Position:Home >> Abstract

Preparation and antibacterial performance of high permeability PVDF/CS-HDH-Cl ultrafiltration membrane
Authors: Xu Jiafeng, Wang Han, Chen Yan, Lang Wanzhong
Units: The Education Ministry Key Lab of Resource Chemistry, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 200234, China.
KeyWords: polyvinylidene fluoride membrane;halamine;chitosan;antibacterial
ClassificationCode:TQ31
year,volume(issue):pagination: 2021,41(6):103-109

Abstract:
 CS-HDH was simply synthesized by chitosan and hine, and then CS-HDH-Cl was finally obtained by chlorination. Polyvinylidene fluoride (PVDF) membranes prepared by adding CS-HDH-Cl have good advantages of hydrophilic, anti-pollution and antibacterial properties. The results showed that the addition of CS-HDH-Cl improved the hydrophilicity of PVDF membranes.
With the addition of CS-HDH-Cl mass increased to 0.9 %, the permeation flux was up to 351.2 L?m-2?h-1. Flux recovery rate(FRR) of PVDF/CS-HDH-Cl membrane could achieves 90.9%. When the oxidative chlorine content increased to 0.69 mmol?g-1, M-4 showed the utmost sterilization ratios of 98.7% and 98.9% against E.coli and S.aureus, respectively.

Funds:
上海绿色能源化工工程技术研究中心(18DZ2254200)

AuthorIntro:
徐佳峰(1998-),女,硕士研究生,主要从事膜分离技术研究,E-mail:xjf101408@163.com

Reference:
 [1] Yuliwati E, Ismail A F. Effect of additives concentration on the surface properties and performance of PVDF ultrafiltration membranes for refinery produced wastewater treatment[J]. Desalination, 2011, 273(1): 226-234.
[2] Rahimpour A, Madaeni S S, Amirinejad M, et al. The effect of heat treatment of PES and PVDF ultrafiltration membranes on morphology and performance for milk filtration[J]. Journal of Membrane Science, 2009, 330(1–2): 189-204.
[3] 康标. 抗菌抗污染有机超滤膜的制备及性能表征[D]. 上海师范大学, 2016.
[4] 刘忠洲, 续曙光, 李锁定. 微滤、超滤过程中的膜污染与清洗[J]. 水处理技术, 1997, (4): 187-193. 
[5] 季君晖, 史维明. 抗菌材料[M].  化学工业出版社, 2004.
[6] And Y S, Sun G. Novel Refreshable N-Halamine Polymeric Biocides:  N-Chlorination of Aromatic Polyamides[J]. Industrial & Engineering Chemistry Research, 2004, 43(17): 5015-5020.
[7] Braun M, Sun Y. Antimicrobial polymers containing melamine derivatives. I. Preparation and characterization of chloromelamine-based cellulose[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2004, 42(15): 3818-3827.
[8] Worley S, Li F, Wu R, et al. A novel N-halamine monomer for preparing biocidal polyurethane coatings[J]. Surface Coatings International Part B: Coatings Transactions, 2003, 86(4): 273-277.
[9] Sun Y, Sun G. Novel refreshable N-halamine polymeric biocides: Grafting hydantoin-containing monomers onto high performance fibers by a continuous process[J]. Journal of Applied Polymer Science, 2003, 88(4): 1032-1039.
[10] Qian L, Sun G. Durable and regenerable antimicrobial textiles: Synthesis and applications of 3-methylol-2,2,5,5-tetramethyl-imidazolidin-4-one (MTMIO)[J]. Journal of Applied Polymer Science, 2003, 89(9): 2418-2425.
[11] 王函. 卤胺及纳米银改性PVDF超滤膜的制备及性能研究[D]. 上海师范大学, 2017.
[12] Zhou C-E, Kan C-W. Plasma-enhanced regenerable 5,5-dimethylhydantoin (DMH) antibacterial finishing for cotton fabric[J]. Applied Surface Science, 2015, 328: 410-417.
[13] Rabea E I, Badawy M E T, Stevens C V, et al. Chitosan as Antimicrobial Agent:  Applications and Mode of Action[J]. Biomacromolecules, 2003, 4(6): 1457-1465. 
[14] Ye W, Xin J H, Li P, et al. Durable antibacterial finish on cotton fabric by using chitosan-based polymeric core-shell particles[J]. Journal of Applied Polymer Science, 2006, 102(2): 1787-1793. 
[15] Elsabee M Z, Abdou E S, Nagy K S A, et al. Surface modification of polypropylene films by chitosan and chitosan/pectin multilayer[J]. Carbohydrate Polymers, 2008, 71(2): 187-195.
[16] Song H, Wu D, Zhang R-Q, et al. Synthesis and application of amphoteric starch graft polymer[J]. Carbohydrate Polymers, 2009, 78(2): 253-257.
[17] Hassan M S. Crease recovery properties of cotton fabrics modified by urea resins under the effect of gamma irradiation[J]. Radiation Physics and Chemistry, 2009, 78(5): 333-337.
[18] 郑化, 杜予民. 纤维素/羧甲基壳聚糖共混膜结构与抗菌性能[J]. 高分子材料科学与工程, 2002, 18(4): 124-128.
[19] Liu F, Qin B, He L, et al. Novel starch/chitosan blending membrane: Antibacterial, permeable and mechanical properties[J]. Carbohydrate Polymers, 2009, 78(1): 146–150.
[20] Cheng X, Ma K, Li R, et al. Antimicrobial coating of modified chitosan onto cotton fabrics[J]. Applied Surface Science, 2014, 309: 138-143. 
[21] 黄袁炜. 改性MWNTs制备具有抗菌性和易清洁性的PVDF膜[D]. 上海师范大学, 2018.
[22] Chen Y, Liu X, Liu L, et al. Functional polyvinylidene fluoride membrane anchored with silver nanoparticle with antibacterial activity[J]. Synthetic Metals, 2013, 174: 1-5.
[23] Pan Y, Yu Z, Shi H, et al. A novel antifouling and antibacterial surface-functionalized PVDF ultrafiltration membrane via binding Ag/SiO2 nanocomposites[J]. Journal of Chemical Technology & Biotechnology, 2016.
[24] Liu S, Sun G. Durable and Regenerable Biocidal Polymers:  Acyclic N-Halamine Cotton Cellulose[J]. Industrial & Engineering Chemistry Research, 2006, 45(19): 6477-6482.
[25] Kang B, Li Y-D, Liang J, et al. Novel PVDF hollow fiber ultrafiltration membranes with antibacterial and antifouling properties by embedding N-halamine functionalized multi-walled carbon nanotubes (MWNTs)[J]. RSC Advances, 2016, 6(3): 1710-1721.

Service:
Download】【Collect

《膜科学与技术》编辑部 Address: Bluestar building, 19 east beisanhuan road, chaoyang district, Beijing; 100029 Postal code; Telephone:010-80492417/010-80485372; Fax:010-80485372 ; Email:mkxyjs@163.com

京公网安备11011302000819号