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Recent Progress in Stimuli-Responsive Polyethersulfone Membranes

Authors： XIE Yi，WEI Ran，CHEN Shengqiu，WEI Zhiwei，ZHAO Weifeng，ZHAO Changsheng

Units： College of Polymer Science and Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

KeyWords： polyethersulfone membranes, stimuli-responsive，pH-responsive; ion-responsive; thermal-responsive; light-responsive

ClassificationCode：TQ31

year,volume(issue):pagination： 2022,42(4):130-137

Abstract：

Polyethersulfone (PES) membranes have been widely used in advanced separation and biomedical fields due to their excellent comprehensive properties. However, with the increasing needs for separation accuracy and the controllability of separation process in different fields, it is more and more difficult for commercial polyethersulfone membranes to meet the actual needs. Therefore, researches and developments of stimuli-responsive PES membranes that can sense and respond to environmental stimuli and change their characteristics, have always been attract much attentions for the researchers. According to the types of stimulus response signals, this article introduces acid-base sensitive membranes, thermal-responsive membranes, ion-responsive membranes, and light-responsive membranes, as well as their applications in different fields, and illustrates the interdependence of stimulus signals-membrane structure response-function applications. Then, we also put forward the prospects for future research direction of environmentally sensitive PES membranes.

Funds：

国家自然科学基金（51903168, 51873115）；国家重点研发专项（2016YFC1103000，2018YFC1106400）。

AuthorIntro：

谢毅（1990-06），男，四川广安人，副研究员，博士，研究方向为生物医用高分子

Reference：

[1] 张翔, 赵伟锋, 赵长生, 功能性聚醚砜膜的研究进展[J]. 功能高分子学报 34 (2021) 114-125.
[2] C. Zhao, J. Xue, F. Ran, et al., Modification of polyethersulfone membranes – A review of methods[J]. Prog. Mater. Sci. 58(1) (2013) 76-150.
[3] C. Zhao, S. Nie, M. Tang, et al., Polymeric pH-sensitive membranes—A review[J]. Prog. Polym. Sci. 36(11) (2011) 1499-1520.
[4] S. Chen, Y. Xie, A. Chinnappan, et al., A self-cleaning zwitterionic nanofibrous membrane for highly efficient oil-in-water separation[J]. Sci. Total Environ. 729 (2020) 138876.
[5] C. Lv, S. Chen, Y. Xie, et al., Positively-charged polyethersulfone nanofibrous membranes for bacteria and anionic dyes removal[J]. J. Colloid. Interf. Sci. 556 (2019) 492-502.
[6] T. Xiang, L.-R. Wang, L. Ma, et al., From commodity polymers to functional polymers[J]. Sci. Rep. 4(1) (2014) 1-5.
[7] Y. Xie, R. Wang, S. Li, et al., A robust way to prepare blood-compatible and anti-fouling polyethersulfone membrane[J]. Colloids Surf. B. Biointerfaces 146 (2016) 326-333.
[8] Y. Xie, S. Li, X. Jiang, et al., Zwitterionic glycosyl modified polyethersulfone membranes with enhanced anti-fouling property and blood compatibility[J]. J. Colloid. Interf. Sci. 443 (2015) 36-44.
[9] L. Yao, C. He, S. Chen, et al., Codeposition of Polydopamine and Zwitterionic Polymer on Membrane Surface with Enhanced Stability and Antibiofouling Property[J]. Langmuir 35(5) (2019) 1430-1439.
[10] Q. Wei, F. Zhang, J. Li, et al., Oxidant-induced dopamine polymerization for multifunctional coatings[J]. Polymer Chemistry 1 (2010) 1430-1433.
[11] Y. Xie, L. Chen, X. Zhang, et al., Integrating zwitterionic polymer and Ag nanoparticles on polymeric membrane surface to prepare antifouling and bactericidal surface via Schiff-based layer-by-layer assembly[J]. J. Colloid. Interf. Sci. 510 (2018) 308-317.
[12] S. Chen, Y. Xie, T. Xiao, et al., Tannic acid-inspiration and post-crosslinking of zwitterionic polymer as a universal approach towards antifouling surface[J]. Chem. Eng. J. 337 (2018) 122-132.
[13] Y. Xie, S. Chen, Y. Qian, et al., Photo-responsive membrane surface: Switching from bactericidal to bacteria-resistant property[J]. Mater. Sci. Eng. C. 84 (2018) 52-59.
[14] C. Cheng, S. Sun, C. Zhao, Progress in heparin and heparin-like/mimicking polymer-functionalized biomedical membranes[J]. J. Mater. Chem. B 2(44) (2014) 7649-7672.
[15] M. Tang, J. Xue, K. Yan, et al., Heparin-like surface modification of polyethersulfone membrane and its biocompatibility[J]. J. Colloid. Interf. Sci. 386(1) (2012) 428-40.
[16] J. Ren, W. Zhao, C. Cheng, et al., Comparison of pH-sensitivity between two copolymer modified polyethersulfone hollow fiber membranes[J]. Desalination 280(1-3) (2011) 152-159.
[17] S. Chen, Y. Du, X. Zhang, et al., One-step electrospinning of negatively-charged polyethersulfone nanofibrous membranes for selective removal of cationic dyes[J]. Journal of the Taiwan Institute of Chemical Engineers 82 (2018) 179-188.
[18] W. Zou, Y. Huang, J. Luo, et al., Poly (methyl methacrylate–acrylic acid–vinyl pyrrolidone) terpolymer modified polyethersulfone hollow fiber membrane with pH sensitivity and protein antifouling property[J]. J. Membr. Sci. 358(1-2) (2010) 76-84.
[19] Q. Wei, J. Li, B. Qian, et al., Preparation, characterization and application of functional polyethersulfone membranes blended with poly (acrylic acid) gels[J]. J. Membr. Sci. 337(1-2) (2009) 266-273.
[20] R. Wang, T. Xiang, W. Yue, et al., Preparation and characterization of pH-sensitive polyethersulfone hollow fiber membranes modified by poly(methyl methylacrylate-co-4-vinyl pyridine) copolymer[J]. J. Membr. Sci. 423-424 (2012) 275-283.
[21] X. Zhang, J. Zhou, R. Wei, et al., Design of anion species/strength responsive membranes via in-situ cross-linked copolymerization of ionic liquids[J]. J. Membr. Sci. 535 (2017) 158-167.
[22] X. Zhang, S. Xu, J. Zhou, et al., Anion-Responsive Poly(ionic liquid)s Gating Membranes with Tunable Hydrodynamic Permeability[J]. ACS Appl. Mater. Interfaces 9(37) (2017) 32237-32247.
[23] R. Wei, F. Yang, R. Gu, et al., Design of Robust Thermal and Anion Dual-Responsive Membranes with Switchable Response Temperature[J]. ACS Appl. Mater. Interfaces 10(42) (2018) 36443-36455.
[24] Ö. Tekinalp, S.A. Altinkaya, Development of high flux nanofiltration membranes through single bilayer polyethyleneimine/alginate deposition[J]. J. Colloid. Interf. Sci. 537 (2019) 215-227.
[25] T. Xiang, T. Lu, W.-F. Zhao, et al., Ionic strength- and thermo-responsive polyethersulfone composite membranes with enhanced antifouling properties[J]. New J. Chem. 42(7) (2018) 5323-5333.
[26] T. Xiang, C.-D. Luo, R. Wang, et al., Ionic-strength-sensitive polyethersulfone membrane with improved anti-fouling property modified by zwitterionic polymer via in situ cross-linked polymerization[J]. J. Membr. Sci. 476 (2015) 234-242.
[27] M. Birkner, Ultrafiltration membranes with markedly different pH-and ion-responsivity by photografted zwitterionic polysulfobetain or polycarbobetain[J]. J. Membr. Sci. 494 (2015) 57-67.
[28] K. Belal, F. Stoffelbach, J. Lyskawa, et al., Recognition-Mediated Hydrogel Swelling Controlled by Interaction with a Negative Thermoresponsive LCST Polymer[J]. Angew. Chem. Int. Ed. 55(45) (2016) 13974-13978.
[29] V. Boyko, S. Richter, I. Grillo, et al., Structure of thermosensitive poly(N-vinylcaprolactam-co-N-vinylpyrrolidone) microgels[J]. Macromolecules 38(12) (2005) 5266-5270.
[30] M.A. Kostiainen, C. Pietsch, R. Hoogenboom, et al., Temperature-Switchable Assembly of Supramolecular Virus-Polymer Complexes[J]. Advanced Functional Materials 21(11) (2011) 2012-2019.
[31] M. He, Q. Wang, J. Zhang, et al., Substrate-Independent Ag-Nanoparticle-Loaded Hydrogel Coating with Regenerable Bactericidal and Thermoresponsive Antibacterial Properties[J]. ACS Appl. Mater. Interfaces 9(51) (2017) 44782-44791.
[32] Q. Wang, Y. Feng, M. He, et al., Thermoresponsive Antibacterial Surfaces Switching from Bacterial Adhesion to Bacterial Repulsion[J]. Macromolecular Materials and Engineering 303(5) (2018).
[33] K.A.S. Bornillo, S. Kim, H. Choi, Cu (II) removal using electrospun dual-responsive polyethersulfone-poly (dimethyl amino) ethyl methacrylate (PES-PDMAEMA) blend nanofibers[J]. Chemosphere 242 (2020) 125287.
[34] R. Wei, F. Yang, R. Gu, et al., Design of Robust Thermal and Anion Dual-Responsive Membranes with Switchable Response Temperature[J]. ACS Appl. Mater. Interfaces 10(42) (2018) 36443-36455.
[35] D. Wang, W. Zhao, Q. Wei, et al., Photoswitchable Azobenzene/Cyclodextrin Host-Guest Complexes: From UV- to Visible/Near-IR-Light-Responsive Systems[J]. chemphotochem 2 (2018) 403-415.
[36] W. Shi, J. Deng, H. Qin, et al., Poly(ether sulfone) membranes with photo-responsive permeability[J]. J. Membr. Sci. 455 (2014) 357-367.
[37] Y. Xu, W. Lin, H. Wang, et al., Dual-functional polyethersulfone composite nanofibrous membranes with synergistic adsorption and photocatalytic degradation for organic dyes[J]. Composites Sci. Technol. 199 (2020).
[38] L. Chen, B. Yang, P. Zhou, et al., A polyethersulfone composite ultrafiltration membrane with the in-situ generation of CdS nanoparticles for the effective removal of organic pollutants and photocatalytic self-cleaning[J]. J. Membr. Sci. (2021) 119715.
[39] R. Wei, J. Guo, L. Jin, et al., Vapor induced phase separation towards anion-/near-infrared-responsive pore channels for switchable anti-fouling membranes[J]. J. Mater. Chem. A 8(18) (2020) 8934-8948.
[40] M. He, Q. Wang, Z. Shi, et al., Inflammation-responsive self-regulated drug release from ultrathin hydrogel coating[J]. Colloids Surf. B. Biointerfaces 158 (2017) 518-526.
[41] W. Shi, L. Zhang, J. Deng, et al., Redox-responsive polymeric membranes via supermolecular host–guest interactions[J]. J. Membr. Sci. 480 (2015) 139-152.

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