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Preparation and anti-biofouling properties of GO/PVDF blend ultrafiltration membrane
Authors: MA Cong, HUANG Jingyun, WANG Liang
Units: Laboratory of Separation Membranes and Membrane Processes/ National Center for International Joint Research on Separation Membranes, Tianjin Polytechnic University; School of Environmental and chemical Engineering, Tianjin Polytechnic University
KeyWords: PVDF; GO; immerse precipitation method; ultrafiltration; antibacterial properties;anti-biofouling properties
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2018,38(4):64-69

Abstract:
 In the study, the blend membranes modified by adding different concentration of GO were prepared through the phase inversion method. The tests of contact angle and SEM imagines were carried out to evaluate membranes surface hydrophilicity and structure of pore. Furthermore, the pseudomonas aeruginosa, as typical pollutants, were filtrated to research the antibacterial and anti-biofouling properties of membranes. The results indicated that contact angle of membranes blended GO/PVDF membrane could decreased the contact angle to improve the hydrophilicity and increase the finger-like pore, which lead to higher water flux. The contact angle decreased to 64° and the water flux increased by 64% under the additive concentration of 0.5wt%.The antibacterial and anti-biofouling properties of PVDF membranes were improved through adding GO. Compared with 5.4×1012m-1of PVDF/0wt%GO, the irreversible resistance of PVDF/0.5wt%GO membranes decreased to 1.8×1012m-1, showing the irreversible resistance of blend membranes decreased by 66.7%.

Funds:
国家自然科学基金项目(51508383,51478314)

AuthorIntro:
第一作者简介:马聪(1982-),男,辽宁沈阳,博士,研究方向是膜法水处理E-mail:macong_0805@126.com 通讯作者,E-mail:mashi7822@163.com

Reference:
 [1] Kang G D, Cao Y M. Application and modification of poly(vinylidene fluoride) (PVDF) membranes – A review[J]. J Membr Sci, 2014, 463(1): 145-165.
[2] Zhao C, Xu X, Jie C, et al. Highly effective antifouling performance of PVDF/graphene oxide composite membrane in membrane bioreactor (MBR) system[J]. Desalination, 2014, 340(1): 59-66.
[3] Chang X, Wang Z, Quan S, et al. Exploring the synergetic effects of graphene oxide (GO) and polyvinylpyrrodione (PVP) on poly(vinylylidenefluoride) (PVDF) ultrafiltration membrane performance[J]. Appl Surf Sci, 2014, 316(1): 537-548.
[4] Safarpour M, Khataee A, Vatanpour V. Preparation of a Novel Polyvinylidene Fluoride (PVDF) Ultrafiltration Membrane Modified with Reduced Graphene Oxide/Titanium Dioxide (TiO2) Nanocomposite with Enhanced Hydrophilicity and Antifouling Properties[J]. Ind Eng Chem Res, 2014, 53(34): 13370-13382.
[5] Perreault F, Tousley M E, Elimelech M. Thin-Film Composite Polyamide Membranes Functionalized with Biocidal Graphene Oxide Nanosheets[J]. Environ.sci.technol.lett, 2016, 1(1): 71–76.
[6] Liu X H, Duan J, Yang J H, et al. Hydrophilicity, morphology and excellent adsorption ability of poly(vinylidene fluoride) membranes induced by graphene oxide and polyvinylpyrrolidone[J]. Colloid Surface A, 2015, 486:172-184.
[7] Xu Z, Zhang J, Shan M, et al. Organosilane-functionalized graphene oxide for enhanced antifouling and mechanical properties of polyvinylidene fluoride ultrafiltration membranes[J]. J Membr Sci, 2014, 458(10): 1-13.
[8] Wu T, Zhou B, Zhu T, et al. Facile and low-cost approach towards a PVDF ultrafiltration membrane with enhanced hydrophilicity and antifouling performance via graphene oxide/water-bath coagulation[J]. Rsc Adv, 2015, 5(11): 7880-7889.
[9] Zhang J, Xu Z, Mai W, et al. Improved hydrophilicity, permeability, antifouling and mechanical performance of PVDF composite ultrafiltration membranes tailored by oxidized low-dimensional carbon nanomaterials[J]. J Mater Chem A, 2013, 1(9): 3101-3111.
[10] 王庐岩. 聚偏氟乙烯共混相容性及成膜机理研究[D]. 北京工业大学, 2002.

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