Position:Home >> Abstract

Preparation and properties of reverse osmosis composite membranes formed by 2,2’,4,4’-biphenyl tetraacyl chloride and trimesoyl chloride
Authors: Dai Lei1,2, Zhang Zhiguang1, Zhang Suobo1*
Units: 1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun 130022, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China
KeyWords: reverse osmosis composite membrane; 2,2’,4,4’-biphenyl tetraacyl chloride; trimesoyl chloride; interfacial polymerization
ClassificationCode:P747;TQ028.8
year,volume(issue):pagination: 2016,36(4):1-6

Abstract:
A serie of reverse osmosis (RO) composite membranes was prepared by interfacial polymerization of 2,2’,4,4’-biphenyl tetraacyl chloride (BTEC)/ trimesoyl chloride (TMC) as organic-phase monomers and 1,3-phenylene diamine (MPD). The effects of surface chemical composition, surface morphology, hydrophilicity and separation performance were systematically investigated by incorporating BTEC. The results showed that smooth polyamide structures were formed, the salt rejection of the RO membranes increased from 99.42% to 99.63% while the permeability just experienced a little decrease.

Funds:
国家重大基础研究“973” 计划(2015CB655302)

AuthorIntro:
第一作者简介: 代 磊(1982- ),男,吉林省长春,硕士研究生,助理研究员,研究方向为反渗透复合膜制备工艺优化及应用, 通讯作者,Email: sbzhang@ciac.ac.cn

Reference:
 [1] 吴礼光, 周勇, 张林, 陈欢林, 高从堦. 反渗透复合膜功能材料研究进展[J]. 化学进展, 2008, 20(7/8):1216-1221.
[2] Larson R E, Cadotte J E, Petersen R J. The FT-30 seawater reverse osmosis membrane--element test results [J]. Desalination, 1981, 38:473-483.
[3] Rana D, Matsuura T. Surface modifications for antifouling membranes [J]. Chem. Rev., 2010, 110:2448-2471.
[4] Kang G D, Cao Y M. Development of antifouling reverse osmosis membranes for water treatment: A review [J]. Water Research, 2012, 46:584-600.
[5] Li L, Zhang S B, Zhang X S, Zheng G D. Polyamide thin film composite membranes prepared from isomeric biphenyl tetraacyl chloride and m-phenylenediamine [J]. J. Membr. Sci., 2008, 315:20-27.
[6] Wang T Y, Dai L, Zhang Q F, Li A, Zhang S B. Effects of acyl chloride monomer functionality on the properties of polyamide reverse osmosis (RO) membrane [J]. J. Membr. Sci., 2013, 440:48-57.  
[7] Kwak S Y, Jung S G, Yoon Y S, Ihm D W. Details of surface features in atomatic polyamide reverse osmosis membrane characterized by scanning electron and atomic force microscopy [J]. J. Polym. Sci.: Part B 37, 1999:1429-1440.
[8] Jeshi S A, Neville A. An investigation into the relationship between flux and roughness on RO membranes using scanning probe microscopy. Desalination 2006, 189:221-228.
[9] Ghosh A K, Jeong B H, Huang X F, Hoek E M V. Impacts of reaction and curing conditions on polyamide composite reverse osmosis membrane properties [J]. J. Membr. Sci., 2008, 311:34-45.
[10] Morgan P W. Condensation Polymers: By Interfacial and Solution Methods [M]. New York, 1965:20-30.
[11] P.W. Morgan. Interfacial Polycondensation [J]. J. Polym. Sci., 1959:289-327. 
[12] Song Y J, Sun P, Henry L L, Sun B. Mechanisms of structure and performance controlled thin film composite membrane formation via interfacial polymerization process [J]. J. Membr. Sci., 2005, 251:67.
[13] Chai G Y, Krantz WB. Formation and characterization of polyamide membranes via interfacial polymerization [J]. J. Membr. Sci., 1994, 93:175.
[14] Liu M H, Wu D H, Yu S C, Gao C J. Influence of the polyacyl chloride structure on the reverse osmosis performance, surface properties and chlorine stability of the thin-film composite polyamide membranes [J]. J. Membr. Sci., 2009, 326:205-214.
[15] Kwak S Y, Jung S G, Kim S H. Structure-Motion-Performance of flux-enhanced reverse osmosis (RO) membranes composed of aromatic polyamide thin film [J]. Environ. Sci. Technol. 2001, 35:4334-4340.
[16] Hirose M, Ito H, Kamiyama Y. Effect of skin layer surface structures on the flux behavior of RO membranes [J]. J. Membr. Sci., 1996, 121:209-215.
 

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号