Position:Home >> Abstract

Preparation and properties of sepiolite modified polyethersulfone membrane
Authors: QIN Ai wen, YANG Yan fu, HE Yun long, HE Gong man, XIN Chang zheng
Units: Henan University of Engineering, Zhengzhou 450007
KeyWords: polyethersulfone; sepiolite; hybrid membrane; antifouling modification
ClassificationCode:TQ028.8
year,volume(issue):pagination: 2020,40(5):70-76

Abstract:
A series of PES/Sepiolite hybrid membranes were obtained by changing the amount of sepiolite, using polyethersulfone (PES) as the membrane material, and N-N dimethylacetamide as the solvent. In the experiment, the hydrophilicity, chemical composition and tensile properties of the membrane were tested and characterized by water contact angle measuring instrument, Fourier infrared spectrometer and electronic fabric strength machine. Subsequently, water permeability, retention rate and antifouling performance of the membrane were tested and characterized by cross-flow penetration using bovine serum albumin as a simulated contaminant. The results show that breaking strength of the hybrid membrane is reduced, and the change of breaking elongation is not obvious with the increase of the amount of modified sepiolite. When the amount of modified sepiolite was 1%, contact angle decreased to a minimum of 61.74 °, while the porosity and pure water flux reached maximum values of 88.64 % and 221.3 L/(m2 h), respectively. In addition, average pollution degree and attenuation coefficient of the hybrid membrane were reduced from 50 % and 40 % to 24.11 % and 15.68 % compared with the blank membrane, indicating that the PES membrane after adding modified sepiolite has better antifouling performance.

Funds:
河南省科技攻关项目(192102310211),河南工程学院博士基金项目(D2016007)

AuthorIntro:
秦爱文(1986-),男,河南郑州,讲师,研究生,博士,膜材料制备和改性,E-mail:qinaiwen@haue.edu.cn,

Reference:
[1]占琦伟, 许振良, 胡登. NIPS法制备小孔径SPESPES共混UF膜及其性能表征[J]. 膜科学与技术, 2014, 34(2): 28-31.
[2]赵津礼, 王建友, 陈青柏. 亲水剂对磺化聚醚砜基阳离子交换膜结构与性能的影响[J]. 膜科学与技术, 2020, 40(1): 93-99.
[3]赵津礼, 王建友, 张玉忠. 新型聚醚砜/磺化聚醚砜共混超滤膜制备方法的研究[J]. 膜科学与技术, 2018, 38(4): 33-42.
[4]王勇, 王鸿儒. 聚砜类分离膜材料及其改性研究进展[J]. 塑料工业, 2012, 40(1): 5-8.
[5]赵羿博, 董延茂, 赵丹, 等. 聚醚砜/类水滑石杂化超滤膜的制备及性能研究[J]. 塑料科技, 2018, 46(6): 46-53.
[6]于凤芹, 王海增. 树脂/聚醚砜复合膜的制备及其对碘离子的吸附性能[J]. 材料导报, 2018, 32(18): 3276-3280.
[7]张兵. 新型分子筛/聚醚砜复合膜材料的制备及性质研究[D]. 天津: 天津工业大学, 2018.
[8]Nagata H. On dehydration of bound water of sepiolite[J]. Clay Clay Miner, 1974, 22(3): 285-293.
[9]Can M, Cinar M, Benli B, et al. Determining the fiber size of nano structured sepiolite using Atomic Force Microscopy (AFM)[J]. Appl Clay Sci, 2010, 47(3): 217-222.
[10]梁凯, 唐丽永, 王大伟. 海泡石活化改性的研究现状及应用前景[J]. 化工矿物与加工, 2006, 35(4): 5-9.
[11]余桂辉, 陈红祥, 王婉婉, 等. 软段长度对聚氨酯/海泡石复合材料结构及性能的影响[J]. 高分子材料科学与工程, 2015, 31(12): 67-72.
[12]王亮, 陈孟林, 何星存, 等. 改性海泡石对亚甲基蓝的吸附性能[J]. 过程工程学报, 2009, 9(6): 1095-1098.
[13]Su X L, Xia G H, Liao R H. Study on preparation and properties of organic sepiolite[J]. J Ceram, 2010, 31(2): 310-314.
[14]Zheng S Q, Han Y, Huang X H. Acid and aluminium modification of sepiolite and its application in FCC catalysis[J]. Clay Miner, 2010, 45(1): 15-22.
[15]Sabah E, Turan M, Celik M S. Adsorption mechanism of cationic surfactants onto acid and heat activated sepiolites[J]. Water Res, 2002, 36(16): 3957-3964.

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号