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Treatment of nickel electrowinning anode solution by nanofiltration coupled with electrodialysis

Authors： Xu qiang,Wang xiaozhen,Zhang pengyun,Wang yingping

Units： 1.Gansu Membrane Science and Technology Research Institute of Co. ,Ltd.,Gansu Research Center of Membrane Separation Engineering Technology;Lanzhou 730020, China

KeyWords： Nickel anodic electrolyte,Electrodialysis,acid salt separation,nanofiltration

ClassificationCode：X758

year,volume(issue):pagination： 2021,41(5):130-138

Abstract：

In order to reduce the Na2CO3 consumption of nickel electrowinning, the coupling technologies of nanofiltration and electrodialysis ware used to separate acid-salt from the anodic solution and recover the dilute acid.. The nickel sulfate in the anodic solution was separated from the sulfuric acid by special nanofiltration membrane, followed by the dilute acid being concentrated and reused by electrodialysis. The results show that under the conditions of feed temperature of 55℃, operating pressure 3.5 MPa and flow rate of 1000L/h, the retention rate of nickel ion and the removal rate of hydrogen ion were 91.36% and 73.07% respectively.There was a good separation effect for acid-salt by nanofiltration. Electrodialysis can concentrate the separated dilute acid. A maximum concentration of sulfuric acid was increased by 4.3 times to 33.8 g/L. The anode liquor of nickel electrowinning was treated by nanofiltration coupled with electrodialysis, showing advantages of no waste water discharge and good economic and environmental benefits.

Funds：

甘肃省重点研发计划项目工业类（20YF3GA004）

AuthorIntro：

徐强（1981-），男，工程师，研究方向：膜分离技术应用，

Reference：

[1] Mohammad A W, Teow Y H, Ang W L, et al. Nanofiltration membranes review: Recent advances and future prospects[J]. Desalination, 2015, 356: 226-254.
[2] Strathmann H. Electrodialysis, a mature technology with a multitude of new applications[J]. Desalination, 2010, 264(3): 268-288.
[3] M. Dalwani, G. Bargeman, S.S. Hosseiny, M. Boerrigter, M. Wessling, N.E. Benes, Sulfonated poly(ether ether ketone) based composite membranes for nanofifiltration of acidic and alkaline media, J. Membr. Sci. 381 (2011) 81–89.
[4] M. Liu, G. Yao, Q. Cheng, M. Ma, S. Yu, C. Gao, Acid stable thin-fifilm composite mem
brane for nanofifiltration prepared from naphthalene-1,3,6-trisulfonylchloride (NTSC) and piperazine (PIP), J. Membr. Sci. 415–416 (2012) 122–131
[5] 陈如,陈庆. 纳滤法回收铝箔腐蚀废酸中磷酸的研究[J]. 辽宁化工, 2020, v.49;No.468(10):41-43.
[6] 王少明, 王建友, 卢会霞,等. 纳滤膜技术浓缩分离含镍离子溶液[J]. 水处理技术, 2010(8):92-95.
[7] 胡明, 张力萍, 陶柏润,等. 电渗析处理污酸进行酸浓缩与水回用的研究[C]// 第五届全国膜分离技术在冶金工业中应用研讨会论文集. 0.
[8] 杭晓风, 窦卫军, 陈向荣,等. 纳滤—电渗析处理纤维染色废水反渗透浓水研究[J]. 水处理技术, 2020, v.46;No.336(01):90-94.
[9] 田秉晖、刘芷源、李昱含. 基于"趋零排放"的高盐废水电渗析浓缩技术研究进展[J]. 环境工程学报, 2020, v.14(09):122-133.
[10] M.J.H. Snow, D. de Winter, R. Buckingham, J. Campbell, J. Wagner, New techniques for extreme conditions: High temperature reverse osmosis and nanofifiltration, Desalination 105 (1996) 57.
[11] Mattias Nilsson,Gun Trägårdh,Karin Östergren. The influence of pH, salt and temperature on nanofiltration performance[J]. Journal of Membrane Science,2007,312(1).
[12] Figoli A, Cassano A, Criscuoli A, et al. Influence of operating parameters on the arsenic removal by nanofiltration[J]. Water research, 2010, 44(1): 97-104.
[13] 邱实, 吴礼光, 张林,等. 纳滤分离机理[J]. 水处理技术, 2009(01):20-24.
[14]V. Freger, T. Arnot, J. Howell, Separation of concentrated organic/inorganic salt mixtures by nanofifiltration, J. Membr. Sci. 178 (2000) 185.
[15] Her N, Amy G, Jarusutthirak C. Nanofifiltration foulant identifification and control: Seasonal variations in inorganic and organic foulants. Proceedings of AWWA 2001 Membrane Technology Conference, Texas, 4–7, 2001.
[16] Gherasim C V , Cuhorka, Ji?í, Mikulá?ek, Petr. Analysis of lead(II) retention from single salt and binary aqueous solutions by a polyamide nanofiltration membrane: Experimental results and modelling[J]. Journal of Membrane Science, 2013, 436:132-144.
[17] Nyström M, Kaipia L, Luque S. Fouling and retention of nanofiltration membranes[J]. Journal of membrane science, 1995, 98(3): 249-262.
[18] Vrouwenvelder JS, van der Kooij D. Diagnosis, prediction and prevention of biofouling of NF and RO membranes. Desalination 2001;139:65–71.
[19] D. Roy, M. Rahni, P. Pierre, V. Yargeau, Forward osmosis for the concentration and reuse of process saline wastewater, Chem. Eng. J. 287 (2016) 277–284.
[20] T. Rottiers, K. Ghyselbrecht, B. Meesschaert, B. Van der Bruggen, L. Pinoy, Influence of the type of anion membrane on solvent flux and back diffusion in electrodialysis of concentrated NaCl solutions, Chem. Eng. Sci. 113 (2014) 95–100.

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