Position:Home >> Abstract

PDMS/PVDF composite membrane for separation of VOC/N2 mixtures
Authors: HAN Qiu, ZHOU Haoli, LIU Gongping, JIN Wangqin*
Units: State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering,
KeyWords: PDMS/PVDF composite membrane; VOC/N2 Separation; Stability
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2015,35(1):75-81

Abstract:
Poly(dimethylsiloxane) (PDMS)/poly(vinylidenefluoride) (PVDF) composite membrane was prepared for the separation of n-hexane/nitrogen, cyclohexane/nitrogen and n-heptane/nitrogen mixtures. The effects of feed concentration, flow rate and operating temperature on the performance of the PDMS composite membrane were systematically studied. It was found that VOC permeance and separation factor increased with increasing feed VOC concentration and feed flow rate, while decreased with the increase of operating temperature. The PDMS/PVDF composite membranes exhibited good and stable performance during three months continuous operation, with n-heptane permeance and separation factor of 1.2*10-6mol/(s?m2?Pa) and 145, respectively.

Funds:
“教育部创新团队”(No. IRT13070) ;“江苏省优势学科”(PAPD)

AuthorIntro:
韩秋(1988-),女,山东菏泽人,硕士研究生,从事膜材料制备及应用研究。*通讯联系人,E-mail:wqjin@njtech.edu.cn

Reference:
[1] Huang W Q, Bai J, Zhao S H, et al. Investig ation of oil vapor emission and its evaluation methods [J]. J Loss Prevent Proc. 2011, 24: 178-186.
[2] Klimont Z, Cofala J, Schopp W, et al. Projections of SO2, NOx, NH3 and VOC emissions in East Asia up to 2030 [J]. Water Air Soil Pollut. 2001, 130: 193-198
[3] Fenger J. Urban air quality [J]. Atmos Environ. 1999, 33: 4877-4900
[4] Atkinson R. Atmospheric chemistry of VOCs and NOx [J], Atmos Environ. 2000, 34(12): 2063-2101.
[5] 郝吉明, 马广大. 大气污染控制工程[M](第二版).北京: 高等教育出版社, 2002
[6] Urashima K, Chang J S. Removal of Volatile organic compunds from air streams and industrial fuel gases by non-thermal plasma technology [J]. IEEE Trans Ind Appl.2000, 7(5): 602-614.
[7] Dinelli G, Civitano L,Rea M, et al. Industrial experiments on pluse corona simultaneous removal of NO and SO2 from fluegas [C]. IEEE IAS Annual Meeting, 1998, 1620-1627.
[8] 吴碧君, 刘晓勤. 挥发性有机物污染控制技术研究进展. 电力环境保护. 2005, 21(4): 39-42
[9] Gales L, Mendes A, Cosat C. Removal of acetone, ethyl acetate and ethanol vapors from air using a hollow fiber PDMS membrane module [J]. J Membr Sci. 2002, 197 (1): 211-222
[10] Liu G P, Wei W, Wu H, et al. Pervaporation performance of PDMS/ceramic composite membrane in acetone butanol ethanol (ABE) fermentation-PV coupled process, J Membr Sci. 2011, 373: 121-129
[11] Strathmann H. Membrane separation processes: current relevanceand future opportunities [J]. AIChE J. 2001, 47 (5): 1077-1087.
[12] Prabhakar R, Freeman B. Application of hydrocarbon-flurocarbon interactions in membrane based gas separations [J]. Desaline, 2002, 144: 79-83.
[13] Liu L, Chakma A, Feng X S. Separation of VOCs from N2 using poly(ether block amide) membrane [J]. Can J Chem Eng. 2004, 39: 149–164.
[14] Majumdar S, Bhaumik D, Sirkar K K. Performance of commercial-size plasma polymerized removing VOCs from N2/air [J]. J Membr Sci. 2003, 214: 323-330.
[15] Park H B, Lee Y M. Separation of toluene/nitrogen through segmented polyurethane and polyurethane urea membranes with different soft segments. J Membr Sci. 2002, 197: 283–296.
[16] Xiangli F J, Chen Y W, Jin W Q, et al. Polydimethylsiloxane(PDMS)/ceramic composite membrane with high flux for pervaporation of ethanol-water mixtures. Ind Eng Chem Res. 2007, 46: 2224-2230.
[17] Liu S, Teoa W K, Tan X Y, et al. Preparation of PDMSvi-Al2O3 composite hollow fibre membranes for VOC recovery from waste gas streams. Sep Purif Technol. 2005, 46: 110–117
[18] Liu G P, Hou D, Wei W, et al. Pervaporation separation of butanol-water mixtures using polydimethylsiloxane/ceramic composite membrane [J]. Chinese J Chem Eng, 2011, 19(1): 40-44.
[19] Yeom C K, Lee S H, Song H Y, et al. Vapor permeations of a series of VOCs/N2 mixtures through PDMS membrane [J]. J Membr Sci. 2002, 198(1): 129-143.
[20] Barton A F M. CRC handbook of solubility parameters and other cohesion parameters, CRC press. Boca Raton, FL, 1985.
[21] Mohtada S, Mohammad A, Kazem S, et al.Gas permeation through a synthesized composite PDMS/PES membrane [J]. J Membr Sci. 2009, 342: 236-250.
[22] Lide D R. CRC Hand Book of Chemistry and Physics, CRC press. Cleveland, OH, 2002-2003.

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号