. TiO2对PVDF超滤膜结构与性能的影响[J]. 膜科学与技术, 2011, 31(4):17-21.
[5] Oh SJ, Kim N, Lee YT. Preparation and characterization of PVDF/TiO2 organic-inorganic composite membranes for fouling resistance improvement[J]. Journal of Membrane Science, 2009, 345(1-2): 13-20.
[6] MadaeniSS, ZinadiniS, VatanpourV. A new approach to improve antifouling property of PVDF membrane using in situ polymerization of PAA functionalized TiO2 nanoparticles[J]. Journal of Membrane Science, 2011, 380(1-2):155-162.
[7]Shi F M, Ma Y X,Ma J, et al. Preparation and characterization of PVDF/TiO2 hybrid membranes with different dosage of nano-TiO2[J]. Journal of Membrane Science, 2012, 389:522-531.
[8]RahimpourA, MadaeniSS, TaheriAH, et al. Coupling TiO2 nanoparticles with UV irradiation for modification of polyethersulfone ultrafiltration membranes[J]. Journal of Membrane Science, 2008, 313(1-2): 158–169.
[9] Augugliaro V, Litter M, Palmisano L, et al. The combination of heterogeneous photocatalysis with chemical and physical operations: A tool for improving the photoprocess performance[J]. Journal of Photochemistry and Photobiology C:Photochemistry Reviews, 2006, 7 (4): 127-144.
[10]马宁.多功能TiO2光催化复合分离膜制备和水处理应用性能研究:[博士学位论文]. 大连: 大连理工大学, 2009年.
[11] Song H C, Shao J H, He Y L, et al. Natural organic matter removal and flux decline with PEG-TiO2-doped PVDF membranes by integration of ultrafiltration with photocatalysis [J]. Journal of Membrane Science, 2012, 405–406: 48-56.
[12]赵媛媛,王志,王纪孝等.含腐殖酸类有机物模拟废水超滤过程研究[J]. 膜科学与技术.2006, 26(1):42-46.
[13] 宋宏臣. 改性超滤膜去除水中天然有机物的研究[D]: [博士学位论文]. 上海:上海交通大学,2012年.
[14] 吴伟.二氧化钛光催化降解腐殖酸的研究: [硕士学位论文]. 上海:华东师范大学,2010年.
[15] 张辉.光催化/膜分离耦合工艺处理印染废水及其过程机理研究:[硕士学位论文].浙江:浙江工业大学. 2010年.
[16] 严晓菊.光催化-膜分离组合工艺去除腐殖酸的效能与机理研究:[博士学位论文].浙江:哈尔滨工业大学. 2009年.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com