膜科学与技术

Position：Home >> Abstract

The effect of counterions on the performance of sulfonated copoly( phthalazinone biphenyl ether sulfone) NF membrane

Authors： Tang Jinjin, Zhang Shouhai, Wang danhui, Xu Peiqi, Xu Shugang, Jian Xigao

Units： College of chemical engineering, Dalian University of Technology, Liaoning High Performance Polymer Engineering Research Center, Liaoning Key Laboratory of Polymer Science and Engineering, Dalian Key Laboratory of Membrane Materials and Process, Dalian 116024, China

KeyWords： sulfonated copoly(phthalazinone biphenyl ether sulfone); counterion; composite nanofiltration membrane; water flux; rejection

ClassificationCode：TQ 326.55；TB 324

year,volume(issue):pagination： 2021,41(5):65-72

Abstract：

Sulfonated copoly(phthalazinone biphenyl ether sulfone) substituted by counterions (SPPBES-M) were prepared from sulfonated copoly(phthalazinone biphenyl ether sulfone) (acid form) immersing in salt solutions. SPPBES-M were characterized by FT-IR and TGA. The 5% decomposition temperature of SPPBES-M was higher than 489 ℃, and SPPBES-M had excellent thermal stability. SPPBES-M/PPBES composite nanofiltration membranes were prepared by coating method. The effects of SPPBES-M concentration, counterions, curing treatment temperature, and curing treatment time on the performance of composite nanofiltration membranes were investigated. The rejection of composite membrane decreased from 65% to 58%, and the flux increased from 29 L/(m2·h) to 36 L/(m2·h) with the increase of the radius of counterions (Li+、Na+ and K+). With the increase of curing treatment temperature and time, the water flux of SPPBES-100-M/PPBES composite membranes were decreased, and the rejection were increased. When the curing treatment time extended from 10min to 40min, the rejection enhanced from 62% to 83%.

Funds：

国家重点研发计划项目(2017YFB0307600)，国家自然科学基金委创新研究群体项目（22021005），辽宁省‘兴辽英才计划’项目(XLYC1802073)，大连市高层次人才创新支持计划（2019RD08）。

AuthorIntro：

唐金金（1996-），女，辽宁省北镇市，硕士，从事磺化杂萘联苯聚醚砜纳滤膜的研究，E-mail：tangjin@mail.dlut.edu.cn

Reference：

[1] 石紫, 王志, 王宠, 等. 染料分离有机纳滤膜制备技术研究进展[J]. 膜科学与技术, 2020, 40(01): 340-351.
[2] Guo S, Wan Y, Chen X, et al. Loose nanofiltration membrane custom-tailored for resource recovery[J]. Chem Eng J, 2021, 409: 127376.
[3] Ji Y, Qian W, Yu Y, et al. Recent developments in nanofiltration membranes based on nanomaterials[J]. Chinese J Chem Eng, 2017, 25(11): 1639-1652.
[4] Qin D, Huang G, Terada D, et al. Nanodiamond mediated interfacial polymerization for high performance nanofiltration membrane[J]. J Membr Sci, 2020, 603: 118003.
[5] 秦爱文, 杨炎福, 何云龙, 等. 海泡石改性聚醚砜膜的制备及性能[J]. 膜科学与技术, 2020, 204(05): 74-80.
[6] Ahmad A, Abdulkarim A, Ooi B. et al. Recent development in additives modifications of polyethersulfone membrane for flux enhancement[J]. Chem Eng J, 2013, 223(5): 246-267.
[7] Muthumeenal A, Neelakandan S, Kanagaraj P, et al. Synthesis and properties of novel proton exchange membranes based on sulfonated polyethersulfone and N-phthaloyl chitosan blends for DMFC applications[J]. Renew Energ, 2016, 86: 922-929.
[8] 观姗姗, 张守海, 王晓丽, 等. 耐氯性能优良的磺化杂萘联苯聚醚砜复合纳滤膜[J]. 膜科学与技术, 2013, 4(33): 17-22.
[9] 王榛麟, 张守海, 蹇锡高, 等. 磺化杂萘联苯共聚醚砜/聚醚砜复合纳滤膜的制备[J]. 水处理技术, 2017, 43(01): 17-21.
[10] Chen Y, Zhang S, Liu Q, et al. The effect of counter-ion substitution on poly(phthalazinone ether ketone) amphoteric ion exchange membranes for vanadium redox flow battery[J]. J Membr Sci, 2021, 620, 118816.
[11] Pérez-Pérez M, Suleiman D. Transport properties of sulfonated poly(ether ether ketone) membranes with counter-ion substitution[J]. J Membr Sci, 2015, 493: 414-427.
[12] Hamad F, Chowdhury G, Matsuura T. Sulfonated polyphenylene oxide-polyethersulfone thin-film composite membranes[J]. J Membr Sci, 2001, 191(13): 71-83.
[13] 张守海, 邵萃, 曾圣达, 等. 杂萘联苯共聚醚砜的磺化[J]. 功能材料, 2012, 41(5): 874-877.
[14] Xie T, Zhao H, Lv Z, et al. A highly active composite electrocatalyst Ni-Fe-P-Nb2O5 / NF for overall water splitting[J]. Int J Hydrogen Energ, 2020, 46(01): 581-588.
[15] Zhu X, Yang Z, Gan Z, et al. Toward tailoring nanofiltration performance of thin-film composite membranes, Novel insights into the role of poly(vinyl alcohol) coating positions[J]. J Membr Sci, 2020, 614(15): 118526.
[16] Bas C, Reymond L, Anne-sophie Danérol, et al. Key counter ion parameters governing polluted nafion membrane properties[J]. J Polym Sci Part B Polym Phys, 2010, 47(14): 1381-1392.
[17] Chen L, Zhang S, Jiang Y, et al. Preparation and characterization of sulfonated poly(aryl ether ketone) containing 3,5-diphenyl phthalazinone moieties for proton exchange membrane[J]. RSC Adv, 2016, 6: 75328–75335.
[18] Kim Y, Park H, Lee Y. Carbon molecular sieve membranes derived from metal-substituted sulfonated polyimide and their gas separation properties[J]. J Membr Sci, 2003, 226(1-2): 145-158.
[19] Farideh Z, Rozita M. M, Saeid R, et al. Preparation of thin film composite nano-filtration membranes for brackish water softening based on the reaction between functionalized UF membranes and polyethyleneimine[J]. J Membr Sci, 2019, 588, 117207.
[20] 杜圣羽, 孙佳楠, 孙璐, 等. 基于温度梯度变化热处理对聚酰胺复合膜性能的影响的研究[J]. 新型工业化, 2019, 009(010): 63-67.
[21] Shi Y, Wang X, Chen G, et al. Preparation and characterization of high erformance dehydrating pervaporation alginate membranes[J]. J Appl Polym Sci, 1998, 68(6): 959-968.
[22] Gong G, Wang P, Zhou Z, et al. New insights into the role of an interlayer for the fabrication of highly selective and permeable thin-film composite nanofiltration membrane[J]. ACS Appl Mater Interf, 2019, 11(7): 7349-7356.

Service：

【Download】【Collect】

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone：010-80492417/010-80485372; Fax：010-80485372 ; Email：mkxyjs@163.com