膜科学与技术

Position：Home >> Abstract

Industrialization preparation technology of fixed carrier membranes for CO2 separation

Authors： WANG Shuqing，QIAO Zhihua，WANG Zhi

Units： Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin Key Laboratory of Membrane Science and Desalination Technology, State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, PR China

KeyWords： fixed carrier membrane; industrialization preparation technology; polyvinylamine(PVAm)-piperazine(PIP); CO2 permeance and selectivity

ClassificationCode：TQ028.8

year,volume(issue):pagination： 2016,36(5):87-94

Abstract：

To realize large-scale industrialization application of CO2 separation membranes, an industrialization preparation technology of fixed carrier membranes for CO2 separation was developed, which is including two parts: (1) the development of continuous fabrication device with industrial scale for membranes and the large-scale fabrication of the fixed carrier membranes (polyvinyl alcohol (PVA)/polyvinylamine (PVAm)-(piperazine) PIP /polysulfone (PSf) membrane) with the width of 1000 mm, (2) the development of the fabrication device for spiral-wound membrane elements and the fabrication of spiral-wound membrane modules (1812 membrane module) with the width of 300 mm and the membrane area of 0.4 m2. For CO2/N2 mixed gas saturated with water vapor, CO2 permeance of the membrane can reach 500 GPU, CO2/N2 selectivity can reach 87, for CO2/CH4 mixed gas saturated with water vapor, CO2 permeance of the membrane can reach 300 GPU, CO2/CH4 selectivity can reach 55. CO2/N2 and CO2/CH4 separation performance of the membranes and membrane modules are higher than that of commercial membranes.

Funds：

国家自然科学基金项目（21436009）；国家高技术研究发展计划（2012AA03A611）

AuthorIntro：

第一作者：王树清（1965-），男，天津，学士，中级工程师。

Reference：

[1] Lin H, Van Wagner E, Freeman B D, Toy L G, Gupta R P. Plasticization-Enhanced Hydrogen Purification Using Polymeric Membranes[J]. Science, 2006, 311 (5761): 639-642.
[2] Ma Z, Qiao Z, Wang Z, Cao X, He Y, Wang J, Wang S. CO2 separation enhancement of the membrane by modifying the polymer with a small molecule containing amine and ester groups[J]. RSC Advances, 2014, 4 (41): 21313-21317.
[3] 朱祥，吕文杰，胡军，汪华林，刘洪来，有机多孔聚合物CO2捕集及分离性能的研究进展 [J]. 化工学报，2014, 65 (5): 1553-1562.
[4] 何文娟，王志，李雯，李诗纯，王纪孝，界面聚合制备含丙烯氧基团的复合膜用于CO2分离 [J]. 化工学报，2014, 65 (11): 4420-4429.
[5] Powell C E, Qiao G G. Polymeric CO2/N2 gas separation membranes for the capture of carbon dioxide from power plant flue gases[J]. Journal of Membrane Science, 2006, 279 (1-2): 1-49.
[6] 王志，袁芳，王明，王纪孝，王世昌，分离CO2膜技术 [J]. 膜科学与技术，2011, 31 (3): 11-17.
[7] Qiao Z, Wang Z, Zhang C, Yuan S, Zhu Y, Wang J, Wang S. PVAm-PIP/PSf Composite Membrane with High Performance for CO2/N2 Separation[J]. AIChE Journal, 2013, 59 (1): 215-228.
[8] Evan J. G., Thomas O. B. Review of novel methods for carbon dioxide separation from flue and fuel gases[J]. Fuel Processing Technology, 2005, 86 (14-15): 1423-1434.
[9] Sandru M., Haukebø S. H., Hägg M. B. Composite hollow fiber membranes for CO2 capture[J]. Journal of Membrane Science, 2010, 346 (1): 172-186.
[10] Zou J., Winston Ho W. S. CO2-selective polymeric membrane containing amines in crosslinked poly(vinyl alcohol) [J]. Journal of Membrane Science, 2006, 286 (1-2): 310-321.
[11] Deng L., Kim T. J., Hägg M. B. Facilitated transport of CO2 in novel PVAm/PVA blend membrane[J]. Journal of Membrane Science, 2009, 340 (1-2): 154-163.
[12] 甄寒菲，王志，李保安，王世昌，用于分离CO2的高分子膜 [J]. 高分子材料科学与工程，1999，15 (6): 29-31.
[13] Zhang Y., Wang Z., Wang S. Selective permeation of CO2 through new facilitated transport membranes[J]. Desalination, 2002, 145 (1-3): 385-388.
[14] Zhang Y., Wang Z., Wang S. Synthesis and characteristics of novel fixed carrier membrane for CO2 separation[J]. Chemistry Letters, 2002, 4: 430-431.
[15] 王志，张莉莉，张颖，王世昌，分离CO2的促进传递膜 [J]. 膜科学与技术，2003，23 (4): 166-171.
[16] 张颖，王志，伊春海，王纪孝，王世昌，VSA-SA/PS固定载体复合膜的制备及其CO2/CH4分离性能 [J]. 化工学报，2006，57 (1): 163-168.
[17] Zhang Y., Wang Z., Wang J., Wang S. Effect of heat cross-linking on carbon dioxide fixed-carrier membrane structure and performance[J]. Desalination, 2006, 193 (1-3): 299-303.
[18] Yi C., Wang Z., Li M., Wang J., Wang S. Facilitated transport of CO2 through polyvinylamine/polyethleneglycol blend membranes[J]. Desalination, 2006, 193 (1-3): 90-96.
[19] Wang Z., Yi C., Zhang Y., Wang J., Wang S. CO2-facilitated transport through poly(N- vinyl-γ-sodium aminobutyrate-co-sodium acrylate)/polysulfone composite membranes[J]. Journal of Applied Polymer Science, 2006, 100 (1): 275-282.
[20] 伊春海，含氨基固定载体膜制备及其CO2传递特性研究 [D]. 天津：天津大学，2007.
[21] Zhao J., Wang Z., Wang J., Wang S. Influence of heat-treatment on CO2 separation performance of novel fixed carrier composite membranes prepared by interfacial polymerization[J]. Journal of Membrane Science, 2006, 283 (1-2): 346-356.
[22] 赵卷，界面聚合法制备分离CO2固定载体复合膜 [D]. 天津：天津大学，2006.
[23] Wang Z., Li M., Cai Y., Wang J., Wang S. Novel CO2 selectively permeating membranes containing PETEDA dendrimer[J]. Journal of Membrane Science, 2007, 290 (1-2): 250-258.
[24] Cai Y., Wang Z., Yi C., Bai Y., Wang J., Wang S. Gas transport property of polyallylamine-poly(vinyl alcohol)/polysulfone composite membranes[J]. Journal of Membrane Science, 2008, 310 (1-2): 184-196.
[25] 蔡彦，提高固定载体促进传递膜渗透性能的方法和理论研究 [D]. 天津：天津大学，2008.
[26] Yu X., Wang Z., Wei Z., Yuan S., Zhao J., Wang J., Wang S. Novel tertiary amino containing thin film composite membranes prepared by interfacial polymerization for CO2 capture [J]. Journal of Membrane Science, 2010, 362 (1-2): 265-278.
[27] 于型伟，界面聚合法制备分离CO2复合膜及成膜过程研究 [D]. 天津：天津大学，2010.
[28] Yuan S., Wang Z., Qiao Z., Wang M., Wang J., Wang S. Improvement of CO2/N2 separation characteristics of polyvinylamine by modifying with ethylenediamine[J]. Journal of Membrane Science, 2011, 378 (1-2): 425-437.
[29] 远双杰，强化含氨基固定载体膜CO2/N2渗透选择性能研究 [D]. 天津：天津大学，2011.
[30] 袁芳，界面聚合法成膜过程观测及分离CO2复合膜制备 [D]. 天津：天津大学，2012.
[31] Wang M., Wang Z., Wang J., Zhu Y., Wang S. An antioxidative composite membrane with the carboxylate group as the fixed carrier for CO2 separation from flue gas[J]. Energy & Environmental Science, 2012, 4 (10): 3196-3200.
[32] Wang M., Wang Z., Li S., Zhang C., Wang J., Wang S. A high performance antioxidative and acid resistant membrane prepared by interfacial polymerization for CO2 separation from flue gas[J]. Energy & Environmental Science, 2013, 6 (2): 539-551.
[33] 王明明，抗氧化耐酸分离CO2膜制备及性能研究 [D]. 天津：天津大学，2012.
[34] Li S., Wang Z., Yu X., Wang J., Wang S. High-Performance Membranes with Multi-Permselectivity for CO2 Separation[J]. Advanced Materials, 2012, 24 (24): 3196-3200.
[35] 李诗纯，具有多种选择透过机制的高性能CO2分离膜 [D]. 天津：天津大学，2014.
[36] 马子健，小分子胺和MOFs分别改性聚乙烯基胺制备高性能CO2分离膜 [M]. 天津：天津大学，2014.
[37] 王志，吕强，李保安，王世昌，新型CO2分离膜的结构和性能 [J]. 高分子材料科学与工程，2000，16 (6): 5-7.
[38] 张晨昕，分离CO2膜传质机理与及其过程模拟研究 [D]. 天津：天津大学，2014.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com